DMOF-1 as a Representative MOF for SO2 Adsorption in Both Humid and Dry Conditions

Hungerford, Julian; Bhattacharyya, Souryadeep; Tumuluri, Uma; Nair, Sankar; Wu, Zili; Walton, Krista S.

doi:10.1021/acs.jpcc.8b06819

Title: DMOF-1 as a Representative MOF for SO₂ Adsorption in Both Humid and Dry Conditions

Journal Article · 20 September 2018 · Journal of Physical Chemistry. C

DOI: https://doi.org/10.1021/acs.jpcc.8b06819 · OSTI ID:1566518

Hungerford, Julian ^[1]; Bhattacharyya, Souryadeep ^[1]; Tumuluri, Uma ^[2];

^[1];

^[2];

^[1]

Georgia Inst. of Technology, Atlanta, GA (United States). School of Chemical & Biomolecular Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

The mixed-ligand metal–organic framework (MOF) DMOF-1 has been successfully synthesized via ligand: 2,3,5,6-tetramethylterephthalic acid (TM), 9,10-anthracenedicarboxylic acid (ADC), 1,4-naphthalenedicarboxylic acid (NDC), 2,5-dimethyl terephthalic acid (DM), and metal (Zn, Cu, Ni, Co) substitutions to develop structure–property relationships for adsorption of water and SO₂, an acid gas commonly found in flue gas streams at ppm-level concentrations. The substitution of bulky ligands, TM and ADC, resulted in not only improved water stability but also stability toward dry SO₂, whereas substitution with NDC and DM did not provide water or SO₂ stability. ADC-functionalized Zn–DMOF exhibited the greatest stability under humid SO₂ exposure of the ligand-functionalized materials that were tested. Metal substitution of Cu into the DMOF–TM structure resulted in the greatest stability of the M–DMOF–TM samples upon exposure to humid SO₂, and Ni–DMOF–TM provided the second most stable material. Finally, these results follow the prediction of the Irving–Williams series of metal node/ligand bond strengths.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME); Georgia Inst. of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012577

OSTI ID:: 1566518

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 41 Vol. 122; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: DMOF-1 as a Representative MOF for SO2 Adsorption in Both Humid and Dry Conditions

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Title: DMOF-1 as a Representative MOF for SO₂ Adsorption in Both Humid and Dry Conditions