Effect of Chloride Oxidation on Local Electric Fields in Microelectrochemical Systems

doi:10.1002/celc.201901402

Title: Effect of Chloride Oxidation on Local Electric Fields in Microelectrochemical Systems

Authors:

Davies, Collin D. ^[1]; Johnson, Sarah E. ^[1];

^[1]

Department of Chemistry and Texas Materials InstituteThe University of Texas at Austin 105 E. 24th St., Stop A5300 Austin, Texas 78712-1224 U.S.A.

Publication Date:: 2019-09-23

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1565992

Grant/Contract Number:: FG02-06ER15758

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: ChemElectroChem

Additional Journal Information:: Journal Name: ChemElectroChem Journal Volume: 6 Journal Issue: 18; Journal ID: ISSN 2196-0216

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Davies, Collin D., Johnson, Sarah E., and Crooks, Richard M. Effect of Chloride Oxidation on Local Electric Fields in Microelectrochemical Systems.  Germany: N. p., 2019. 
        Web.  doi:10.1002/celc.201901402.

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                    Davies, Collin D., Johnson, Sarah E., & Crooks, Richard M. Effect of Chloride Oxidation on Local Electric Fields in Microelectrochemical Systems.  Germany.  doi:10.1002/celc.201901402.

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                    Davies, Collin D., Johnson, Sarah E., and Crooks, Richard M. Mon .  
        "Effect of Chloride Oxidation on Local Electric Fields in Microelectrochemical Systems".  Germany.  doi:10.1002/celc.201901402.

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@article{osti_1565992,

  title        = {Effect of Chloride Oxidation on Local Electric Fields in Microelectrochemical Systems},

  author       = {Davies, Collin D. and Johnson, Sarah E. and Crooks, Richard M.},

  abstractNote = {},

  doi          = {10.1002/celc.201901402},

  journal      = {ChemElectroChem},

  number       = 18,

  volume       = 6,

  place        = {Germany},

  year         = {2019},

  month        = {9}

}

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DOI: 10.1002/celc.201901402

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Title: Effect of Chloride Oxidation on Local Electric Fields in Microelectrochemical Systems

Citation Formats

Fabrication of microfluidic systems in poly(dimethylsiloxane) journal, January 2000

Numerical simulation of electrochemical desalination journal, April 2016

Contact Conductivity Detection in Poly(methyl methacylate)-Based Microfluidic Devices for Analysis of Mono- and Polyanionic Molecules journal, May 2002

Kinetics of Reversible Chlorine Hydrolysis: Temperature Dependence and General-Acid/Base-Assisted Mechanisms journal, March 1994

Scanning Electrochemical Microscopy, 52. Bipolar Conductance Technique at Ultramicroelectrodes for Resistance Measurements journal, December 2004

Experimental verification of simultaneous desalting and molecular preconcentration by ion concentration polarization journal, January 2017

Field Gradient Focusing: A Novel Method for Protein Separation journal, December 1996

Continuous Redirection and Separation of Microbeads by Faradaic Ion Concentration Polarization journal, June 2017

Oxidation of Chloride Ion on Platinum Electrode: Dynamics of Electrode Passivation and its Effect on Oxidation Kinetics journal, December 2011

The Kinetics of the Hydrolysis of Chlorine. i. Reinvestigation of the Hydrolysis in pure Water journal, November 1960

Electrochemical Desalination for a Sustainable Water Future journal, March 2014

On-line sample pre-concentration in microfluidic devices: A review journal, March 2012

A Compelling Case for Bipolar Electrochemistry journal, March 2016

Enrichment of Cations via Bipolar Electrode Focusing journal, August 2012

Open Circuit (Mixed) Potential Changes Upon Contact Between Different Inert Electrodes–Size and Kinetic Effects journal, December 2012

Micro-separation of fluid systems: A state-of-the-art review journal, December 2013

Multichannel Microchip Electrophoresis Device Fabricated in Polycarbonate with an Integrated Contact Conductivity Sensor Array journal, February 2007

Enhanced Salt Removal by Unipolar Ion Conduction in Ion Concentration Polarization Desalination journal, May 2016

Sample pre-concentration with high enrichment factors at a fixed location in paper-based microfluidic devices journal, January 2016

A review on recent developments for biomolecule separation at analytical scale using microfluidic devices journal, February 2016

