Modularized Production of Value-Added Products and Fuels from Distributed Waste Carbon-Rich Feedstocks

Weber, Robert S.; Holladay, Johnathan E.

doi:10.1016/j.eng.2018.05.012

Title: Modularized Production of Value-Added Products and Fuels from Distributed Waste Carbon-Rich Feedstocks

Journal Article · 01 June 2018 · Engineering

DOI: https://doi.org/10.1016/j.eng.2018.05.012 · OSTI ID:1564371

Weber, Robert S. ^[1]; Holladay, Johnathan E. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Here, we have adapted and characterized electrolysis reactors to complement the conversion of regional- and community-scale quantities of waste into fuel or chemicals. The overall process must be able to contend with a wide range of feedstocks, must be inherently safe, and should not rely on external facilities for co-reactants or heat rejection and supply. Our current approach is based on the upgrading of bio-oil produced by the hydrothermal liquefaction (HTL) of carbon-containing waste feedstocks. HTL can convert a variety of feedstocks into a bio-oil that requires much less upgrading than the products of other ways of deconstructing biomass. We are now investigating the use of electrochemical processes for the further conversions needed to transform the bio-oil from HTL into fuel or higher value chemicals. We, and others, have shown that electrochemical reduction can offer adequate reaction rates and at least some of the necessary generality. In addition, an electrochemical reactor necessarily both oxidizes (removes electrons) on one side of the reactor and reduces (adds electrons) on the other side. Therefore, the two types of reactions could, in principle, be coupled to upgrade the bio-oil and simultaneously polish the water that is employed as a reactant and a carrier in the upstream HTL. Here, we overview a notional process, the possible conversion chemistry, and the economics of an HTL-electrochemical process.

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