How lasing happens in CsPbBr3 perovskite nanowires

Schlaus, Andrew P.; Spencer, Michael S.; Miyata, Kiyoshi; Liu, Fang; Wang, Xiaoxia; Datta, Ipshita; Lipson, Michal; Pan, Anlian; Zhu, X. -Y.

doi:10.1038/s41467-018-07972-7

Title: How lasing happens in CsPbBr₃ perovskite nanowires

Journal Article · 16 January 2019 · Nature Communications

DOI: https://doi.org/10.1038/s41467-018-07972-7 · OSTI ID:1566607

Schlaus, Andrew P. ^[1]; Spencer, Michael S. ^[1];

^[1]; Liu, Fang ^[1]; Wang, Xiaoxia ^[2];

^[1]; Lipson, Michal ^[1]; Pan, Anlian ^[2]; Zhu, X. -Y. ^[1]

Columbia Univ., New York, NY (United States)
Hunan Univ., Changsha (China)

Lead halide perovskites are emerging as an excellent material platform for optoelectronic processes. There have been extensive discussions on lasing, polariton formation, and nonlinear processes in this material system, but the underlying mechanism remains unknown. Here we probe lasing from CsPbBr₃ perovskite nanowires with picosecond (ps) time resolution and show that lasing originates from stimulated emission of an electron-hole plasma. We observe an anomalous blue-shifting of the lasing gain profile with time up to 25 ps, and assign this as a signature for lasing involving plasmon emission. The time domain view provides an ultra-sensitive probe of many-body physics which was obscured in previous time-integrated measurements of lasing from lead halide perovskite nanowires.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Programmable Quantum Materials (Pro-QM); Columbia Univ., New York, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: SC0010692; SC0019443

OSTI ID:: 1566607

Journal Information:: Nature Communications, Vol. 10, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 149 works

Citation information provided by
Web of Science

References (49)

