An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements

Ridenour, J. August; Surbella, III, Robert G.; Gelis, Artem V.; Koury, Daniel; Poineau, Frederic; Czerwinski, Kenneth R.; Cahill, Christopher L.

doi:10.1002/anie.201909988

Title: An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements

Journal Article · 30 September 2019 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201909988 · OSTI ID:1567890

Ridenour, J. August ^[1]; Surbella, III, Robert G. ^[2]; Gelis, Artem V. ^[3]; Koury, Daniel ^[3]; Poineau, Frederic ^[3]; Czerwinski, Kenneth R. ^[3];

^[1]

Department of Chemistry The George Washington University 800 22^nd St NW Washington D.C. 20052 USA
Pacific Northwest National Laboratory 902 Battelle Boulevard Richland WA 99354 USA
Radiochemistry Department of Chemistry and Biochemistry University of Nevada Las Vegas 4505 S. Maryland Pkwy Las Vegas NV 89154 USA

Abstract The synthesis, structure, and spectroscopic characterization of the first transplutonium metal–organic framework (MOF) is described. The preparation and structure of Am‐GWMOF‐6, [Am ₂ (C ₆ H ₈ O ₄ ) ₃ (H ₂ O) ₂ ][(C ₁₀ H ₈ N ₂ )], is analogous to that of the isostructural trivalent lanthanide‐only containing material GWMOF‐6. The presented MOF architecture is used as a platform to probe Am ³⁺ coordination chemistry and guest‐enhanced luminescent emission, whereas the framework itself provides a means to monitor the effects of self‐irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that MOFs provide in the structural and spectroscopic study of actinides.

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Sponsoring Organization:: USDOE

OSTI ID:: 1567890

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Vol. 58 Journal Issue: 46; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 20 works

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