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Title: NpSe 2 : a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous‐Valent Metal

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3]; ORCiD logo [4];  [5];  [6];  [7]; ORCiD logo [3]; ORCiD logo [3]
  1. Chemical Sciences and Engineering Division Argonne National Laboratory Argonne IL 60439 USA, Current address: 3M Corporate Research Analytical Laboratory St. Paul MN 55144 USA
  2. Material Science Division Argonne National Laboratory Argonne IL 60439 USA, Current address: Northwestern University Evanston IL USA
  3. Chemical Sciences and Engineering Division Argonne National Laboratory Argonne IL 60439 USA
  4. Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley California 94720 USA
  5. Department of Chemistry Northwestern University Evanston IL 60208-3113 USA
  6. Stanford Synchrotron Radiation Lightsource SLAC National Accelerator Laboratory Menlo Park California 94025 USA
  7. Stanford Synchrotron Radiation Lightsource SLAC National Accelerator Laboratory Menlo Park California 94025 USA, Current address: HPSTAR 1690 Cailun Rd., Bldg. 6 Shanghai 201203 China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1566164
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 45; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Jin, Geng Bang, Malliakas, Christos D., Hu, Yung‐Jin, Booth, Corwin H., Ibers, James A., Sokaras, D., Weng, T. ‐C., Skanthakumar, S., and Soderholm, L. NpSe 2 : a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous‐Valent Metal. Germany: N. p., 2019. Web. doi:10.1002/ange.201910353.
Jin, Geng Bang, Malliakas, Christos D., Hu, Yung‐Jin, Booth, Corwin H., Ibers, James A., Sokaras, D., Weng, T. ‐C., Skanthakumar, S., & Soderholm, L. NpSe 2 : a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous‐Valent Metal. Germany. https://doi.org/10.1002/ange.201910353
Jin, Geng Bang, Malliakas, Christos D., Hu, Yung‐Jin, Booth, Corwin H., Ibers, James A., Sokaras, D., Weng, T. ‐C., Skanthakumar, S., and Soderholm, L. Tue . "NpSe 2 : a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous‐Valent Metal". Germany. https://doi.org/10.1002/ange.201910353.
@article{osti_1566164,
title = {NpSe 2 : a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous‐Valent Metal},
author = {Jin, Geng Bang and Malliakas, Christos D. and Hu, Yung‐Jin and Booth, Corwin H. and Ibers, James A. and Sokaras, D. and Weng, T. ‐C. and Skanthakumar, S. and Soderholm, L.},
abstractNote = {},
doi = {10.1002/ange.201910353},
journal = {Angewandte Chemie},
number = 45,
volume = 131,
place = {Germany},
year = {Tue Sep 24 00:00:00 EDT 2019},
month = {Tue Sep 24 00:00:00 EDT 2019}
}

Works referenced in this record:

Cu x UTe 3 :  Stabilization of UTe 3 in the ZrSe 3 Structure Type via Copper Insertion. The Artifact of Te−Te Chains and Evidence for Distortions Due to Long Range Modulations
journal, May 2001

  • Patschke, Rhonda; Breshears, Jean D.; Brazis, Paul
  • Journal of the American Chemical Society, Vol. 123, Issue 20
  • DOI: 10.1021/ja0042534

Explicit periodic trend of van der Waals radii
journal, November 1992


Commensurate and incommensurate lattice distortions in dysprosium selenide (DySe1.84) and rubidium dysprosium selenide (Rb0.33DySe2.67)
journal, July 1993

  • Foran, Brendan; Lee, Stephen; Aronson, Meigan C.
  • Chemistry of Materials, Vol. 5, Issue 7
  • DOI: 10.1021/cm00031a016

Structural and magnetic properties of the tetragonal actinide compounds
journal, December 1987


Preparation et structures cristallines de quelques tellurures de neptunium
journal, February 1974


Syntheses, Structures, Physical Properties, and Theoretical Study of LaCu 0.40 Te 2 , NdCu 0.37 Te 2 , SmCu 0.34 Te 2 , GdCu 0.33 Te 2 , and DyCu 0.32 Te 2
journal, January 2000

  • Huang, Fu Qiang; Brazis, Paul; Kannewurf, Carl R.
  • Journal of the American Chemical Society, Vol. 122, Issue 1
  • DOI: 10.1021/ja9919635

High-Resolution Study of X-Ray Resonant Raman Scattering at the K Edge of Silicon
journal, August 2006


Three New Sodium Neptunyl(V) Selenate Hydrates: Structures, Raman Spectroscopy, and Magnetism
journal, February 2012

  • Jin, Geng Bang; Skanthakumar, S.; Soderholm, L.
  • Inorganic Chemistry, Vol. 51, Issue 5
  • DOI: 10.1021/ic202703j