Quantum Theory of the Optical and Electronic Properties of Semiconductors Haug, Hartmut; Koch, Stephan W. https://doi.org/10.1142/7184	book	January 2009
Hot-carrier cooling and photoinduced refractive index changes in organic–inorganic lead halide perovskites Price, Michael B.; Butkus, Justinas; Jellicoe, Tom C. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9420	journal	September 2015
Tunable polariton absorption of distributed feedback microcavities at room temperature Fujita, Tohru; Sato, Yoshihiro; Kuitani, Tetsuya Physical Review B, Vol. 57, Issue 19 https://doi.org/10.1103/PhysRevB.57.12428	journal	May 1998
Light–Matter Interactions in Cesium Lead Halide Perovskite Nanowire Lasers Park, Kidong; Lee, Jong Woon; Kim, Jun Dong The Journal of Physical Chemistry Letters, Vol. 7, Issue 18 https://doi.org/10.1021/acs.jpclett.6b01821	journal	September 2016
Experimental Demonstration of Correlated Flux Scaling in Photoconductivity and Photoluminescence of Lead-Halide Perovskites Yi, Hee Taek; Irkhin, Pavel; Joshi, Prakriti P. Physical Review Applied, Vol. 10, Issue 5 https://doi.org/10.1103/PhysRevApplied.10.054016	journal	November 2018
Semiconductor Optics Klingshirn, Claus https://doi.org/10.1007/978-3-540-38347-5	book	March 2007
Continuous-Wave Lasing in Cesium Lead Bromide Perovskite Nanowires Evans, Tyler J. S.; Schlaus, Andrew; Fu, Yongping Advanced Optical Materials, Vol. 6, Issue 2 https://doi.org/10.1002/adom.201700982	journal	December 2017
Semiconductor excitons in new light Koch, S. W.; Kira, M.; Khitrova, G. Nature Materials, Vol. 5, Issue 7 https://doi.org/10.1038/nmat1658	journal	July 2006
Room-Temperature Polariton Lasing in All-Inorganic Perovskite Nanoplatelets Su, Rui; Diederichs, Carole; Wang, Jun Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b01956	journal	May 2017
Metal halide perovskites for energy applications Zhang, Wei; Eperon, Giles E.; Snaith, Henry J. Nature Energy, Vol. 1, Issue 6 https://doi.org/10.1038/nenergy.2016.48	journal	May 2016
Review on the dynamics of semiconductor nanowire lasers Röder, Robert; Ronning, Carsten Semiconductor Science and Technology, Vol. 33, Issue 3 https://doi.org/10.1088/1361-6641/aaa7be	journal	February 2018
Ultrafast carrier thermalization in lead iodide perovskite probed with two-dimensional electronic spectroscopy Richter, Johannes M.; Branchi, Federico; Valduga de Almeida Camargo, Franco Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00546-z	journal	August 2017
UV polaritonic emission from a perovskite-based microcavity Lanty, G.; Lauret, J. S.; Deleporte, E. Applied Physics Letters, Vol. 93, Issue 8 https://doi.org/10.1063/1.2971206	journal	August 2008
65 years of ZnO research - old and very recent results Klingshirn, Claus; Fallert, J.; Zhou, H. physica status solidi (b), Vol. 247, Issue 6 https://doi.org/10.1002/pssb.200983195	journal	April 2010
Correlated electron–hole plasma in organometal perovskites Saba, Michele; Cadelano, Michele; Marongiu, Daniela Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6049	journal	September 2014
Bright triplet excitons in caesium lead halide perovskites Becker, Michael A.; Vaxenburg, Roman; Nedelcu, Georgian Nature, Vol. 553, Issue 7687 https://doi.org/10.1038/nature25147	journal	January 2018
Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors Zhu, Haiming; Fu, Yongping; Meng, Fei Nature Materials, Vol. 14, Issue 6 https://doi.org/10.1038/nmat4271	journal	April 2015
Entropy in halide perovskites Katan, Claudine; Mohite, Aditya D.; Even, Jacky Nature Materials, Vol. 17, Issue 5 https://doi.org/10.1038/s41563-018-0070-0	journal	April 2018
Lasing in robust cesium lead halide perovskite nanowires Eaton, Samuel W.; Lai, Minliang; Gibson, Natalie A. Proceedings of the National Academy of Sciences, Vol. 113, Issue 8 https://doi.org/10.1073/pnas.1600789113	journal	February 2016
Dispersion and line shape of plasmon satellites in one, two, and three dimensions Vigil-Fowler, Derek; Louie, Steven G.; Lischner, Johannes Physical Review B, Vol. 93, Issue 23 https://doi.org/10.1103/PhysRevB.93.235446	journal	June 2016
Low surface recombination velocity in solution-grown CH3NH3PbBr3 perovskite single crystal Yang, Ye; Yan, Yong; Yang, Mengjin Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8961	journal	August 2015
Nanowire Lasers of Formamidinium Lead Halide Perovskites and Their Stabilized Alloys with Improved Stability Fu, Yongping; Zhu, Haiming; Schrader, Alex W. Nano Letters, Vol. 16, Issue 2 https://doi.org/10.1021/acs.nanolett.5b04053	journal	January 2016
Slow hot carrier cooling in cesium lead iodide perovskites Shen, Qing; Ripolles, Teresa S.; Even, Jacky Applied Physics Letters, Vol. 111, Issue 15 https://doi.org/10.1063/1.4991993	journal	October 2017
Screening in crystalline liquids protects energetic carriers in hybrid perovskites Zhu, H.; Miyata, K.; Fu, Y. Science, Vol. 353, Issue 6306 https://doi.org/10.1126/science.aaf9570	journal	September 2016
Lead halide perovskites: Crystal-liquid duality, phonon glass electron crystals, and large polaron formation Miyata, Kiyoshi; Atallah, Timothy L.; Zhu, X. -Y. Science Advances, Vol. 3, Issue 10 https://doi.org/10.1126/sciadv.1701469	journal	October 2017
