Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes

doi:10.1039/C9FD00041K

Title: Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes

Abstract

The details of ligand-induced backbonding in nickel diphosphine π complexes are explored using nickel L-edge (3d←2p) X-ray absorption spectroscopy as a means of quantifying the degree of backbonding derived from direct Ni 3d donation into the π ligand.

Authors:

^[1];

^[1]

The University of British Columbia, Department of Chemistry, Vancouver, Canada

Publication Date:: 2019-12-02

Sponsoring Org.:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

OSTI Identifier:: 1564507

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Faraday Discussions

Additional Journal Information:: Journal Name: Faraday Discussions Journal Volume: 220; Journal ID: ISSN 1359-6640

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    He, Weiying, and Kennepohl, Pierre. Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes.  United Kingdom: N. p., 2019. 
        Web.  doi:10.1039/C9FD00041K.

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                    He, Weiying, & Kennepohl, Pierre. Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes.  United Kingdom.  doi:10.1039/C9FD00041K.

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                    He, Weiying, and Kennepohl, Pierre. Mon .  
        "Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes".  United Kingdom.  doi:10.1039/C9FD00041K.

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@article{osti_1564507,

  title        = {Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes},

  author       = {He, Weiying and Kennepohl, Pierre},

  abstractNote = {The details of ligand-induced backbonding in nickel diphosphine π complexes are explored using nickel L-edge (3d←2p) X-ray absorption spectroscopy as a means of quantifying the degree of backbonding derived from direct Ni 3d donation into the π ligand.},

  doi          = {10.1039/C9FD00041K},

  journal      = {Faraday Discussions},

  number       = ,

  volume       = 220,

  place        = {United Kingdom},

  year         = {2019},

  month        = {12}

}

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DOI: 10.1039/C9FD00041K

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Title: Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes

Abstract

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