Bipolar Electrochemistry journal, July 2013

Dual-channel bipolar electrode focusing: simultaneous separation and enrichment of both anions and cations journal, January 2012

Bipolar pulse technique for fast conductance measurements journal, March 1970

Ion concentration polarization in a single and open microchannel induced by a surface-patterned perm-selective film journal, January 2013

Double Layer Capacitance on Platinum in 1M H[sub 2]SO[sub 4] from the Reversible Hydrogen Potential to the Oxygen Formation Region journal, January 1969

Recent progress in chromogenic and fluorogenic chemosensors for hypochlorous acid journal, January 2016

Reaction kinetics in the absorption of chlorine into aqueous media journal, November 1962

Microscale electrodialysis: Concentration profiling and vortex visualization journal, January 2013

Recent advancements in ion concentration polarization journal, January 2016

Bipolar Electrode Focusing: The Effect of Current and Electric Field on Concentration Enrichment journal, December 2009

Redox Potential Measurement in Aqueous Solutions and Biological Media conference, January 2008

Tunable sheathless microfluidic focusing using ion concentration polarization journal, August 2015

Photoelectrochemical ion concentration polarization: membraneless ion filtration based on light-driven electrochemical reactions journal, January 2017

Bipolar electrode focusing: tuning the electric field gradient journal, January 2011

Electrokinetics in Microfluidic Channels Containing a Floating Electrode journal, August 2008

Shaping and exploring the micro- and nanoworld using bipolar electrochemistry journal, March 2011

Rapid Prototyping of Microfluidic Systems in Poly(dimethylsiloxane) journal, October 1998

Purification of High Salinity Brine by Multi-Stage Ion Concentration Polarization Desalination journal, August 2016

Label-Free Electrochemical Monitoring of Concentration Enrichment during Bipolar Electrode Focusing journal, September 2011

Electrochemically Mediated Seawater Desalination journal, June 2013

Microfluidic isotachophoresis: A review: Microfluidics and Miniaturization journal, May 2013

Voltammetric study of halide ion adsorption on platinum in perchloric acid solutions journal, December 1963

Bipolar electrochemistry—A wireless approach for electrode reactions journal, April 2017

Capacitive deionization on-chip as a method for microfluidic sample preparation journal, January 2015

Counter-flow gradient electrofocusing journal, February 2007

Bipolar electrode depletion: membraneless filtration of charged species using an electrogenerated electric field gradient journal, January 2011

Electrokinetic Trapping and Concentration Enrichment of DNA in a Microfluidic Channel journal, October 2003

Electric field gradient focusing journal, October 2005

Ion concentration polarization on paper-based microfluidic devices and its application to preconcentrate dilute sample solutions journal, January 2015

Bipolar Electrochemistry: From Materials Science to Motion and Beyond journal, May 2013

Increasing the Detection Sensitivity for DNA-Morpholino Hybridization in Sub-Nanomolar Regime by Enhancing the Surface Ion Conductance of PEDOT:PSS Membrane in a Microchannel journal, June 2016

Direct seawater desalination by ion concentration polarization journal, March 2010

Bipolar Electrode Focusing: Faradaic Ion Concentration Polarization journal, March 2011

Fabrication of microfluidic systems in poly(dimethylsiloxane)
journal, January 2000

Numerical simulation of electrochemical desalination
journal, April 2016

Contact Conductivity Detection in Poly(methyl methacylate)-Based Microfluidic Devices for Analysis of Mono- and Polyanionic Molecules
journal, May 2002

Kinetics of Reversible Chlorine Hydrolysis: Temperature Dependence and General-Acid/Base-Assisted Mechanisms
journal, March 1994

Scanning Electrochemical Microscopy, 52. Bipolar Conductance Technique at Ultramicroelectrodes for Resistance Measurements
journal, December 2004

Experimental verification of simultaneous desalting and molecular preconcentration by ion concentration polarization
journal, January 2017

Field Gradient Focusing: A Novel Method for Protein Separation
journal, December 1996

Continuous Redirection and Separation of Microbeads by Faradaic Ion Concentration Polarization
journal, June 2017

Oxidation of Chloride Ion on Platinum Electrode: Dynamics of Electrode Passivation and its Effect on Oxidation Kinetics
journal, December 2011

The Kinetics of the Hydrolysis of Chlorine. i. Reinvestigation of the Hydrolysis in pure Water
journal, November 1960

