An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements
Abstract
Abstract The synthesis, structure, and spectroscopic characterization of the first transplutonium metal–organic framework (MOF) is described. The preparation and structure of Am‐GWMOF‐6, [Am 2 (C 6 H 8 O 4 ) 3 (H 2 O) 2 ][(C 10 H 8 N 2 )], is analogous to that of the isostructural trivalent lanthanide‐only containing material GWMOF‐6. The presented MOF architecture is used as a platform to probe Am 3+ coordination chemistry and guest‐enhanced luminescent emission, whereas the framework itself provides a means to monitor the effects of self‐irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that MOFs provide in the structural and spectroscopic study of actinides.
- Authors:
-
- Department of Chemistry The George Washington University 800 22nd St NW Washington D.C. 20052 USA
- Pacific Northwest National Laboratory 902 Battelle Boulevard Richland WA 99354 USA
- Radiochemistry Department of Chemistry and Biochemistry University of Nevada Las Vegas 4505 S. Maryland Pkwy Las Vegas NV 89154 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1567890
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition) Journal Volume: 58 Journal Issue: 46; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Ridenour, J. August, Surbella, III, Robert G., Gelis, Artem V., Koury, Daniel, Poineau, Frederic, Czerwinski, Kenneth R., and Cahill, Christopher L. An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements. Germany: N. p., 2019.
Web. doi:10.1002/anie.201909988.
Ridenour, J. August, Surbella, III, Robert G., Gelis, Artem V., Koury, Daniel, Poineau, Frederic, Czerwinski, Kenneth R., & Cahill, Christopher L. An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements. Germany. https://doi.org/10.1002/anie.201909988
Ridenour, J. August, Surbella, III, Robert G., Gelis, Artem V., Koury, Daniel, Poineau, Frederic, Czerwinski, Kenneth R., and Cahill, Christopher L. Mon .
"An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements". Germany. https://doi.org/10.1002/anie.201909988.
@article{osti_1567890,
title = {An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements},
author = {Ridenour, J. August and Surbella, III, Robert G. and Gelis, Artem V. and Koury, Daniel and Poineau, Frederic and Czerwinski, Kenneth R. and Cahill, Christopher L.},
abstractNote = {Abstract The synthesis, structure, and spectroscopic characterization of the first transplutonium metal–organic framework (MOF) is described. The preparation and structure of Am‐GWMOF‐6, [Am 2 (C 6 H 8 O 4 ) 3 (H 2 O) 2 ][(C 10 H 8 N 2 )], is analogous to that of the isostructural trivalent lanthanide‐only containing material GWMOF‐6. The presented MOF architecture is used as a platform to probe Am 3+ coordination chemistry and guest‐enhanced luminescent emission, whereas the framework itself provides a means to monitor the effects of self‐irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that MOFs provide in the structural and spectroscopic study of actinides.},
doi = {10.1002/anie.201909988},
journal = {Angewandte Chemie (International Edition)},
number = 46,
volume = 58,
place = {Germany},
year = {Mon Sep 30 00:00:00 EDT 2019},
month = {Mon Sep 30 00:00:00 EDT 2019}
}
https://doi.org/10.1002/anie.201909988
Web of Science
Works referenced in this record:
Examination of Structure and Bonding in 10-Coordinate Europium and Americium Terpyridyl Complexes
journal, September 2018
- White, Frankie D.; Gaiser, Alyssa N.; Warzecha, Evan J.
- Inorganic Chemistry, Vol. 57, Issue 20
Toward Templated Metal−Organic Frameworks: Synthesis, Structures, Thermal Properties, and Luminescence of Three Novel Lanthanide−Adipate Frameworks
journal, January 2005
- de Lill, Daniel T.; Gunning, Noel S.; Cahill, Christopher L.
- Inorganic Chemistry, Vol. 44, Issue 2
Actinide Lanthanide Separation Process—ALSEP
journal, January 2014
- Gelis, Artem V.; Lumetta, Gregg J.
- Industrial & Engineering Chemistry Research, Vol. 53, Issue 4
The Actinide-Lanthanide Separation Concept
journal, May 2014
- Lumetta, Gregg J.; Gelis, Artem V.; Carter, Jennifer C.
