skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on July 8, 2020

Title: 31P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues

Abstract

Complexation of nitric acid by ligands containing conjugated aromatic phosphine oxide functionalities affords activated radioprotection through quenching n-dodecane excited states originating from gamma radiolysis.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [1]
  1. Idaho National Lab. (INL), Idaho Falls, ID (United States)
  2. Western Michigan Univ., Kalamazoo MI (United States)
  3. Valparaiso Univ., IN (United States)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States)
  5. California State Univ. (CalState), Long Beach, CA (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States); Idaho National Lab. (INL), Idaho Falls, ID (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1566070
Alternate Identifier(s):
OSTI ID: 1543412; OSTI ID: 1544591
Report Number(s):
BNL-211907-2019-JAAM; INL/JOU-19-55534-Rev000
Journal ID: ISSN 1477-9226; ICHBD9
Grant/Contract Number:  
SC0012704; AC07-05ID14517; FC02-04ER15533; NE0008406
Resource Type:
Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 48; Journal Issue: 30; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; CMPO; Gamma Radiation; Activated Radioprotection

Citation Formats

Horne, Gregory P., Kiddle, James J., Zarzana, Christopher A., Rae, Cathy, Peller, Julie R., Cook, Andrew R., Mezyk, Stephen P., and Mincher, Bruce J. 31P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues. United States: N. p., 2019. Web. doi:10.1039/C9DT01950B.
Horne, Gregory P., Kiddle, James J., Zarzana, Christopher A., Rae, Cathy, Peller, Julie R., Cook, Andrew R., Mezyk, Stephen P., & Mincher, Bruce J. 31P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues. United States. doi:10.1039/C9DT01950B.
Horne, Gregory P., Kiddle, James J., Zarzana, Christopher A., Rae, Cathy, Peller, Julie R., Cook, Andrew R., Mezyk, Stephen P., and Mincher, Bruce J. Mon . "31P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues". United States. doi:10.1039/C9DT01950B.
@article{osti_1566070,
title = {31P NMR study of the activated radioprotection mechanism of octylphenyl- N , N -diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues},
author = {Horne, Gregory P. and Kiddle, James J. and Zarzana, Christopher A. and Rae, Cathy and Peller, Julie R. and Cook, Andrew R. and Mezyk, Stephen P. and Mincher, Bruce J.},
abstractNote = {Complexation of nitric acid by ligands containing conjugated aromatic phosphine oxide functionalities affords activated radioprotection through quenching n-dodecane excited states originating from gamma radiolysis.},
doi = {10.1039/C9DT01950B},
journal = {Dalton Transactions},
number = 30,
volume = 48,
place = {United States},
year = {2019},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on July 8, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Track effects in the radiolysis of aromatic liquids
journal, September 2012


Studies on hydrolysis and radiolysis of N,N,N′,N′-tetraoctyl-3-oxapentane-1,5-diamide
journal, January 2002


Radical production in the radiolysis of liquid benzene
journal, August 1999


Effect of Dissolved Gases on the Densities of Hydrocarbons
journal, November 1997

  • Ashcroft, Stanley J.; Isa, Mustafa Ben
  • Journal of Chemical & Engineering Data, Vol. 42, Issue 6
  • DOI: 10.1021/je9701588

Bond Rupture in the Radiolysis of n -Alkanes:  An Application of Gel Permeation Chromatography to Studies of Radical Scavenging by Iodine
journal, February 2000

  • Wojnarovits, Laszlo; Schuler, Robert H.
  • The Journal of Physical Chemistry A, Vol. 104, Issue 6
  • DOI: 10.1021/jp992933r

The Primary Photodynamics of Aqueous Nitrate:  Formation of Peroxynitrite
journal, December 2003

  • Madsen, Dorte; Larsen, Jane; Jensen, Svend Knak
  • Journal of the American Chemical Society, Vol. 125, Issue 50
  • DOI: 10.1021/ja030135f

Reduction potential of the nitrate radical in aqueous solution
journal, November 1992

  • Jiang, Pei Yun; Katsumura, Yosuke; Ishigure, Kenkichi
  • Inorganic Chemistry, Vol. 31, Issue 24
  • DOI: 10.1021/ic00050a038

Review Article: The Effects of Radiation Chemistry on Solvent Extraction 3: A Review of Actinide and Lanthanide Extraction
journal, December 2009

  • Mincher, Bruce J.; Modolo, Giuseppe; Mezyk, Stephen P.
  • Solvent Extraction and Ion Exchange, Vol. 27, Issue 5-6
  • DOI: 10.1080/07366290903114098

An NMR Study of the Structure of Carboxylate CMPO Complexes∗
journal, July 1987


Formation and Decay of the Triplet Excited State of Pyridine
journal, August 2006