Neptunium
book, January 2008

  • Yoshida, Zenko; Johnson, Stephen G.; Kimura, Takaumi
  • The Chemistry of the Actinide and Transactinide Elements
  • DOI: 10.1007/1-4020-3598-5_6

Magnetic structure of UO 2 and NpO 2 by first-principle methods
journal, January 2019

  • Pegg, James T.; Shields, Ashley E.; Storr, Mark T.
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 2
  • DOI: 10.1039/C8CP03581D

CuTe: Remarkable Bonding Features as a Consequence of a Charge Density Wave
journal, November 2012

  • Stolze, Karoline; Isaeva, Anna; Nitsche, Fabian
  • Angewandte Chemie International Edition, Vol. 52, Issue 3
  • DOI: 10.1002/anie.201207333

Coexistence and Coupling of Two Distinct Charge Density Waves in Sm 2 Te 5
journal, March 2008

  • Malliakas, Christos D.; Iavarone, Maria; Fedor, Jan
  • Journal of the American Chemical Society, Vol. 130, Issue 11
  • DOI: 10.1021/ja7111405

Solid State Polyselenides and Polytellurides: A Large Variety of Se–Se and Te–Te Interactions
journal, August 2009


The Chemistry of the Actinide and Transactinide Elements
book, January 2006


Neptunium Thiophosphate Chemistry: Intermediate Behavior between Uranium and Plutonium
journal, October 2011

  • Jin, Geng Bang; Skanthakumar, S.; Haire, Richard G.
  • Inorganic Chemistry, Vol. 50, Issue 19
  • DOI: 10.1021/ic201493w

Synthesis, Properties, and Complex Crystal Structure of Th 2 Se 5
journal, December 2012

  • Bellott, Brian J.; Malliakas, Christos D.; Koscielski, Lukasz A.
  • Inorganic Chemistry, Vol. 52, Issue 2
  • DOI: 10.1021/ic302154p

Charge Density Wave and Narrow Energy Gap at Room Temperature in 2D Pb 3– x Sb 1+ x S 4 Te 2−δ with Square Te Sheets
journal, August 2017

  • Chen, Haijie; Malliakas, Christos D.; Narayan, Awadhesh
  • Journal of the American Chemical Society, Vol. 139, Issue 32
  • DOI: 10.1021/jacs.7b06446

Syntheses, Structures, and Magnetic Properties of Np 3 S 5 and Np 3 Se 5
journal, February 2011

  • Jin, Geng Bang; Skanthakumar, S.; Haire, Richard G.
  • Inorganic Chemistry, Vol. 50, Issue 3
  • DOI: 10.1021/ic101915x

Charge Density Wave Caused by Reducing ThSe3 by One Electron. Superstructure and Short-Range Order in ATh2Se6 (A = K, Rb) Studied by X-ray Diffraction, Electron Diffraction, and Diffuse Scattering
journal, October 1998

  • Choi, Kyoung-Shin; Patschke, Rhonda; Billinge, Simon J. L.
  • Journal of the American Chemical Society, Vol. 120, Issue 41, p. 10706-10714
  • DOI: 10.1021/ja981675t

Transient Electronic Structure and Melting of a Charge Density Wave in TbTe3
journal, September 2008


XANES Spectroelectrochemistry:  A New Method for Determining Formal Potentials
journal, October 1999

  • Soderholm, L.; Antonio, Mark R.; Williams, Clayton
  • Analytical Chemistry, Vol. 71, Issue 20
  • DOI: 10.1021/ac990080t

Reinvestigation of Np 2 Se 5 : A Clear Divergence from Th 2 S 5 and Th 2 Se 5 in Chalcogen–Chalcogen and Metal–Chalcogen Interactions
journal, July 2013

  • Jin, Geng Bang; Hu, Yung-Jin; Bellott, Brian
  • Inorganic Chemistry, Vol. 52, Issue 15
  • DOI: 10.1021/ic401384t

237 Np Mössbauer isomer shifts in neptunium chalcogenides
journal, October 1984

  • Thévenin, T.; Jové, J.; Pagès, M.
  • Hyperfine Interactions, Vol. 20, Issue 3
  • DOI: 10.1007/BF02073561

Neptunium octupole and hexadecapole motifs in NpO 2 directly from electric dipole (E1) enhanced x-ray Bragg diffraction
journal, June 2003


Structural data of the actinide elements and of their binary compounds with non-metallic elements
journal, February 1987


CuTe - außergewöhnliche Bindungscharakteristika als Folge einer Ladungsdichtewelle
journal, November 2012

  • Stolze, Karoline; Isaeva, Anna; Nitsche, Fabian
  • Angewandte Chemie, Vol. 125, Issue 3
  • DOI: 10.1002/ange.201207333