NpSe2: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous-Valent Metal

Jin, Geng Bang; Malliakas, Christos D.; Hu, Yung‐Jin; Booth, Corwin H.; Ibers, James A.; Sokaras, D.; Weng, T. ‐C.; Skanthakumar, S.; Soderholm, L.

doi:10.1002/anie.201910353

Title: NpSe₂: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous-Valent Metal

Abstract

A new binary compound, NpSe₂, possesses metal-chalcogen and chalcogen-chalcogen interactions different from those reported for other metal dichalcogenides. Its structure is incommensurately modulated and features linear Se chains and valence-ambiguous Np cations.

Authors:

^[1];

^[1]; Hu, Yung‐Jin ^[1];

^[2]; Ibers, James A. ^[3]; Sokaras, D. ^[4]; Weng, T. ‐C. ^[4];

^[1];

^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Northwestern Univ., Evanston, IL (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)

Publication Date:: Mon Nov 04 00:00:00 EST 2019

Research Org.:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

OSTI Identifier:: 1647091

Alternate Identifier(s):: OSTI ID: 1566166; OSTI ID: 1633303

Grant/Contract Number:: AC02-76SF00515; AC02-05CH11231; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Angewandte Chemie (International Edition)

Additional Journal Information:: Journal Name: Angewandte Chemie (International Edition); Journal Volume: 58; Journal Issue: 45; Journal ID: ISSN 1433-7851

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; X-ray Emission Spectroscopy; X-ray diffraction; magnetism; modulated structure; neptunium; polyselenides

Citation Formats


                    Jin, Geng Bang, Malliakas, Christos D., Hu, Yung‐Jin, Booth, Corwin H., Ibers, James A., Sokaras, D., Weng, T. ‐C., Skanthakumar, S., and Soderholm, L. NpSe2: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous-Valent Metal.  United States: N. p., 2019. 
Web.  doi:10.1002/anie.201910353.

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                    Jin, Geng Bang, Malliakas, Christos D., Hu, Yung‐Jin, Booth, Corwin H., Ibers, James A., Sokaras, D., Weng, T. ‐C., Skanthakumar, S., & Soderholm, L. NpSe2: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous-Valent Metal.  United States.  https://doi.org/10.1002/anie.201910353

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                    Jin, Geng Bang, Malliakas, Christos D., Hu, Yung‐Jin, Booth, Corwin H., Ibers, James A., Sokaras, D., Weng, T. ‐C., Skanthakumar, S., and Soderholm, L. Mon .  
"NpSe2: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous-Valent Metal".  United States.  https://doi.org/10.1002/anie.201910353.  https://www.osti.gov/servlets/purl/1647091.

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@article{osti_1647091,

  title        = {NpSe2: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous-Valent Metal},

  author       = {Jin, Geng Bang and Malliakas, Christos D. and Hu, Yung‐Jin and Booth, Corwin H. and Ibers, James A. and Sokaras, D. and Weng, T. ‐C. and Skanthakumar, S. and Soderholm, L.},

  abstractNote = {A new binary compound, NpSe2, possesses metal-chalcogen and chalcogen-chalcogen interactions different from those reported for other metal dichalcogenides. Its structure is incommensurately modulated and features linear Se chains and valence-ambiguous Np cations.},

  doi          = {10.1002/anie.201910353},

  journal      = {Angewandte Chemie (International Edition)},

  number       = 45,

  volume       = 58,

  place        = {United States},

  year         = {Mon Nov 04 00:00:00 EST 2019},

  month        = {Mon Nov 04 00:00:00 EST 2019}

}

Copy to clipboard

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Title: NpSe2: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous-Valent Metal

Abstract

Citation Formats

Cu x UTe 3 : Stabilization of UTe 3 in the ZrSe 3 Structure Type via Copper Insertion. The Artifact of Te−Te Chains and Evidence for Distortions Due to Long Range Modulations journal, May 2001

Explicit periodic trend of van der Waals radii journal, November 1992

Thermodynamic Properties of Actinides and Actinide Compounds book, January 2010

Commensurate and incommensurate lattice distortions in dysprosium selenide (DySe1.84) and rubidium dysprosium selenide (Rb0.33DySe2.67) journal, July 1993

Structural and magnetic properties of the tetragonal actinide compounds journal, December 1987

The Chemistry of the Actinide and Transactinide Elements book, January 2011

Preparation et structures cristallines de quelques tellurures de neptunium journal, February 1974

Syntheses, Structures, Physical Properties, and Theoretical Study of LaCu 0.40 Te 2 , NdCu 0.37 Te 2 , SmCu 0.34 Te 2 , GdCu 0.33 Te 2 , and DyCu 0.32 Te 2 journal, January 2000

High-Resolution Study of X-Ray Resonant Raman Scattering at the K Edge of Silicon journal, August 2006

Three New Sodium Neptunyl(V) Selenate Hydrates: Structures, Raman Spectroscopy, and Magnetism journal, February 2012

Neptunium book, January 2008

CuTe: Remarkable Bonding Features as a Consequence of a Charge Density Wave journal, November 2012

Hypervalenzbindung in einer, zwei und drei Dimensionen: Erweiterung des Zintl-Klemm-Konzepts auf nichtklassische elektronenreiche Netze journal, July 2000

Coexistence and Coupling of Two Distinct Charge Density Waves in Sm 2 Te 5 journal, March 2008

Solid State Polyselenides and Polytellurides: A Large Variety of Se–Se and Te–Te Interactions journal, August 2009

The Chemistry of the Actinide and Transactinide Elements book, January 2006

Neptunium Thiophosphate Chemistry: Intermediate Behavior between Uranium and Plutonium journal, October 2011

Synthesis, Properties, and Complex Crystal Structure of Th 2 Se 5 journal, December 2012

Charge Density Wave and Narrow Energy Gap at Room Temperature in 2D Pb 3– x Sb 1+ x S 4 Te 2−δ with Square Te Sheets journal, August 2017

Syntheses, Structures, and Magnetic Properties of Np 3 S 5 and Np 3 Se 5 journal, February 2011

Charge Density Wave Caused by Reducing ThSe3 by One Electron. Superstructure and Short-Range Order in ATh2Se6 (A = K, Rb) Studied by X-ray Diffraction, Electron Diffraction, and Diffuse Scattering journal, October 1998

Transient Electronic Structure and Melting of a Charge Density Wave in TbTe3 journal, September 2008

XANES Spectroelectrochemistry: A New Method for Determining Formal Potentials journal, October 1999

Reinvestigation of Np 2 Se 5 : A Clear Divergence from Th 2 S 5 and Th 2 Se 5 in Chalcogen–Chalcogen and Metal–Chalcogen Interactions journal, July 2013

237 Np Mössbauer isomer shifts in neptunium chalcogenides journal, October 1984

Neptunium octupole and hexadecapole motifs in NpO 2 directly from electric dipole (E1) enhanced x-ray Bragg diffraction journal, June 2003

Structural data of the actinide elements and of their binary compounds with non-metallic elements journal, February 1987

CuTe - außergewöhnliche Bindungscharakteristika als Folge einer Ladungsdichtewelle journal, November 2012

Hypervalent Bonding in One, Two, and Three Dimensions: Extending the Zintl-Klemm Concept to Nonclassical Electron-Rich Networks journal, July 2000

Title: NpSe₂: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous-Valent Metal

Cu _x UTe ₃ : Stabilization of UTe ₃ in the ZrSe ₃ Structure Type via Copper Insertion. The Artifact of Te−Te Chains and Evidence for Distortions Due to Long Range Modulations
journal, May 2001

Explicit periodic trend of van der Waals radii
journal, November 1992

Thermodynamic Properties of Actinides and Actinide Compounds
book, January 2010

Commensurate and incommensurate lattice distortions in dysprosium selenide (DySe1.84) and rubidium dysprosium selenide (Rb0.33DySe2.67)
journal, July 1993

Structural and magnetic properties of the tetragonal actinide compounds
journal, December 1987

The Chemistry of the Actinide and Transactinide Elements
book, January 2011

Preparation et structures cristallines de quelques tellurures de neptunium
journal, February 1974

Syntheses, Structures, Physical Properties, and Theoretical Study of LaCu _0.40 Te ₂ , NdCu _0.37 Te ₂ , SmCu _0.34 Te ₂ , GdCu _0.33 Te ₂ , and DyCu _0.32 Te ₂
journal, January 2000

High-Resolution Study of X-Ray Resonant Raman Scattering at the $K$ Edge of Silicon
journal, August 2006

Three New Sodium Neptunyl(V) Selenate Hydrates: Structures, Raman Spectroscopy, and Magnetism
journal, February 2012

Neptunium
book, January 2008

CuTe: Remarkable Bonding Features as a Consequence of a Charge Density Wave
journal, November 2012

Hypervalenzbindung in einer, zwei und drei Dimensionen: Erweiterung des Zintl-Klemm-Konzepts auf nichtklassische elektronenreiche Netze
journal, July 2000

Coexistence and Coupling of Two Distinct Charge Density Waves in Sm ₂ Te ₅
journal, March 2008

Solid State Polyselenides and Polytellurides: A Large Variety of Se–Se and Te–Te Interactions
journal, August 2009

The Chemistry of the Actinide and Transactinide Elements
book, January 2006

Neptunium Thiophosphate Chemistry: Intermediate Behavior between Uranium and Plutonium
journal, October 2011

Synthesis, Properties, and Complex Crystal Structure of Th ₂ Se ₅
journal, December 2012

Charge Density Wave and Narrow Energy Gap at Room Temperature in 2D Pb _{3– x} Sb _{1+ x} S ₄ Te _2−δ with Square Te Sheets
journal, August 2017

Syntheses, Structures, and Magnetic Properties of Np ₃ S ₅ and Np ₃ Se ₅
journal, February 2011

Charge Density Wave Caused by Reducing ThSe₃ by One Electron. Superstructure and Short-Range Order in ATh₂Se₆ (A = K, Rb) Studied by X-ray Diffraction, Electron Diffraction, and Diffuse Scattering
journal, October 1998

Transient Electronic Structure and Melting of a Charge Density Wave in TbTe3
journal, September 2008

XANES Spectroelectrochemistry: A New Method for Determining Formal Potentials
journal, October 1999

Reinvestigation of Np ₂ Se ₅ : A Clear Divergence from Th ₂ S ₅ and Th ₂ Se ₅ in Chalcogen–Chalcogen and Metal–Chalcogen Interactions
journal, July 2013

237 Np Mössbauer isomer shifts in neptunium chalcogenides
journal, October 1984

Neptunium octupole and hexadecapole motifs in NpO ₂ directly from electric dipole (E1) enhanced x-ray Bragg diffraction
journal, June 2003

Structural data of the actinide elements and of their binary compounds with non-metallic elements
journal, February 1987

CuTe - außergewöhnliche Bindungscharakteristika als Folge einer Ladungsdichtewelle
journal, November 2012

Hypervalent Bonding in One, Two, and Three Dimensions: Extending the Zintl-Klemm Concept to Nonclassical Electron-Rich Networks
journal, July 2000