Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes
Abstract
The details of ligand-induced backbonding in nickel diphosphine π complexes are explored using nickel L-edge (3d←2p) X-ray absorption spectroscopy as a means of quantifying the degree of backbonding derived from direct Ni 3d donation into the π ligand.
- Authors:
-
- The University of British Columbia, Department of Chemistry, Vancouver, Canada
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1564507
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Faraday Discussions
- Additional Journal Information:
- Journal Name: Faraday Discussions Journal Volume: 220; Journal ID: ISSN 1359-6640
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
He, Weiying, and Kennepohl, Pierre. Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9FD00041K.
He, Weiying, & Kennepohl, Pierre. Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes. United Kingdom. https://doi.org/10.1039/C9FD00041K
He, Weiying, and Kennepohl, Pierre. Mon .
"Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes". United Kingdom. https://doi.org/10.1039/C9FD00041K.
@article{osti_1564507,
title = {Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes},
author = {He, Weiying and Kennepohl, Pierre},
abstractNote = {The details of ligand-induced backbonding in nickel diphosphine π complexes are explored using nickel L-edge (3d←2p) X-ray absorption spectroscopy as a means of quantifying the degree of backbonding derived from direct Ni 3d donation into the π ligand.},
doi = {10.1039/C9FD00041K},
journal = {Faraday Discussions},
number = ,
volume = 220,
place = {United Kingdom},
year = {2019},
month = {12}
}
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https://doi.org/10.1039/C9FD00041K
https://doi.org/10.1039/C9FD00041K
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Cited by: 2 works
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