Vapor deposition of a nonmesogen prepares highly structured organic glasses
Abstract
Significance Organic glasses are useful, versatile materials for current and future organic electronic technologies. They are nonequilibrium materials, so a single-component system can be processed in different ways to create a wide range of solids with diverse structural and optical properties. In this work, we use physical vapor deposition to prepare glasses with structure similar to that of an aligned smectic liquid crystal from a molecule that does not have any liquid crystal phases. This shows the potential to create highly structured glasses from a wide range of molecules.
- Authors:
-
[1];
[3];
- Department of Chemistry, University of Wisconsin–Madison, Madison, WI 53706,
- The National Institute of Standards and Technology, Gaithersburg, MD 20899,
- Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, CA 94025,
- Department of Chemistry, University of Wisconsin–Madison, Madison, WI 53706,, School of Pharmacy, University of Wisconsin–Madison, Madison, WI 53705
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1566219
- Grant/Contract Number:
- AC02-76SF00515
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 116 Journal Issue: 43; Journal ID: ISSN 0027-8424
- Publisher:
- Proceedings of the National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Bishop, Camille, Thelen, Jacob L., Gann, Eliot, Toney, Michael F., Yu, Lian, DeLongchamp, Dean M., and Ediger, M. D. Vapor deposition of a nonmesogen prepares highly structured organic glasses. United States: N. p., 2019.
Web. doi:10.1073/pnas.1908445116.
Bishop, Camille, Thelen, Jacob L., Gann, Eliot, Toney, Michael F., Yu, Lian, DeLongchamp, Dean M., & Ediger, M. D. Vapor deposition of a nonmesogen prepares highly structured organic glasses. United States. https://doi.org/10.1073/pnas.1908445116
Bishop, Camille, Thelen, Jacob L., Gann, Eliot, Toney, Michael F., Yu, Lian, DeLongchamp, Dean M., and Ediger, M. D. Mon .
"Vapor deposition of a nonmesogen prepares highly structured organic glasses". United States. https://doi.org/10.1073/pnas.1908445116.
@article{osti_1566219,
title = {Vapor deposition of a nonmesogen prepares highly structured organic glasses},
author = {Bishop, Camille and Thelen, Jacob L. and Gann, Eliot and Toney, Michael F. and Yu, Lian and DeLongchamp, Dean M. and Ediger, M. D.},
abstractNote = {Significance Organic glasses are useful, versatile materials for current and future organic electronic technologies. They are nonequilibrium materials, so a single-component system can be processed in different ways to create a wide range of solids with diverse structural and optical properties. In this work, we use physical vapor deposition to prepare glasses with structure similar to that of an aligned smectic liquid crystal from a molecule that does not have any liquid crystal phases. This shows the potential to create highly structured glasses from a wide range of molecules.},
doi = {10.1073/pnas.1908445116},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 43,
volume = 116,
place = {United States},
year = {2019},
month = {9}
}
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https://doi.org/10.1073/pnas.1908445116
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