Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes

He, Weiying; Kennepohl, Pierre

doi:10.1039/C9FD00041K

Title: Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes

Journal Article · 01 December 2019 · Faraday Discussions

DOI: https://doi.org/10.1039/C9FD00041K · OSTI ID:1564507

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The University of British Columbia, Department of Chemistry, Vancouver, Canada

The details of ligand-induced backbonding in nickel diphosphine π complexes are explored using nickel L-edge (3d←2p) X-ray absorption spectroscopy as a means of quantifying the degree of backbonding derived from direct Ni 3d donation into the π ligand.

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Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

OSTI ID:: 1564507

Journal Information:: Faraday Discussions, Journal Name: Faraday Discussions Vol. 220; ISSN 1359-6640; ISSN FDISE6

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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