Luminescence of Mn4+ in the Orthorhombic Perovskites, ASnO3 (A=Ca, Sr)

Srivastava, A. M.; Brik, M. G.; Comanzo, H. A.; Beers, W. W.; Cohen, W.; Cherepy, N.; Payne, S. A.

doi:10.1149/2.0132001JSS

Title: Luminescence of Mn⁴⁺ in the Orthorhombic Perovskites, ASnO₃ (A=Ca, Sr)

Abstract

The aim of this paper is to provide a comparative study of the spectroscopic properties of Mn⁴⁺ (3d³) ion in the orthorhombic perovskites, ASnO₃ (A=Ca, Sr). The most significant parameter controlling the energy of the zero-phonon line (²E→⁴A₂ transition) is the deviation of the octahedral O-Mn-O bond angle from the ideal 90⁰ value. It is significant that despite the longer Sn⁴⁺-O^2- bond distance, the crystal field strength (10 Dq) in CaSnO₃ is higher than that of SrSnO₃. We discuss this result in relation to the perovskite crystal chemistry. Mulliken population analysis and bond order calculation are made to clarify the nature of chemical bonding in the stannate perovskites.

Authors:

; Brik, M. G.; Comanzo, H. A.; Beers, W. W.; Cohen, W.; Cherepy, N.; Payne, S. A.

Publication Date:: Thu Sep 26 00:00:00 EDT 2019

Research Org.:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office; National Recruitment Program of High-end Foreign Experts; Programme for the Foreign Experts; Chongqing University of Posts and Telecommunications (CQUPT); Estonian Research Council; European Regional Development Fund (ERDF)

OSTI Identifier:: 1566901

Alternate Identifier(s):: OSTI ID: 1635082

Report Number(s):: LLNL-JRNL-808457
Journal ID: ISSN 2162-8769; /jss/9/1/016009.atom

Grant/Contract Number:: AC52-07NA27344; AC02-07CH11358; GDT20185200479; GDW20145200225; W2017011; PUT PRG111

Resource Type:: Published Article

Journal Name:: ECS Journal of Solid State Science and Technology

Additional Journal Information:: Journal Name: ECS Journal of Solid State Science and Technology Journal Volume: 9 Journal Issue: 1; Journal ID: ISSN 2162-8769

Publisher:: Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Srivastava, A. M., Brik, M. G., Comanzo, H. A., Beers, W. W., Cohen, W., Cherepy, N., and Payne, S. A. Luminescence of Mn4+ in the Orthorhombic Perovskites, ASnO3 (A=Ca, Sr).  United States: N. p., 2019. 
Web.  doi:10.1149/2.0132001JSS.

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                    Srivastava, A. M., Brik, M. G., Comanzo, H. A., Beers, W. W., Cohen, W., Cherepy, N., & Payne, S. A. Luminescence of Mn4+ in the Orthorhombic Perovskites, ASnO3 (A=Ca, Sr).  United States.  https://doi.org/10.1149/2.0132001JSS

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                    Srivastava, A. M., Brik, M. G., Comanzo, H. A., Beers, W. W., Cohen, W., Cherepy, N., and Payne, S. A. Thu .  
"Luminescence of Mn4+ in the Orthorhombic Perovskites, ASnO3 (A=Ca, Sr)".  United States.  https://doi.org/10.1149/2.0132001JSS.

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@article{osti_1566901,

  title        = {Luminescence of Mn4+ in the Orthorhombic Perovskites, ASnO3 (A=Ca, Sr)},

  author       = {Srivastava, A. M. and Brik, M. G. and Comanzo, H. A. and Beers, W. W. and Cohen, W. and Cherepy, N. and Payne, S. A.},

  abstractNote = {The aim of this paper is to provide a comparative study of the spectroscopic properties of Mn4+ (3d3) ion in the orthorhombic perovskites, ASnO3 (A=Ca, Sr). The most significant parameter controlling the energy of the zero-phonon line (2E→4A2 transition) is the deviation of the octahedral O-Mn-O bond angle from the ideal 900 value. It is significant that despite the longer Sn4+-O2- bond distance, the crystal field strength (10 Dq) in CaSnO3 is higher than that of SrSnO3. We discuss this result in relation to the perovskite crystal chemistry. Mulliken population analysis and bond order calculation are made to clarify the nature of chemical bonding in the stannate perovskites.},

  doi          = {10.1149/2.0132001JSS},

  journal      = {ECS Journal of Solid State Science and Technology},

  number       = 1,

  volume       = 9,

  place        = {United States},

  year         = {Thu Sep 26 00:00:00 EDT 2019},

  month        = {Thu Sep 26 00:00:00 EDT 2019}

}

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Cited by: 6 works

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Figure 1: The low temperature (T = 15 K) excitation spectra of Mn⁴⁺ in CaSnO₃ (λ_em = 695 nm; dashed blue line) and SrSnO₃ (λ_em = 702 nm; solid red line).

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Title: Luminescence of Mn4+ in the Orthorhombic Perovskites, ASnO3 (A=Ca, Sr)

Abstract

Citation Formats

Figures / Tables:

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Title: Luminescence of Mn⁴⁺ in the Orthorhombic Perovskites, ASnO₃ (A=Ca, Sr)

Structural and electronic relaxations around substitutional ${Cr}^{3 +}$ and ${Fe}^{3 +}$ ions in corundum
journal, March 2003

Mn4+ emission in pyrochlore oxides
journal, January 2015

Zero-phonon transitions and the Stokes shift of ${Mn}^{2 +}$ -doped perovskites: Dependence on the metal-ligand distance
journal, August 1994

Revisiting the Spectroscopy of the Bi ³⁺ Ion in Oxide Compounds
journal, April 2013

Effects of Eu ³⁺ Sites on Photoluminescence in Ba ₂ Ln(BO ₃ ) ₂ Cl (Ln = Gd, Y) Hosts
journal, November 2012

Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3
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The luminescence of tetravalent manganese in CaZrO3:Mn
journal, January 1981

Crystal field studies of the Mn4+ energy levels in the perovskite, LaAlO3
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Influence of Covalency on the Mn ^{4+ 2} E _g → ⁴ A _2g Emission Energy in Crystals
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Preparation and characterization of BaMnO3 and SrMnO3 polytypes
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Luminescence of Mn 4+ in the orthorhombic perovskite, LaGaO 3
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Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
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Pressure dependence of the ${}^{4}$ $T_{2}$ and ${}^{4}$ $T_{1}$ absorption bands of ruby to 35 GPa
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