Irradiation effects of medium-entropy alloy NiCoCr with and without pre-indentation

Lu, Chenyang; Yang, Tai-Ni; Jin, Ke; Velisa, Gihan; Xiu, Pengyuan; Peng, Qing; Gao, Fei; Zhang, Yanwen; Bei, Hongbin; Weber, William J.; Wang, Lumin

doi:10.1016/j.jnucmat.2019.06.020

Title: Irradiation effects of medium-entropy alloy NiCoCr with and without pre-indentation

Abstract

Medium entropy alloy NiCoCr draws great attention due to its excellent strength-ductility trade-off mechanical behavior. Its irradiation behavior at elevated temperatures has been investigated using ion beam irradiation in a temperature range of 420–580°C and transmission electron microscopy. Irradiation induced stacking fault tetrahedra were only observed at 420°C. With increasing irradiation temperature, all stacking fault tetrahedra vanished, while the size of voids and dislocation loops increased significantly. Nanoindentation-induced structural complexities, including dislocations, stacking faults and twins helped to reduce void swelling. However, at the elevated temperatures, NiCoCr is still much more susceptible to void swelling compared to high entropy alloys such as NiCoFeCrMn and NiCoFeCrPd.

Authors:

Lu, Chenyang ^[1]; Yang, Tai-Ni ^[1]; Jin, Ke ^[2];

^[2]; Xiu, Pengyuan ^[1];

^[1]; Gao, Fei ^[1]; Zhang, Yanwen ^[1];

^[2];

^[3]; Wang, Lumin ^[4]

Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Nuclear Engineering and Radiological Sciences
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Materials Science and Engineering
Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Nuclear Engineering and Radiological Sciences; Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Materials Science and Engineering

Publication Date:: 2019-10-01

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Energy Dissipation to Defect Evolution (EDDE); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1564113

Alternate Identifier(s):: OSTI ID: 1776023

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Nuclear Materials

Additional Journal Information:: Journal Volume: 524; Journal Issue: C; Journal ID: ISSN 0022-3115

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Medium entropy alloy; Void swelling; Structural complexity; Ion beam irradiation

Citation Formats


                    Lu, Chenyang, Yang, Tai-Ni, Jin, Ke, Velisa, Gihan, Xiu, Pengyuan, Peng, Qing, Gao, Fei, Zhang, Yanwen, Bei, Hongbin, Weber, William J., and Wang, Lumin. Irradiation effects of medium-entropy alloy NiCoCr with and without pre-indentation.  United States: N. p., 2019. 
Web.  doi:10.1016/j.jnucmat.2019.06.020.

Copy to clipboard


                    Lu, Chenyang, Yang, Tai-Ni, Jin, Ke, Velisa, Gihan, Xiu, Pengyuan, Peng, Qing, Gao, Fei, Zhang, Yanwen, Bei, Hongbin, Weber, William J., & Wang, Lumin. Irradiation effects of medium-entropy alloy NiCoCr with and without pre-indentation.  United States.  https://doi.org/10.1016/j.jnucmat.2019.06.020

Copy to clipboard


                    Lu, Chenyang, Yang, Tai-Ni, Jin, Ke, Velisa, Gihan, Xiu, Pengyuan, Peng, Qing, Gao, Fei, Zhang, Yanwen, Bei, Hongbin, Weber, William J., and Wang, Lumin. Tue .  
"Irradiation effects of medium-entropy alloy NiCoCr with and without pre-indentation".  United States.  https://doi.org/10.1016/j.jnucmat.2019.06.020.  https://www.osti.gov/servlets/purl/1564113.

Copy to clipboard


                    
@article{osti_1564113,

  title        = {Irradiation effects of medium-entropy alloy NiCoCr with and without pre-indentation},

  author       = {Lu, Chenyang and Yang, Tai-Ni and Jin, Ke and Velisa, Gihan and Xiu, Pengyuan and Peng, Qing and Gao, Fei and Zhang, Yanwen and Bei, Hongbin and Weber, William J. and Wang, Lumin},

  abstractNote = {Medium entropy alloy NiCoCr draws great attention due to its excellent strength-ductility trade-off mechanical behavior. Its irradiation behavior at elevated temperatures has been investigated using ion beam irradiation in a temperature range of 420–580°C and transmission electron microscopy. Irradiation induced stacking fault tetrahedra were only observed at 420°C. With increasing irradiation temperature, all stacking fault tetrahedra vanished, while the size of voids and dislocation loops increased significantly. Nanoindentation-induced structural complexities, including dislocations, stacking faults and twins helped to reduce void swelling. However, at the elevated temperatures, NiCoCr is still much more susceptible to void swelling compared to high entropy alloys such as NiCoFeCrMn and NiCoFeCrPd.},

  doi          = {10.1016/j.jnucmat.2019.06.020},

  journal      = {Journal of Nuclear Materials},

  number       = C,

  volume       = 524,

  place        = {United States},

  year         = {2019},

  month        = {10}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1016/j.jnucmat.2019.06.020