  • Enomoto, Kazuyuki; LaVerne, Jay A.; Seki, Shu
  • The Journal of Physical Chemistry A, Vol. 110, Issue 32
  • DOI: 10.1021/jp0632539

Solvent effects on the reactivities of organometallic compounds
journal, February 1976


Deuterium isotope effects on 31 P NMR parameters: hydrogen bonding in a solid urea–phosphoric acid adduct
journal, January 1996

  • Lagier, Claudia M.; Apperley, David C.; Scheler, Ulrich
  • J. Chem. Soc., Faraday Trans., Vol. 92, Issue 24
  • DOI: 10.1039/FT9969205047

The Radiation Chemistry of CMPO: Part 2. Alpha Radiolysis
journal, January 2014

  • Mincher, Bruce J.; Mezyk, Stephen P.; Elias, Gracy
  • Solvent Extraction and Ion Exchange, Vol. 32, Issue 2
  • DOI: 10.1080/07366299.2013.850300

Hydrolytic and Radiolytic Degradation of Octyl(Phenyl)-N,N-Diiso-Butylcarbamoylmethylphosphine Oxide and Related Compounds
journal, January 1986


Role of the Low-Energy Excited States in the Radiolysis of Aromatic Liquids
journal, July 2011

  • Baidak, Aliaksandr; Badali, Matthew; LaVerne, Jay A.
  • The Journal of Physical Chemistry A, Vol. 115, Issue 26
  • DOI: 10.1021/jp202802a

Degradation of Truex-Dodecane Process Solvent
journal, January 1989

  • Nash, K. L.; Rickert, P. G.; Horwitz, E. P.
  • Solvent Extraction and Ion Exchange, Vol. 7, Issue 4
  • DOI: 10.1080/07360298908962330

A Comparison of the γ -Radiolysis of TODGA and T(EH)DGA Using UHPLC-ESI-MS Analysis
journal, March 2015

  • Zarzana, Christopher A.; Groenewold, Gary S.; Mincher, Bruce J.
  • Solvent Extraction and Ion Exchange, Vol. 33, Issue 5
  • DOI: 10.1080/07366299.2015.1012885

The acceptor number ? A quantitative empirical parameter for the electrophilic properties of solvents
journal, January 1975

  • Mayer, Ulrich; Gutmann, Viktor; Gerger, Wolfgang
  • Monatshefte f�r Chemie, Vol. 106, Issue 6
  • DOI: 10.1007/BF00913599

The role of organic solvent radical cations in separations ligand degradation
journal, November 2015

  • Mezyk, Stephen P.; Mincher, Bruce J.; Dhiman, Surajdevprakash B.
  • Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 3
  • DOI: 10.1007/s10967-015-4582-7

The Reactivity of the Nitrate Radical ( NO 3 ) in Aqueous and Organic Solutions : THE REACTIVITY OF THE NITRATE RADICAL IN AQUEOUS AND ORGANIC SOLUTIONS
journal, July 2017

  • Mezyk, Stephen P.; Cullen, Thomas D.; Rickman, Kimberly A.
  • International Journal of Chemical Kinetics, Vol. 49, Issue 9
  • DOI: 10.1002/kin.21103

NMR Quantification of Hydrogen-Bond-Activating Effects for Organocatalysts including Boronic Acids
journal, December 2018

  • Diemoz, Kayla M.; Franz, Annaliese K.
  • The Journal of Organic Chemistry, Vol. 84, Issue 3
  • DOI: 10.1021/acs.joc.8b02389

Beta-radiolysis of liquid benzene
journal, January 1964

  • Cherniak, E. A.; Collinson, E.; Dainton, F. S.
  • Transactions of the Faraday Society, Vol. 60
  • DOI: 10.1039/tf9646001408

Inhibition of Radiolytic Molecular Hydrogen Formation by Quenching of Excited State Water
journal, May 2017

  • Horne, Gregory P.; Pimblott, Simon M.; LaVerne, Jay A.
  • The Journal of Physical Chemistry B, Vol. 121, Issue 21
  • DOI: 10.1021/acs.jpcb.7b02775

Effect of pH on H 2 O 2 Production in the Radiolysis of Water
journal, February 2011

  • Roth, Olivia; LaVerne, Jay A.
  • The Journal of Physical Chemistry A, Vol. 115, Issue 5
  • DOI: 10.1021/jp1099927

Radiation chemical effects on radiochemistry: A review of examples important to nuclear power
journal, January 2009


Diamex Process for Minor Actinide Partitioning: Hydrolytic and Radiolytic Degradations of Malonamide Extractants
journal, June 2001

  • Berthon, L.; Morel, J. M.; Zorz, N.
  • Separation Science and Technology, Vol. 36, Issue 5-6
  • DOI: 10.1081/SS-100103616

Perchloric Acid and Its Salts: Very Powerful Catalysts in Organic Chemistry
journal, June 2010