- Solvent Extraction and Ion Exchange, Vol. 32, Issue 4
Stable Metal-Organic Frameworks: Design, Synthesis, and Applications
journal, February 2018
- Yuan, Shuai; Feng, Liang; Wang, Kecheng
- Advanced Materials, Vol. 30, Issue 37
Identifying the Recognition Site for Selective Trapping of 99 TcO 4 – in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework
journal, October 2017
- Zhu, Lin; Sheng, Daopeng; Xu, Chao
- Journal of the American Chemical Society, Vol. 139, Issue 42
Direct Radiation Detection by a Semiconductive Metal–Organic Framework
journal, May 2019
- Wang, Yaxing; Liu, Xin; Li, Xiaoyan
- Journal of the American Chemical Society, Vol. 141, Issue 20
[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex
journal, July 2019
- Goodwin, Conrad A. P.; Su, Jing; Albrecht‐Schmitt, Thomas E.
- Angewandte Chemie, Vol. 131, Issue 34
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Luminescence of americium (III) and europium (III) in the cubic structure ThO2
journal, September 1992
- Hubert, S.; Thouvenot, P.
- Journal of Luminescence, Vol. 54, Issue 2
Crystal structure of americium sulfate octahydrate
journal, September 1972
- Burns, John H.; Baybarz, Russell D.
- Inorganic Chemistry, Vol. 11, Issue 9
The Chemistry of TALSPEAK: A Review of the Science
journal, December 2014
- Nash, Kenneth L.
- Solvent Extraction and Ion Exchange, Vol. 33, Issue 1
A structural and spectrophotometric study on the complexation of Am( iii ) with TMOGA in comparison with the extracted complex of DMDOOGA
journal, January 2015
- Tian, Guoxin; Shuh, David K.; Beavers, Christine M.
- Dalton Transactions, Vol. 44, Issue 42
Adsorption-based atmospheric water harvesting device for arid climates
journal, March 2018
- Kim, Hyunho; Rao, Sameer R.; Kapustin, Eugene A.
- Nature Communications, Vol. 9, Issue 1
Exploration of porous metal–organic frameworks for gas separation and purification
journal, January 2019
- Lin, Rui-Biao; Xiang, Shengchang; Xing, Huabin
- Coordination Chemistry Reviews, Vol. 378
Low‐Temperature Optical Absorption of Americium Halides
journal, August 1969
- Pappalardo, R. G.; Carnall, W. T.; Fields, P. R.
- The Journal of Chemical Physics, Vol. 51, Issue 3
Spectroscopic studies and crystal-field analyses of and in the cubic-symmetry site of
journal, September 1993
- Hubert, S.; Thouvenot, P.; Edelstein, N.
- Physical Review B, Vol. 48, Issue 9
Synthesis and Characterization of Tris-chelate Complexes for Understanding f -Orbital Bonding in Later Actinides
journal, January 2019
- Galley, Shane S.; Pattenaude, Scott A.; Gaggioli, Carlo Alberto
- Journal of the American Chemical Society, Vol. 141, Issue 6
Highly porous and stable metal–organic frameworks for uranium extraction
journal, January 2013
- Carboni, Michaël; Abney, Carter W.; Liu, Shubin
- Chemical Science, Vol. 4, Issue 6, p. 2396-2402
Intramolecular sensitization of americium luminescence in solution: shining light on short-lived forbidden 5f transitions
journal, January 2016
- Sturzbecher-Hoehne, M.; Yang, P.; D'Aléo, A.
- Dalton Transactions, Vol. 45, Issue 24
Coordination Modes of Americium in the Am 2 (C 2 O 4 ) 3 (H 2 O) 6 ·4H 2 O Oxalate: Synthesis, Crystal Structure, Spectroscopic Characterizations and Comparison in the M 2 (C 2 O 4 ) 3 (H 2 O) 6 · n H 2 O (M = Ln, An) Series
journal, December 2015
- Tamain, C.; Arab-Chapelet, B.; Rivenet, M.
- Inorganic Chemistry, Vol. 55, Issue 1
Volume changes in δ-plutonium from helium and other decay products
journal, September 2006
- Wolfer, W. G.; Söderlind, Per; Landa, A.
