The Role of Electrolyte in the First-Cycle Transformations of LiNi 0.6 Mn 0.2 Co 0.2 O 2

doi:10.1149/2.1561912jes

Title: The Role of Electrolyte in the First-Cycle Transformations of LiNi _0.6 Mn _0.2 Co _0.2 O ₂

Authors:

;

Publication Date:: 2019-08-16

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

OSTI Identifier:: 1564404

Grant/Contract Number:: DEAC02- 05CH11231

Resource Type:: Published Article

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Name: Journal of the Electrochemical Society Journal Volume: 166 Journal Issue: 13; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Renfrew, Sara E., and McCloskey, Bryan D. The Role of Electrolyte in the First-Cycle Transformations of LiNi 0.6 Mn 0.2 Co 0.2 O 2.  United States: N. p., 2019. 
        Web.  doi:10.1149/2.1561912jes.

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                    Renfrew, Sara E., & McCloskey, Bryan D. The Role of Electrolyte in the First-Cycle Transformations of LiNi 0.6 Mn 0.2 Co 0.2 O 2.  United States.  doi:10.1149/2.1561912jes.

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                    Renfrew, Sara E., and McCloskey, Bryan D. Fri .  
        "The Role of Electrolyte in the First-Cycle Transformations of LiNi 0.6 Mn 0.2 Co 0.2 O 2".  United States.  doi:10.1149/2.1561912jes.

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@article{osti_1564404,

  title        = {The Role of Electrolyte in the First-Cycle Transformations of LiNi 0.6 Mn 0.2 Co 0.2 O 2},

  author       = {Renfrew, Sara E. and McCloskey, Bryan D.},

  abstractNote = {},

  doi          = {10.1149/2.1561912jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 13,

  volume       = 166,

  place        = {United States},

  year         = {2019},

  month        = {8}

}

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DOI: 10.1149/2.1561912jes

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Citation Formats

The Impact of Electrolyte Additives Determined Using Isothermal Microcalorimetry journal, January 2013

Effect of electrolyte composition on rock salt surface degradation in NMC cathodes during high-voltage potentiostatic holds journal, January 2019

A Mild Surface Washing Method Using Protonated Polyaniline for Ni-rich LiNi 0.8 Co 0.1 Mn 0.1 O 2 Material of Lithium Ion Batteries journal, September 2017

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The Effect of CO 2 on Alkyl Carbonate Trans-Esterification during Formation of Graphite Electrodes in Li-Ion Batteries journal, January 2017

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Title: The Role of Electrolyte in the First-Cycle Transformations of LiNi _0.6 Mn _0.2 Co _0.2 O ₂

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journal, December 2014

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journal, January 2017

Effects of Solvent, Lithium Salt, and Temperature on Stability of Carbonate-Based Electrolytes for 5.0 V LiNi _0.5 Mn _1.5 O ₄ Electrode s
journal, November 2015

Singlet oxygen evolution from layered transition metal oxide cathode materials and its implications for lithium-ion batteries
journal, October 2018

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journal, March 2017

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journal, November 2011

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journal, October 2018

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journal, January 2019

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journal, March 1999

Temperature Dependence of Oxygen Release from LiNi _0.6 Mn _0.2 Co _0.2 O ₂ (NMC622) Cathode Materials for Li-Ion Batteries
journal, January 2018

SNIFTIRS investigation of the oxidative decomposition of organic-carbonate-based electrolytes for lithium-ion cells
journal, July 2000

Adsorption of ethylene carbonate on lithium cobalt oxide thin films: A synchrotron-based spectroscopic study of the surface chemistry
journal, November 2017

Singlet Oxygen Reactivity with Carbonate Solvents Used for Li-Ion Battery Electrolytes
journal, October 2018

Quantification of Surface Oxygen Depletion and Solid Carbonate Evolution on the First Cycle of LiNi _0.6 Mn _0.2 Co _0.2 O ₂ Electrodes
journal, April 2019

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries
journal, January 2017

The influence of water on the oxidation of propylene carbonate on platinum—an electrochemical, in situ FT-ir and on-line MS study
journal, January 1991