Quantum confinement of zero-dimensional hybrid organic-inorganic polaritons at room temperature Nguyen, H. S.; Han, Z.; Abdel-Baki, K. Applied Physics Letters, Vol. 104, Issue 8 https://doi.org/10.1063/1.4866606	journal	February 2014
Acoustic-optical phonon up-conversion and hot-phonon bottleneck in lead-halide perovskites Yang, Jianfeng; Wen, Xiaoming; Xia, Hongze Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14120	journal	January 2017
Broad Wavelength Tunable Robust Lasing from Single-Crystal Nanowires of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, I) Fu, Yongping; Zhu, Haiming; Stoumpos, Constantinos C. ACS Nano, Vol. 10, Issue 8 https://doi.org/10.1021/acsnano.6b03916	journal	July 2016
Organic Cations Might Not Be Essential to the Remarkable Properties of Band Edge Carriers in Lead Halide Perovskites Zhu, Haiming; Trinh, M. Tuan; Wang, Jue Advanced Materials, Vol. 29, Issue 1 https://doi.org/10.1002/adma.201603072	journal	October 2016
Room-temperature stimulated emission of ZnO: Alternatives to excitonic lasing Klingshirn, Claus; Hauschild, Robert; Fallert, Johannes Physical Review B, Vol. 75, Issue 11 https://doi.org/10.1103/PhysRevB.75.115203	journal	March 2007
Perovskite photonic sources Sutherland, Brandon R.; Sargent, Edward H. Nature Photonics, Vol. 10, Issue 5 https://doi.org/10.1038/nphoton.2016.62	journal	April 2016
Ultrafast screening and carrier dynamics in ZnO: Theory and experiment Versteegh, Marijn A. M.; Kuis, Tim; Stoof, H. T. C. Physical Review B, Vol. 84, Issue 3 https://doi.org/10.1103/PhysRevB.84.035207	journal	July 2011
Ferroelectric large polarons Miyata, Kiyoshi; Zhu, X. -Y. Nature Materials, Vol. 17, Issue 5 https://doi.org/10.1038/s41563-018-0068-7	journal	April 2018
Impact of the Halide Cage on the Electronic Properties of Fully Inorganic Cesium Lead Halide Perovskites Yang, Z.; Surrente, A.; Galkowski, K. ACS Energy Letters, Vol. 2, Issue 7 https://doi.org/10.1021/acsenergylett.7b00416	journal	June 2017
ZnO: Material, Physics and Applications Klingshirn, C. ChemPhysChem, Vol. 8, Issue 6 https://doi.org/10.1002/cphc.200700002	journal	April 2007
Determination of the exciton binding energy and effective masses for methylammonium and formamidinium lead tri-halide perovskite semiconductors Galkowski, Krzysztof; Mitioglu, Anatolie; Miyata, Atsuhiko Energy & Environmental Science, Vol. 9, Issue 3 https://doi.org/10.1039/C5EE03435C	journal	January 2016
Carrier density driven lasing dynamics in ZnO nanowires Wille, Marcel; Sturm, Chris; Michalsky, Tom Nanotechnology, Vol. 27, Issue 22 https://doi.org/10.1088/0957-4484/27/22/225702	journal	April 2016
Perovskite Materials for Light-Emitting Diodes and Lasers Veldhuis, Sjoerd A.; Boix, Pablo P.; Yantara, Natalia Advanced Materials, Vol. 28, Issue 32 https://doi.org/10.1002/adma.201600669	journal	May 2016
Hot carrier cooling mechanisms in halide perovskites Fu, Jianhui; Xu, Qiang; Han, Guifang Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01360-3	journal	November 2017
Observation of a hot-phonon bottleneck in lead-iodide perovskites Yang, Ye; Ostrowski, David P.; France, Ryan M. Nature Photonics, Vol. 10, Issue 1 https://doi.org/10.1038/nphoton.2015.213	journal	October 2015
Semiconductor Optics Klingshirn, Claus F. Graduate Texts in Physics https://doi.org/10.1007/978-3-642-28362-8	book	January 2012
Directional Growth of Ultralong CsPbBr ₃ Perovskite Nanowires for High-Performance Photodetectors Shoaib, Muhammad; Zhang, Xuehong; Wang, Xiaoxia Journal of the American Chemical Society, Vol. 139, Issue 44 https://doi.org/10.1021/jacs.7b08818	journal	October 2017
Semiconductor Optics Klingshirn, Claus Advanced Texts in Physics https://doi.org/10.1007/b138175	book	January 2005
Lead halide perovskites: Crystal-liquid duality, phonon glass electron crystals, and large polaron formation Miyata, Kiyoshi; Atallah, Timothy Luke; Zhu, Xiaoyang Columbia University https://doi.org/10.7916/d8281kg3	text	January 2017
Ultrafast carrier thermalization in lead iodide perovskite probed with two-dimensional electronic spectroscopy Richter, Johannes; Branchi, F.; Valduga De Almeida Camargo, F. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.11191	text	January 2017
Ultrafast screening and carrier dynamics in ZnO: Theory and experiment Versteegh, Marijn A. M.; Kuis, Tim; Stoof, H. T. C. arXiv https://doi.org/10.48550/arxiv.1012.3600	text	January 2010
Quantum confinement of zero-dimensional hybrid organic-inorganic polaritons at room temperature Nguyen, Hai Son; Han, Zheng; Abdel-Baki, Katia arXiv https://doi.org/10.48550/arxiv.1408.1438	text	January 2014
Carrier density driven lasing dynamics in ZnO nanowires Wille, Marcel; Sturm, Chris; Michalsky, Tom arXiv https://doi.org/10.48550/arxiv.1601.03866	text	January 2016
Dispersion and lineshape of plasmon satellites in one, two and three dimensions Vigil-Fower, Derek; Louie, Steven G.; Lischner, Johannes arXiv https://doi.org/10.48550/arxiv.1606.06619	text	January 2016