- Journal of Nuclear Materials, Vol. 355, Issue 1-3
Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state
journal, August 2016
- Silver, M. A.; Cary, S. K.; Johnson, J. A.
- Science, Vol. 353, Issue 6302
Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery
journal, October 2011
- Della Rocca, Joseph; Liu, Demin; Lin, Wenbin
- Accounts of Chemical Research, Vol. 44, Issue 10, p. 957-968
Simulating radiation damage in δ-plutonium
journal, September 2009
- Robinson, M.; Kenny, S. D.; Smith, R.
- Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 267, Issue 18
An efficient nanosieve
journal, November 2018
- Bavykina, Anastasiya; Gascon, Jorge
- Nature Materials, Vol. 17, Issue 12
The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution
journal, January 2007
- Lindqvist-Reis, Patric; Apostolidis, Christos; Rebizant, Jean
- Angewandte Chemie International Edition, Vol. 46, Issue 6
Emergence of californium as the second transitional element in the actinide series
journal, April 2015
- Cary, Samantha K.; Vasiliu, Monica; Baumbach, Ryan E.
- Nature Communications, Vol. 6, Issue 1
Revised values of effective ionic radii
journal, July 1970
- Shannon, R. D.; Prewitt, C. T.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 26, Issue 7
Capture of iodine in highly stable metal–organic frameworks: a systematic study
journal, January 2013
- Falaise, Clément; Volkringer, Christophe; Facqueur, Jacques
- Chemical Communications, Vol. 49, Issue 87
Luminescent metal–organic frameworks
journal, January 2009
- Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.
- Chemical Society Reviews, Vol. 38, Issue 5
Lanthanide ion probes of structure in biology. Laser-induced luminescence decay constants provide a direct measure of the number of metal-coordinated water molecules
journal, January 1979
- Horrocks, William DeW.; Sudnick, Daniel R.
- Journal of the American Chemical Society, Vol. 101, Issue 2
Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium
journal, September 2016
- Cross, Justin N.; Macor, Joseph A.; Bertke, Jeffery A.
- Angewandte Chemie International Edition, Vol. 55, Issue 41
Synthesis, Structure, and Spectroscopic Properties of Am(IO 3 ) 3 and the Photoluminescence Behavior of Cm(IO 3 ) 3
journal, August 2005
- Sykora, Richard E.; Assefa, Zerihun; Haire, Richard G.
- Inorganic Chemistry, Vol. 44, Issue 16
From Antenna to Assay: Lessons Learned in Lanthanide Luminescence
journal, April 2009
- Moore, Evan G.; Samuel, Amanda P. S.; Raymond, Kenneth N.
- Accounts of Chemical Research, Vol. 42, Issue 4
The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution
journal, January 2007
- Lindqvist-Reis, Patric; Apostolidis, Christos; Rebizant, Jean
- Angewandte Chemie, Vol. 119, Issue 6
Applications of metal–organic frameworks in heterogeneous supramolecular catalysis
journal, January 2014
- Liu, Jiewei; Chen, Lianfen; Cui, Hao
- Chemical Society Reviews, Vol. 43, Issue 16, p. 6011-6061
Acid-Resistant Mesoporous Metal–Organic Framework toward Oral Insulin Delivery: Protein Encapsulation, Protection, and Release
journal, April 2018
- Chen, Yijing; Li, Peng; Modica, Justin A.
- Journal of the American Chemical Society, Vol. 140, Issue 17
The Separation of Americium and Curium from the Rare Earth Elements
journal, June 1950
- Street, Kenneth; Seaborg, Glenn T.
- Journal of the American Chemical Society, Vol. 72, Issue 6
Unidirectional rotary motion in a metal–organic framework
journal, March 2019
- Danowski, Wojciech; van Leeuwen, Thomas; Abdolahzadeh, Shaghayegh
- Nature Nanotechnology, Vol. 14, Issue 5
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
Catalysis and photocatalysis by metal organic frameworks
journal, January 2018
- Dhakshinamoorthy, Amarajothi; Li, Zhaohui; Garcia, Hermenegildo
- Chemical Society Reviews, Vol. 47, Issue 22
Luminescence study on determination of the inner-sphere hydration number of Am(III) and Nd(III)
journal, June 1998
- Kimura, Takaumi; Kato, Yoshiharu
- Journal of Alloys and Compounds, Vol. 271-273
Origin of Selectivity of a Triazinyl Ligand for Americium(III) over Neodymium(III)
journal, February 2019
- Dan, David; Celis‐Barros, Cristian; White, Frankie D.