Influence of electrolyte additives on the cathode electrolyte interphase (CEI) formation on LiNi1/3Mn1/3Co1/3O2 in half cells with Li metal counter electrode
journal, October 2016

Fluoroethylene Carbonate and Vinylene Carbonate Reduction: Understanding Lithium-Ion Battery Electrolyte Additives and Solid Electrolyte Interphase Formation
journal, November 2016

Bisalt ether electrolytes: a pathway towards lithium metal batteries with Ni-rich cathodes
journal, January 2019

The Impact of Electrolyte Additives and Upper Cut-off Voltage on the Formation of a Rocksalt Surface Layer in LiNi _0.8 Mn _0.1 Co _0.1 O ₂ Electrodes
journal, January 2017

Residual Lithium Carbonate Predominantly Accounts for First Cycle CO ₂ and CO Outgassing of Li-Stoichiometric and Li-Rich Layered Transition-Metal Oxides
journal, November 2017

Depth-Dependent Redox Behavior of LiNi _0.6 Mn _0.2 Co _0.2 O ₂
journal, January 2018

Surface Structural and Chemical Evolution of Layered LiNi _0.8 Co _0.15 Al _0.05 O ₂ (NCA) under High Voltage and Elevated Temperature Conditions
journal, November 2018

Understanding the SEI Formation at Pristine Li-Ion Cathodes: Chemisorption and Reaction of DEC on LiCoO ₂ Surfaces Studied by a Combined SXPS/HREELS Approach
journal, October 2017

Interaction of Ultrathin Films of Ethylene Carbonate with Oxidized and Reduced Lithium Cobalt Oxide-A Model Study of the Cathode|Electrolyte Interface in Li-Ion Batteries
journal, December 2018

Effects of Cobalt Deficiency on Nickel-Rich Layered LiNi _0.8 Co _0.1 Mn _0.1 O ₂ Positive Electrode Materials for Lithium-Ion Batteries
journal, December 2018

Collapse of LiNi _{1– x – y} Co _x Mn _y O ₂ Lattice at Deep Charge Irrespective of Nickel Content in Lithium-Ion Batteries
journal, March 2019

Study of the Consumption of Vinylene Carbonate in Li[Ni _0.33 Mn _0.33 Co _0.33 ]O ₂ /Graphite Pouch Cells
journal, January 2014

Impact of Microcrack Generation and Surface Degradation on a Nickel-Rich Layered Li[Ni _0.9 Co _0.05 Mn _0.05 ]O ₂ Cathode for Lithium-Ion Batteries
journal, September 2017

A review of Ni-based layered oxides for rechargeable Li-ion batteries
journal, January 2017

Investigations on the electrochemical decomposition of the electrolyte additive vinylene carbonate in Li metal half cells and lithium ion full cells
journal, November 2016

Oxygen Release and Its Effect on the Cycling Stability of LiNi _x Mn _y Co _z O ₂ (NMC) Cathode Materials for Li-Ion Batteries
journal, January 2017

Microstructural Observation of LiNi _0.8 Co _0.15 Al _0.05 O ₂ after Charge and Discharge by Scanning Transmission Electron Microscopy
journal, January 2012

Electrochemical Oxidation of Lithium Carbonate Generates Singlet Oxygen
journal, April 2018

In Situ Analysis of Gas Generation in Lithium-Ion Batteries with Different Carbonate-Based Electrolytes
journal, October 2015

Solvents’ Critical Role in Nonaqueous Lithium–Oxygen Battery Electrochemistry
journal, May 2011

A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries
journal, January 2017

Combining Accurate O ₂ and Li ₂ O ₂ Assays to Separate Discharge and Charge Stability Limitations in Nonaqueous Li–O ₂ Batteries
journal, August 2013

Degradation mechanism of alkyl carbonate solvents used in lithium-ion cells during initial charging
journal, October 1997

Positive film-forming effect of fluoroethylene carbonate (FEC) on high-voltage cycling with three-electrode LiCoO2/Graphite pouch cell
journal, April 2018