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Title: Surface functionalization of polyoxovanadium clusters: generation of highly soluble charge carriers for nonaqueous energy storage

Journal Article · · ChemComm
DOI: https://doi.org/10.1039/C9CC05380H · OSTI ID:1566889
 [1];  [2];  [2]; ORCiD logo [1]
  1. Department of Chemistry, University of Rochester, Rochester, USA
  2. Sandia National Laboratories, Albuquerque, USA
+ Show Author Affiliations

Here, we demonstrate the effects of surface functionalization on a tunable series of nano-sized electron shuttles toward improving their function in nonaqueous energy storage.

Sponsoring Organization:
USDOE
Grant/Contract Number:
NA0003525
OSTI ID:
1566889
Journal Information:
ChemComm, Journal Name: ChemComm Vol. 55 Journal Issue: 81; ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 16 works
Citation information provided by
Web of Science

References (19)

Highly reduced and protonated aqueous solutions of [P2W18O62]6− for on-demand hydrogen generation and energy storage journal August 2018
Mechanism-Based Development of a Low-Potential, Soluble, and Cyclable Multielectron Anolyte for Nonaqueous Redox Flow Batteries journal November 2016
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Cost-driven materials selection criteria for redox flow battery electrolytes journal October 2016
Polyoxovanadate-alkoxide clusters as multi-electron charge carriers for symmetric non-aqueous redox flow batteries journal January 2018
Metal acetylacetonate complexes for high energy density non-aqueous redox flow batteries journal January 2015
Organic Functionalization of Polyoxovanadate–Alkoxide Clusters: Improving the Solubility of Multimetallic Charge Carriers for Nonaqueous Redox Flow Batteries journal November 2018
High current density, long duration cycling of soluble organic active species for non-aqueous redox flow batteries journal January 2016
Physicochemical implications of alkoxide “mixing” in polyoxovanadium clusters for nonaqueous energy storage journal January 2019
Heterometal functionalization yields improved energy density for charge carriers in nonaqueous redox flow batteries journal January 2018
A polyoxometalate flow battery journal August 2013
Neutral and Cationic V IV /V V Mixed-Valence Alkoxo-polyoxovanadium Clusters [V 6 O 7 (OR) 12 ] n + (R = −CH 3 , −C 2 H 5 ):  Structural, Cyclovoltammetric and IR-Spectroscopic Investigations on Mixed Valency in a Hexanuclear Core journal October 2005
Nonaqueous redox-flow batteries: organic solvents, supporting electrolytes, and redox pairs journal January 2015
Progress in the Design of Polyoxovanadate-Alkoxides as Charge Carriers for Nonaqueous Redox Flow Batteries journal March 2019
Consequences of ligand derivatization on the electronic properties of polyoxovanadate-alkoxide clusters journal March 2019
Electrochemical Properties of Keggin-Structure Polyoxometalates in Acetonitrile: Effects of Countercation, Heteroatom, and Framework Metal Exchange journal September 2016
Transport and Electron Transfer Kinetics of Polyoxovanadate-Alkoxide Clusters journal January 2019
Asymmetric polyoxometalate electrolytes for advanced redox flow batteries journal January 2018
Mixed-Metal, Structural, and Substitution Effects of Polyoxometalates on Electrochemical Behavior in a Redox Flow Battery journal August 2014

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