- Chemistry – A European Journal
First demonstration of a centrifugal solvent extraction process for minor actinides from a concentrated spent fuel solution
journal, October 2005
- Serrano-Purroy, Daniel; Baron, Pascal; Christiansen, Birgit
- Separation and Purification Technology, Vol. 45, Issue 2
A series of dithiocarbamates for americium, curium, and californium
journal, January 2018
- Cary, Samantha K.; Su, Jing; Galley, Shane S.
- Dalton Transactions, Vol. 47, Issue 41
Structure and properties of 2,2-dihydroxymalonates of trivalent Y, lanthanides, Pu and Am
journal, March 2013
- Gogolev, A. V.; Grigoriev, M. S.; Budantseva, N. A.
- Russian Journal of Coordination Chemistry, Vol. 39, Issue 3
Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium
journal, September 2016
- Cross, Justin N.; Macor, Joseph A.; Bertke, Jeffery A.
- Angewandte Chemie, Vol. 128, Issue 41
Covalency in Americium(III) Hexachloride
journal, June 2017
- Cross, Justin N.; Su, Jing; Batista, Enrique R.
- Journal of the American Chemical Society, Vol. 139, Issue 25
Exploring Lanthanide Luminescence in Metal-Organic Frameworks: Synthesis, Structure, and Guest-Sensitized Luminescence of a Mixed Europium/Terbium-Adipate Framework and a Terbium-Adipate Framework
journal, May 2007
- de Lill, Daniel T.; de Bettencourt-Dias, Ana; Cahill, Christopher L.
- Inorganic Chemistry, Vol. 46, Issue 10
Absorption Spectrum of Americium Tricyclopentadienide
journal, July 1969
- Pappalardo, R.; Carnall, W. T.; Fields, P. R.
- The Journal of Chemical Physics, Vol. 51, Issue 2
[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex
journal, July 2019
- Goodwin, Conrad A. P.; Su, Jing; Albrecht-Schmitt, Thomas E.
- Angewandte Chemie International Edition, Vol. 58, Issue 34
THE TRUEX PROCESS - A PROCESS FOR THE EXTRACTION OF THE TKANSURANIC ELEMENTS EROM NITRIC AC In WASTES UTILIZING MODIFIED PUREX SOLVENT*
journal, February 1985
- Philip Horwitz, E.; Kalina, Dale C.; Diamond, Herbert
- Solvent Extraction and Ion Exchange, Vol. 3, Issue 1-2
Metal–organic framework with optimally selective xenon adsorption and separation
journal, June 2016
- Banerjee, Debasis; Simon, Cory M.; Plonka, Anna M.
- Nature Communications, Vol. 7, Issue 1
Sensitizing Curium Luminescence through an Antenna Protein To Investigate Biological Actinide Transport Mechanisms
journal, February 2013
- Sturzbecher-Hoehne, Manuel; Goujon, Christophe; Deblonde, Gauthier J. -P.
- Journal of the American Chemical Society, Vol. 135, Issue 7
An Advanced TALSPEAK Concept Using 2-Ethylhexylphosphonic Acid Mono-2-Ethylhexyl Ester as the Extractant
journal, December 2014
- Lumetta, Gregg J.; Casella, Amanda J.; Rapko, Brian M.
- Solvent Extraction and Ion Exchange, Vol. 33, Issue 3
Spectroscopic speciation of aqueous Am( iii )–oxalate complexes
journal, January 2019
- Kim, H. -K.; Jeong, K.; Cho, H. -R.
- Dalton Transactions, Vol. 48, Issue 27
Taking advantage of luminescent lanthanide ions
journal, January 2005
- Bünzli, Jean-Claude G.; Piguet, Claude
- Chemical Society Reviews, Vol. 34, Issue 12
Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform
journal, February 2018
- Corbey, Jordan F.; Rapko, Brian M.; Wang, Zheming
- Inorganic Chemistry, Vol. 57, Issue 4