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Title: The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework

Abstract

The thermally generatable decarboxylation activation pathway of a carboxylate-based Iron MOF is reported; cluster and gas sorption changes are characterized.

Authors:
ORCiD logo [1];  [1];  [2]; ORCiD logo [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1];  [1];  [1];  [3]; ORCiD logo [4]; ORCiD logo [5]
  1. Department of Chemistry, Texas A&M University, College Station, USA
  2. Department of Biochemistry and Biophysics, Texas A&M University, College Station, USA
  3. Framergy Inc. College Station, USA
  4. Department of Chemistry, Texas A&M University, College Station, USA, Department of Biochemistry and Biophysics
  5. Department of Chemistry, Texas A&M University, College Station, USA, Department of Materials Science and Engineering
Publication Date:
Sponsoring Org.:
USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1567713
Grant/Contract Number:  
FE0026472; SC0001015
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 55 Journal Issue: 85; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Drake, Hannah F., Day, Gregory S., Vali, Shaik Waseem, Xiao, Zhifeng, Banerjee, Sayan, Li, Jialuo, Joseph, Elizabeth A., Kuszynski, Jason E., Perry, Zachary T., Kirchon, Angelo, Ozdemir, Osman K., Lindahl, Paul A., and Zhou, Hong-Cai. The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC04555D.
Drake, Hannah F., Day, Gregory S., Vali, Shaik Waseem, Xiao, Zhifeng, Banerjee, Sayan, Li, Jialuo, Joseph, Elizabeth A., Kuszynski, Jason E., Perry, Zachary T., Kirchon, Angelo, Ozdemir, Osman K., Lindahl, Paul A., & Zhou, Hong-Cai. The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework. United Kingdom. doi:10.1039/C9CC04555D.
Drake, Hannah F., Day, Gregory S., Vali, Shaik Waseem, Xiao, Zhifeng, Banerjee, Sayan, Li, Jialuo, Joseph, Elizabeth A., Kuszynski, Jason E., Perry, Zachary T., Kirchon, Angelo, Ozdemir, Osman K., Lindahl, Paul A., and Zhou, Hong-Cai. Tue . "The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework". United Kingdom. doi:10.1039/C9CC04555D.
@article{osti_1567713,
title = {The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework},
author = {Drake, Hannah F. and Day, Gregory S. and Vali, Shaik Waseem and Xiao, Zhifeng and Banerjee, Sayan and Li, Jialuo and Joseph, Elizabeth A. and Kuszynski, Jason E. and Perry, Zachary T. and Kirchon, Angelo and Ozdemir, Osman K. and Lindahl, Paul A. and Zhou, Hong-Cai},
abstractNote = {The thermally generatable decarboxylation activation pathway of a carboxylate-based Iron MOF is reported; cluster and gas sorption changes are characterized.},
doi = {10.1039/C9CC04555D},
journal = {ChemComm},
number = 85,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9CC04555D

Citation Metrics:
Cited by: 1 work
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Works referenced in this record:

Iron( iii ) metal–organic frameworks as solid Lewis acids for the isomerization of α-pinene oxide
journal, January 2012

  • Dhakshinamoorthy, Amarajothi; Alvaro, Mercedes; Chevreau, Hubert
  • Catal. Sci. Technol., Vol. 2, Issue 2
  • DOI: 10.1039/C2CY00376G

From fundamentals to applications: a toolbox for robust and multifunctional MOF materials
journal, January 2018

  • Kirchon, Angelo; Feng, Liang; Drake, Hannah F.
  • Chemical Society Reviews, Vol. 47, Issue 23
  • DOI: 10.1039/C8CS00688A

Ab Initio Study of the Adsorption of Small Molecules on Metal–Organic Frameworks with Oxo-centered Trimetallic Building Units: The Role of the Undercoordinated Metal Ion
journal, August 2015


Effect of Fe open metal site in metal-organic frameworks on post-combustion CO 2 capture performance : Original Research Article: Effect of Fe open metal site in metal-organic frameworks
journal, December 2016

