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Title: An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements

Abstract

Abstract The synthesis, structure, and spectroscopic characterization of the first transplutonium metal–organic framework (MOF) is described. The preparation and structure of Am‐GWMOF‐6, [Am 2 (C 6 H 8 O 4 ) 3 (H 2 O) 2 ][(C 10 H 8 N 2 )], is analogous to that of the isostructural trivalent lanthanide‐only containing material GWMOF‐6. The presented MOF architecture is used as a platform to probe Am 3+ coordination chemistry and guest‐enhanced luminescent emission, whereas the framework itself provides a means to monitor the effects of self‐irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that MOFs provide in the structural and spectroscopic study of actinides.

Authors:
 [1];  [2];  [3];  [3];  [3];  [3]; ORCiD logo [1]
  1. Department of Chemistry The George Washington University 800 22nd St NW Washington D.C. 20052 USA
  2. Pacific Northwest National Laboratory 902 Battelle Boulevard Richland WA 99354 USA
  3. Radiochemistry Department of Chemistry and Biochemistry University of Nevada Las Vegas 4505 S. Maryland Pkwy Las Vegas NV 89154 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1567888
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 46; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Ridenour, J. August, Surbella, III, Robert G., Gelis, Artem V., Koury, Daniel, Poineau, Frederic, Czerwinski, Kenneth R., and Cahill, Christopher L. An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements. Germany: N. p., 2019. Web. doi:10.1002/ange.201909988.
Ridenour, J. August, Surbella, III, Robert G., Gelis, Artem V., Koury, Daniel, Poineau, Frederic, Czerwinski, Kenneth R., & Cahill, Christopher L. An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements. Germany. https://doi.org/10.1002/ange.201909988
Ridenour, J. August, Surbella, III, Robert G., Gelis, Artem V., Koury, Daniel, Poineau, Frederic, Czerwinski, Kenneth R., and Cahill, Christopher L. Mon . "An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements". Germany. https://doi.org/10.1002/ange.201909988.
@article{osti_1567888,
title = {An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements},
author = {Ridenour, J. August and Surbella, III, Robert G. and Gelis, Artem V. and Koury, Daniel and Poineau, Frederic and Czerwinski, Kenneth R. and Cahill, Christopher L.},
abstractNote = {Abstract The synthesis, structure, and spectroscopic characterization of the first transplutonium metal–organic framework (MOF) is described. The preparation and structure of Am‐GWMOF‐6, [Am 2 (C 6 H 8 O 4 ) 3 (H 2 O) 2 ][(C 10 H 8 N 2 )], is analogous to that of the isostructural trivalent lanthanide‐only containing material GWMOF‐6. The presented MOF architecture is used as a platform to probe Am 3+ coordination chemistry and guest‐enhanced luminescent emission, whereas the framework itself provides a means to monitor the effects of self‐irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that MOFs provide in the structural and spectroscopic study of actinides.},
doi = {10.1002/ange.201909988},
journal = {Angewandte Chemie},
number = 46,
volume = 131,
place = {Germany},
year = {Mon Sep 30 00:00:00 EDT 2019},
month = {Mon Sep 30 00:00:00 EDT 2019}
}

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