Cited By (11)

High‐Order Shift Current Induced Terahertz Emission from Inorganic Cesium Bromine Lead Perovskite Engendered by Two‐Photon Absorption He, Yuhang; Su, Rui; Huang, Yuanyuan Advanced Functional Materials, Vol. 29, Issue 40 https://doi.org/10.1002/adfm.201904694	journal	August 2019
Single‐Crystalline Perovskite Microlasers for High‐Contrast and Sub‐Diffraction Imaging Wang, Kaiyang; Wang, Shuai; Xiao, Shumin Advanced Functional Materials, Vol. 29, Issue 39 https://doi.org/10.1002/adfm.201904868	journal	July 2019
Continuous‐Wave Pumped Perovskite Lasers Mi, Yang; Zhong, Yangguang; Zhang, Qing Advanced Optical Materials, Vol. 7, Issue 17 https://doi.org/10.1002/adom.201900544	journal	June 2019
Structure and optical properties of perovskite-embedded dual-phase microcrystals synthesized by sonochemistry Cho, Sangyeon; Yun, Seok Hyun Communications Chemistry, Vol. 3, Issue 1 https://doi.org/10.1038/s42004-020-0265-6	journal	February 2020
Amplified spontaneous emission and random lasing using CsPbBr ₃ quantum dot glass through controlling crystallization Zhang, Huiling; Yuan, Lin; Chen, Ya Chemical Communications, Vol. 56, Issue 19 https://doi.org/10.1039/c9cc07676j	journal	January 2020
Active meta-optics and nanophotonics with halide perovskites Berestennikov, Alexander S.; Voroshilov, Pavel M.; Makarov, Sergey V. Applied Physics Reviews, Vol. 6, Issue 3 https://doi.org/10.1063/1.5107449	journal	September 2019
Lasing from reduced dimensional perovskite microplatelets: Fabry-Pérot or whispering-gallery-mode? Li, Qi; Li, Chun; Shang, Qiuyu The Journal of Chemical Physics, Vol. 151, Issue 21 https://doi.org/10.1063/1.5127946	journal	December 2019
Lead-Free Perovskites for Lighting and Lasing Applications: A Minireview Ushakova, Elena V.; Cherevkov, Sergei A.; Kuznetsova, Vera A. Materials, Vol. 12, Issue 23 https://doi.org/10.3390/ma12233845	journal	November 2019
Active meta-optics and nanophotonics with halide perovskites Berestennikov, Alexander S.; Voroshilov, Pavel M.; Makarov, Sergey V. arXiv https://doi.org/10.48550/arxiv.1906.05787	preprint	January 2019
Mixed halide perovskites for spectrally stable and high-efficiency blue light-emitting diodes Karlsson, Max; Yi, Ziyue; Reichert, Sebastian Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-020-20582-6	journal	January 2021
Lead-Free Perovskites for Lighting and Lasing Applications: A Minireview Ushakova, Elena V.; Cherevkov, Sergei A.; Kuznetsova, Vera A. Materials, Vol. 12, Issue 23 https://doi.org/10.3390/ma12233845	journal	November 2019

Similar Records

Continuous‐Wave Lasing in Cesium Lead Bromide Perovskite Nanowires

Journal Article · 2017 · Advanced Optical Materials · OSTI ID:1413827

Evans, Tyler J. S.; Schlaus, Andrew; Fu, Yongping; +6 more

Nanowire Lasers of Formamidinium Lead Halide Perovskites and Their Stabilized Alloys with Improved Stability

Journal Article · 2016 · Nano Letters · OSTI ID:1234264

Fu, Yongping; Zhu, Haiming; Schrader, Alex W.; +6 more

Lasing in robust cesium lead halide perovskite nanowires

Journal Article · 2016 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1237515

Eaton, Samuel W.; Lai, Minliang; Gibson, Natalie A.; +6 more

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
optics
defects
charge transport
superconductivity
magnetism and spin physics
mesoscale science
materials and chemistry by design
mesostructured materials
synthesis (novel materials)
synthesis (self-assembly)

Title: How lasing happens in CsPbBr3 perovskite nanowires

Citation Formats

References (49)

Cited By (11)

Similar Records

Related Subjects

Title: How lasing happens in CsPbBr₃ perovskite nanowires