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 4 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Microstructural development in equiatomic multicomponent alloys
journal, July 2004

Cantor, B.; Chang, I. T. H.; Knight, P.
Materials Science and Engineering: A, Vol. 375-377
DOI: 10.1016/j.msea.2003.10.257

Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004

Yeh, J.-W.; Chen, S.-K.; Lin, S.-J.
Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303
DOI: 10.1002/adem.200300567

Relative effects of enthalpy and entropy on the phase stability of equiatomic high-entropy alloys
journal, April 2013

Otto, F.; Yang, Y.; Bei, H.
Acta Materialia, Vol. 61, Issue 7
DOI: 10.1016/j.actamat.2013.01.042

Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off
journal, May 2016

Li, Zhiming; Pradeep, Konda Gokuldoss; Deng, Yun
Nature, Vol. 534, Issue 7606
DOI: 10.1038/nature17981

A fracture-resistant high-entropy alloy for cryogenic applications
journal, September 2014

Gludovatz, B.; Hohenwarter, A.; Catoor, D.
Science, Vol. 345, Issue 6201
DOI: 10.1126/science.1254581

Radiation-induced segregation on defect clusters in single-phase concentrated solid-solution alloys
journal, April 2017

Lu, Chenyang; Yang, Taini; Jin, Ke
Acta Materialia, Vol. 127
DOI: 10.1016/j.actamat.2017.01.019

Microstructural stability and mechanical behavior of FeNiMnCr high entropy alloy under ion irradiation
journal, July 2016

Kumar, N. A. P. Kiran; Li, C.; Leonard, K. J.
Acta Materialia, Vol. 113
DOI: 10.1016/j.actamat.2016.05.007

Effects of temperature on the irradiation responses of Al0.1CoCrFeNi high entropy alloy
journal, February 2018

Yang, Tengfei; Xia, Songqin; Guo, Wei
Scripta Materialia, Vol. 144
DOI: 10.1016/j.scriptamat.2017.09.025

Atomic-level heterogeneity and defect dynamics in concentrated solid-solution alloys
journal, October 2017

Zhang, Yanwen; Zhao, Shijun; Weber, William J.
Current Opinion in Solid State and Materials Science, Vol. 21, Issue 5
DOI: 10.1016/j.cossms.2017.02.002

Mechanism of Radiation Damage Reduction in Equiatomic Multicomponent Single Phase Alloys
journal, April 2016

Granberg, F.; Nordlund, K.; Ullah, Mohammad W.
Physical Review Letters, Vol. 116, Issue 13
DOI: 10.1103/PhysRevLett.116.135504

Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures
journal, December 2014

Wu, Z.; Bei, H.; Pharr, G. M.
Acta Materialia, Vol. 81
DOI: 10.1016/j.actamat.2014.08.026

Reasons for the superior mechanical properties of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi
journal, April 2017

Laplanche, G.; Kostka, A.; Reinhart, C.
Acta Materialia, Vol. 128
DOI: 10.1016/j.actamat.2017.02.036

The evolution of the deformation substructure in a Ni-Co-Cr equiatomic solid solution alloy
journal, June 2017

Miao, J.; Slone, C. E.; Smith, T. M.
Acta Materialia, Vol. 132
DOI: 10.1016/j.actamat.2017.04.033

Dislocation mechanisms and 3D twin architectures generate exceptional strength-ductility-toughness combination in CrCoNi medium-entropy alloy
journal, February 2017

Zhang, Zijiao; Sheng, Hongwei; Wang, Zhangjie
Nature Communications, Vol. 8, Issue 1
DOI: 10.1038/ncomms14390

Influence of chemical disorder on energy dissipation and defect evolution in advanced alloys
journal, August 2016

Zhang, Yanwen; Jin, Ke; Xue, Haizhou
Journal of Materials Research, Vol. 31, Issue 16
DOI: 10.1557/jmr.2016.269

Effect of alloying elements on defect evolution in Ni-20X binary alloys
journal, June 2018

Yang, