skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on September 20, 2020

Title: The good, the neutral, and the positive: buffer identity impacts CO 2 reduction activity by nickel( ii ) cyclam

Abstract

Electrocatalytic and light-driven CO 2 reduction by nickel cyclam is strongly dependent on the nature of the buffering agent.

Authors:
 [1];  [2]; ORCiD logo [3]
  1. Ohio State Biochemistry Program, The Ohio State University, Columbus, USA
  2. Department of Chemistry & Biochemistry, The Ohio State University, Columbus, USA
  3. Ohio State Biochemistry Program, The Ohio State University, Columbus, USA, Department of Chemistry & Biochemistry
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1566929
Grant/Contract Number:  
SC0018020
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Schneider, Camille R., Lewis, Luke C., and Shafaat, Hannah S. The good, the neutral, and the positive: buffer identity impacts CO 2 reduction activity by nickel( ii ) cyclam. United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT03114F.
Schneider, Camille R., Lewis, Luke C., & Shafaat, Hannah S. The good, the neutral, and the positive: buffer identity impacts CO 2 reduction activity by nickel( ii ) cyclam. United Kingdom. doi:10.1039/C9DT03114F.
Schneider, Camille R., Lewis, Luke C., and Shafaat, Hannah S. Tue . "The good, the neutral, and the positive: buffer identity impacts CO 2 reduction activity by nickel( ii ) cyclam". United Kingdom. doi:10.1039/C9DT03114F.
@article{osti_1566929,
title = {The good, the neutral, and the positive: buffer identity impacts CO 2 reduction activity by nickel( ii ) cyclam},
author = {Schneider, Camille R. and Lewis, Luke C. and Shafaat, Hannah S.},
abstractNote = {Electrocatalytic and light-driven CO 2 reduction by nickel cyclam is strongly dependent on the nature of the buffering agent.},
doi = {10.1039/C9DT03114F},
journal = {Dalton Transactions},
number = ,
volume = ,
place = {United Kingdom},
year = {2019},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on September 20, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Basic Research Needs: Catalysis for Energy
report, March 2008

  • Bell, Alexis T.; Gates, Bruce C.; Ray, Douglas
  • PNNL--17214
  • DOI: 10.2172/927492

Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials
journal, September 2011

  • Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R.
  • Science, Vol. 334, Issue 6056, p. 643-644
  • DOI: 10.1126/science.1209786

Low-pressure solubility of gases in liquid water
journal, April 1977

  • Wilhelm, Emmerich.; Battino, Rubin.; Wilcock, Robert J.
  • Chemical Reviews, Vol. 77, Issue 2, p. 219-262
  • DOI: 10.1021/cr60306a003

Reversible interconversion of carbon dioxide and formate by an electroactive enzyme
journal, July 2008

  • Reda, T.; Plugge, C. M.; Abram, N. J.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 31, p. 10654-10658
  • DOI: 10.1073/pnas.0801290105

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects
journal, July 2008

  • Savéant, Jean-Michel
  • Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378
  • DOI: 10.1021/cr068079z

Crystal Structure of Formate Dehydrogenase H: Catalysis Involving Mo, Molybdopterin, Selenocysteine, and an Fe4S4 Cluster
journal, February 1997

  • Boyington, Jeffrey C.; Gladyshev, Vadim N.; Khangulov, Sergei V.
  • Science, Vol. 275, Issue 5304, p. 1305-1308
  • DOI: 10.1126/science.275.5304.1305