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Title: The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework

Abstract

The thermally generatable decarboxylation activation pathway of a carboxylate-based Iron MOF is reported; cluster and gas sorption changes are characterized.

Authors:
ORCiD logo [1];  [1];  [2]; ORCiD logo [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1];  [1];  [1];  [3]; ORCiD logo [4]; ORCiD logo [5]
  1. Department of Chemistry, Texas A&M University, College Station, USA
  2. Department of Biochemistry and Biophysics, Texas A&M University, College Station, USA
  3. Framergy Inc. College Station, USA
  4. Department of Chemistry, Texas A&M University, College Station, USA, Department of Biochemistry and Biophysics
  5. Department of Chemistry, Texas A&M University, College Station, USA, Department of Materials Science and Engineering
Publication Date:
Sponsoring Org.:
USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1567713
Grant/Contract Number:  
FE0026472; SC0001015
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 55 Journal Issue: 85; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Drake, Hannah F., Day, Gregory S., Vali, Shaik Waseem, Xiao, Zhifeng, Banerjee, Sayan, Li, Jialuo, Joseph, Elizabeth A., Kuszynski, Jason E., Perry, Zachary T., Kirchon, Angelo, Ozdemir, Osman K., Lindahl, Paul A., and Zhou, Hong-Cai. The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC04555D.
Drake, Hannah F., Day, Gregory S., Vali, Shaik Waseem, Xiao, Zhifeng, Banerjee, Sayan, Li, Jialuo, Joseph, Elizabeth A., Kuszynski, Jason E., Perry, Zachary T., Kirchon, Angelo, Ozdemir, Osman K., Lindahl, Paul A., & Zhou, Hong-Cai. The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework. United Kingdom. doi:10.1039/C9CC04555D.
Drake, Hannah F., Day, Gregory S., Vali, Shaik Waseem, Xiao, Zhifeng, Banerjee, Sayan, Li, Jialuo, Joseph, Elizabeth A., Kuszynski, Jason E., Perry, Zachary T., Kirchon, Angelo, Ozdemir, Osman K., Lindahl, Paul A., and Zhou, Hong-Cai. Tue . "The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework". United Kingdom. doi:10.1039/C9CC04555D.
@article{osti_1567713,
title = {The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework},
author = {Drake, Hannah F. and Day, Gregory S. and Vali, Shaik Waseem and Xiao, Zhifeng and Banerjee, Sayan and Li, Jialuo and Joseph, Elizabeth A. and Kuszynski, Jason E. and Perry, Zachary T. and Kirchon, Angelo and Ozdemir, Osman K. and Lindahl, Paul A. and Zhou, Hong-Cai},
abstractNote = {The thermally generatable decarboxylation activation pathway of a carboxylate-based Iron MOF is reported; cluster and gas sorption changes are characterized.},
doi = {10.1039/C9CC04555D},
journal = {ChemComm},
number = 85,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {10}
}

Journal Article:
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This content will become publicly available on September 24, 2020
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Works referenced in this record:

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Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of M-BTT Metal–Organic Frameworks
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