Electrochemical Desalination for a Sustainable Water Future
journal, March 2014

On-line sample pre-concentration in microfluidic devices: A review
journal, March 2012

A Compelling Case for Bipolar Electrochemistry
journal, March 2016

Enrichment of Cations via Bipolar Electrode Focusing
journal, August 2012

Open Circuit (Mixed) Potential Changes Upon Contact Between Different Inert Electrodes–Size and Kinetic Effects
journal, December 2012

Micro-separation of fluid systems: A state-of-the-art review
journal, December 2013

Multichannel Microchip Electrophoresis Device Fabricated in Polycarbonate with an Integrated Contact Conductivity Sensor Array
journal, February 2007

Enhanced Salt Removal by Unipolar Ion Conduction in Ion Concentration Polarization Desalination
journal, May 2016

Sample pre-concentration with high enrichment factors at a fixed location in paper-based microfluidic devices
journal, January 2016

A review on recent developments for biomolecule separation at analytical scale using microfluidic devices
journal, February 2016

Bipolar Electrochemistry
journal, July 2013

Dual-channel bipolar electrode focusing: simultaneous separation and enrichment of both anions and cations
journal, January 2012

Bipolar pulse technique for fast conductance measurements
journal, March 1970

Ion concentration polarization in a single and open microchannel induced by a surface-patterned perm-selective film
journal, January 2013

Double Layer Capacitance on Platinum in 1M H[sub 2]SO[sub 4] from the Reversible Hydrogen Potential to the Oxygen Formation Region
journal, January 1969

Recent progress in chromogenic and fluorogenic chemosensors for hypochlorous acid
journal, January 2016

Reaction kinetics in the absorption of chlorine into aqueous media
journal, November 1962

Microscale electrodialysis: Concentration profiling and vortex visualization
journal, January 2013

Recent advancements in ion concentration polarization
journal, January 2016

Bipolar Electrode Focusing: The Effect of Current and Electric Field on Concentration Enrichment
journal, December 2009

Redox Potential Measurement in Aqueous Solutions and Biological Media
conference, January 2008

Tunable sheathless microfluidic focusing using ion concentration polarization
journal, August 2015

Photoelectrochemical ion concentration polarization: membraneless ion filtration based on light-driven electrochemical reactions
journal, January 2017

Bipolar electrode focusing: tuning the electric field gradient
journal, January 2011

Electrokinetics in Microfluidic Channels Containing a Floating Electrode
journal, August 2008

Shaping and exploring the micro- and nanoworld using bipolar electrochemistry
journal, March 2011

Rapid Prototyping of Microfluidic Systems in Poly(dimethylsiloxane)
journal, October 1998

Purification of High Salinity Brine by Multi-Stage Ion Concentration Polarization Desalination
journal, August 2016

Label-Free Electrochemical Monitoring of Concentration Enrichment during Bipolar Electrode Focusing
journal, September 2011

Electrochemically Mediated Seawater Desalination
journal, June 2013

Microfluidic isotachophoresis: A review: Microfluidics and Miniaturization
journal, May 2013

Voltammetric study of halide ion adsorption on platinum in perchloric acid solutions
journal, December 1963

Bipolar electrochemistry—A wireless approach for electrode reactions
journal, April 2017

Capacitive deionization on-chip as a method for microfluidic sample preparation
journal, January 2015

Counter-flow gradient electrofocusing
journal, February 2007

Bipolar electrode depletion: membraneless filtration of charged species using an electrogenerated electric field gradient
journal, January 2011

Electrokinetic Trapping and Concentration Enrichment of DNA in a Microfluidic Channel
journal, October 2003

Electric field gradient focusing
journal, October 2005

Ion concentration polarization on paper-based microfluidic devices and its application to preconcentrate dilute sample solutions
journal, January 2015

Bipolar Electrochemistry: From Materials Science to Motion and Beyond
journal, May 2013

Increasing the Detection Sensitivity for DNA-Morpholino Hybridization in Sub-Nanomolar Regime by Enhancing the Surface Ion Conductance of PEDOT:PSS Membrane in a Microchannel
journal, June 2016

Direct seawater desalination by ion concentration polarization
journal, March 2010

Bipolar Electrode Focusing: Faradaic Ion Concentration Polarization
journal, March 2011