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Title: Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes

Abstract

The details of ligand-induced backbonding in nickel diphosphine π complexes are explored using nickel L-edge (3d←2p) X-ray absorption spectroscopy as a means of quantifying the degree of backbonding derived from direct Ni 3d donation into the π ligand.

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. The University of British Columbia, Department of Chemistry, Vancouver, Canada
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)
OSTI Identifier:
1564507
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Faraday Discussions
Additional Journal Information:
Journal Name: Faraday Discussions Journal Volume: 220; Journal ID: ISSN 1359-6640
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

He, Weiying, and Kennepohl, Pierre. Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes. United Kingdom: N. p., 2019. Web. doi:10.1039/C9FD00041K.
He, Weiying, & Kennepohl, Pierre. Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes. United Kingdom. doi:10.1039/C9FD00041K.
He, Weiying, and Kennepohl, Pierre. Mon . "Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes". United Kingdom. doi:10.1039/C9FD00041K.
@article{osti_1564507,
title = {Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes},
author = {He, Weiying and Kennepohl, Pierre},
abstractNote = {The details of ligand-induced backbonding in nickel diphosphine π complexes are explored using nickel L-edge (3d←2p) X-ray absorption spectroscopy as a means of quantifying the degree of backbonding derived from direct Ni 3d donation into the π ligand.},
doi = {10.1039/C9FD00041K},
journal = {Faraday Discussions},
number = ,
volume = 220,
place = {United Kingdom},
year = {2019},
month = {12}
}

Journal Article:
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