  • Dalpozzo, Renato; Bartoli, Giuseppe; Sambri, Letizia
  • Chemical Reviews, Vol. 110, Issue 6
  • DOI: 10.1021/cr9003488

Behaviour of some organophosphorus(V) compounds in strongly acidic solvents. Part 2. Ph2P(O)OH, Ph2P(O)Cl, Ph3PO, Ph3PS, and MeP(O)-Cl2
journal, January 1982

  • Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.
  • Journal of the Chemical Society, Dalton Transactions, Issue 2
  • DOI: 10.1039/dt9820000465

Gamma-radiolytic stability of new methylated TODGA derivatives for minor actinide recycling
journal, January 2015

  • Galán, Hitos; Zarzana, Christopher A.; Wilden, Andreas
  • Dalton Transactions, Vol. 44, Issue 41
  • DOI: 10.1039/C5DT02484F

Combinations of Aromatic and Aliphatic Radiolysis
journal, September 2015

  • LaVerne, Jay A.; Dowling-Medley, Jennifer
  • The Journal of Physical Chemistry A, Vol. 119, Issue 40
  • DOI: 10.1021/acs.jpca.5b07414

Characterization of CMPO and its radiolysis products by direct infusion ESI-MS
journal, September 2012


Effect of Nitric Acid Distribution on Extraction Behavior of Trivalent F‐Elements in a TRUEX System
journal, July 2006

  • Fujii, Toshiyuki; Aoki, Kansui; Yamana, Hajimu
  • Solvent Extraction and Ion Exchange, Vol. 24, Issue 3
  • DOI: 10.1080/07366290600647002

Radiation resistance of a series of organophosphorus extractants
journal, January 2006


Molecular Hydrogen Yields from the α-Self-Radiolysis of Nitric Acid Solutions Containing Plutonium or Americium
journal, February 2018

  • Gregson, Colin R.; Horne, Gregory P.; Orr, Robin M.
  • The Journal of Physical Chemistry B, Vol. 122, Issue 9
  • DOI: 10.1021/acs.jpcb.7b12267

Determination of CMPO using HPLC–UV
journal, June 2012


The Radiation Chemistry of CMPO: Part 1. Gamma Radiolysis
journal, September 2013

  • Mincher, Bruce J.; Mezyk, Stephen P.; Elias, Gracy
  • Solvent Extraction and Ion Exchange, Vol. 31, Issue 7
  • DOI: 10.1080/07366299.2013.815491

THE EXTRACTION OF Am(III) FROM NITRIC ACID BY OCTYL(PHENYL)-N,N-DIISOBUTYLCARBAMOYLMETHYLPHOSPHINE OXIDE - TRI-n-BUTYL PHOSPHATE MIXTURES
journal, April 1984


Studies of geminate ion recombination and formation of excited states in liquid n-dodecane by means of a new picosecond pulse radiolysis system
journal, March 1993

  • Yoshida, Y.; Ueda, T.; Kobayashi, T.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 327, Issue 1
  • DOI: 10.1016/0168-9002(93)91405-C

Review Article: The Effects of Radiation Chemistry on Solvent Extraction: 1. Conditions in Acidic Solution and a Review of TBP Radiolysis
journal, January 2009

  • Mincher, Bruce J.; Modolo, Giuseppe; Mezyk, Stephen P.
  • Solvent Extraction and Ion Exchange, Vol. 27, Issue 1
  • DOI: 10.1080/07366290802544767

Radiation protection effects by addition of aromatic compounds to n-dodecane
journal, July 2001


Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution
journal, July 1988

  • Neta, P.; Huie, Robert E.; Ross, Alberta B.
  • Journal of Physical and Chemical Reference Data, Vol. 17, Issue 3
  • DOI: 10.1063/1.555808

Hydrolytic and Radiolytic Degradation of Oφd(iB)Cmpo: Continuing Studies
journal, October 1988

  • Nash, K. L.; Gatrone, R. C.; Clark, G. A.
  • Separation Science and Technology, Vol. 23, Issue 12-13
  • DOI: 10.1080/01496398808075635

Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O in Aqueous Solution
journal, April 1988

  • Buxton, George V.; Greenstock, Clive L.; Helman, W. Phillips
  • Journal of Physical and Chemical Reference Data, Vol. 17, Issue 2
  • DOI: 10.1063/1.555805

The Oxidation of Fe ++ to Fe +++ by the Irradiation with X‐Rays of Solutions of Ferrous Sulfate in Sulfuric Acid
journal, January 1935

  • Fricke, Hugo; Hart, Edwin J.
  • The Journal of Chemical Physics, Vol. 3, Issue 1
  • DOI: 10.1063/1.1749558

Considerations for choice of a kinetic fig. of merit in process radiation chemistry for waste treatment
journal, February 2000