  • Wongsakulphasatch, Suwimol; Kiatkittipong, Worapon; Saupsor, Janenipa
  • Greenhouse Gases: Science and Technology, Vol. 7, Issue 2
  • DOI: 10.1002/ghg.1662

Gradual Release of Strongly Bound Nitric Oxide from Fe 2 (NO) 2 (dobdc)
journal, March 2015

  • Bloch, Eric D.; Queen, Wendy L.; Chavan, Sachin
  • Journal of the American Chemical Society, Vol. 137, Issue 10
  • DOI: 10.1021/ja5132243

Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal–Organic Frameworks
journal, January 2018

  • Feng, Liang; Yuan, Shuai; Zhang, Liang-Liang
  • Journal of the American Chemical Society, Vol. 140, Issue 6
  • DOI: 10.1021/jacs.7b12916

Metal-Organic Frameworks for Carbon Dioxide Capture and Methane Storage
journal, December 2016

  • Lin, Yichao; Kong, Chunglong; Zhang, Qiuju
  • Advanced Energy Materials, Vol. 7, Issue 4
  • DOI: 10.1002/aenm.201601296

Design of New Materials for Methane Storage
journal, March 2004

  • Düren, Tina; Sarkisov, Lev; Yaghi, Omar M.
  • Langmuir, Vol. 20, Issue 7, p. 2683-2689
  • DOI: 10.1021/la0355500

Fe-Based MOFs for Photocatalytic CO 2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways
journal, October 2014

  • Wang, Dengke; Huang, Renkun; Liu, Wenjun
  • ACS Catalysis, Vol. 4, Issue 12
  • DOI: 10.1021/cs501169t

Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
journal, March 2012


Grand Challenges and Future Opportunities for Metal–Organic Frameworks
journal, June 2017

  • Hendon, Christopher H.; Rieth, Adam J.; Korzyński, Maciej D.
  • ACS Central Science, Vol. 3, Issue 6
  • DOI: 10.1021/acscentsci.7b00197

Incorporating Heavy Alkanes in Metal–Organic Frameworks for Optimizing Adsorbed Natural Gas Capacity
journal, July 2018

  • Fang, Yu; Banerjee, Sayan; Joseph, Elizabeth A.
  • Chemistry – A European Journal, Vol. 24, Issue 64
  • DOI: 10.1002/chem.201804012

Direct accessibility of mixed-metal ( iii / ii ) acid sites through the rational synthesis of porous metal carboxylates
journal, January 2015

  • Wongsakulphasatch, S.; Nouar, F.; Rodriguez, J.
  • Chemical Communications, Vol. 51, Issue 50
  • DOI: 10.1039/C5CC02550H

Structures and H2 Adsorption Properties of Porous Scandium Metal-Organic Frameworks
journal, October 2010

  • Ibarra, Ilich A.; Lin, Xiang; Yang, Sihai
  • Chemistry - A European Journal, Vol. 16, Issue 46
  • DOI: 10.1002/chem.201000926

Metal–organic frameworks to satisfy gas upgrading demands: fine-tuning the soc -MOF platform for the operative removal of H 2 S
journal, January 2017

  • Belmabkhout, Youssef; Pillai, Renjith S.; Alezi, Dalal
  • Journal of Materials Chemistry A, Vol. 5, Issue 7
  • DOI: 10.1039/C6TA09406F

Efficient degradation of high concentration azo-dye wastewater by heterogeneous Fenton process with iron-based metal-organic framework
journal, May 2015


Systematic Engineering of Single Substitution in Zirconium Metal–Organic Frameworks toward High-Performance Catalysis
journal, December 2017

  • Huang, Ning; Yuan, Shuai; Drake, Hannah
  • Journal of the American Chemical Society, Vol. 139, Issue 51
  • DOI: 10.1021/jacs.7b09553

Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of M-BTT Metal–Organic Frameworks
journal, January 2013

  • Sumida, Kenji; Stück, David; Mino, Lorenzo
  • Journal of the American Chemical Society, Vol. 135, Issue 3, p. 1083-1091
  • DOI: 10.1021/ja310173e

Suspension Processing of Microporous Metal-Organic Frameworks: A Scalable Route to High-Quality Adsorbents
journal, July 2018