Near-field infrared spectroscopy of monolayer
Abstract
We measured the near-field infrared response of MnPS3 in bulk, few-, and single-layer form and compared our findings with traditional far-field vibrational spectroscopies, a symmetry analysis, and first-principles lattice dynamics calculations. Furthermore, trends in the Bu mode near 450cm–1 are striking, with the disappearance of this structure in the thinnest sheets. Combined with the amplified response of the activated Ag mode and analysis of the Au + Bu features, we find that symmetry is unexpectedly increased in few- and single-sheet MnPS3 due to a restoration of the threefold axes of rotation. Monoclinicity in this system is therefore a consequence of the long-range stacking pattern and temperature rather than local structure.
- Authors:
-
[2];
[1]
- Univ. of Tennessee, Knoxville, TN (United States)
- Rutgers Univ., Piscataway, NJ (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1566879
- Alternate Identifier(s):
- OSTI ID: 1558692
- Report Number(s):
- BNL-212141-2019-JAAM
Journal ID: ISSN 2469-9950; PRBMDO; TRN: US2001011
- Grant/Contract Number:
- SC0012704; FG02-01ER45885; AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 100; Journal Issue: 7; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Neal, Sabine N., Kim, Heung-Sik, Smith, Kevin A., Haglund, Amanda V., Mandrus, David G., Bechtel, Hans A., Carr, G. Lawrence, Haule, Kristjan, Vanderbilt, David, and Musfeldt, Janice L. Near-field infrared spectroscopy of monolayer MnPS3. United States: N. p., 2019.
Web. doi:10.1103/PhysRevB.100.075428.
Neal, Sabine N., Kim, Heung-Sik, Smith, Kevin A., Haglund, Amanda V., Mandrus, David G., Bechtel, Hans A., Carr, G. Lawrence, Haule, Kristjan, Vanderbilt, David, & Musfeldt, Janice L. Near-field infrared spectroscopy of monolayer MnPS3. United States. doi:10.1103/PhysRevB.100.075428.
Neal, Sabine N., Kim, Heung-Sik, Smith, Kevin A., Haglund, Amanda V., Mandrus, David G., Bechtel, Hans A., Carr, G. Lawrence, Haule, Kristjan, Vanderbilt, David, and Musfeldt, Janice L. Thu .
"Near-field infrared spectroscopy of monolayer MnPS3". United States. doi:10.1103/PhysRevB.100.075428. https://www.osti.gov/servlets/purl/1566879.
@article{osti_1566879,
title = {Near-field infrared spectroscopy of monolayer MnPS3},
author = {Neal, Sabine N. and Kim, Heung-Sik and Smith, Kevin A. and Haglund, Amanda V. and Mandrus, David G. and Bechtel, Hans A. and Carr, G. Lawrence and Haule, Kristjan and Vanderbilt, David and Musfeldt, Janice L.},
abstractNote = {We measured the near-field infrared response of MnPS3 in bulk, few-, and single-layer form and compared our findings with traditional far-field vibrational spectroscopies, a symmetry analysis, and first-principles lattice dynamics calculations. Furthermore, trends in the Bu mode near 450cm–1 are striking, with the disappearance of this structure in the thinnest sheets. Combined with the amplified response of the activated Ag mode and analysis of the Au + Bu features, we find that symmetry is unexpectedly increased in few- and single-sheet MnPS3 due to a restoration of the threefold axes of rotation. Monoclinicity in this system is therefore a consequence of the long-range stacking pattern and temperature rather than local structure.},
doi = {10.1103/PhysRevB.100.075428},
journal = {Physical Review B},
number = 7,
volume = 100,
place = {United States},
year = {2019},
month = {8}
}
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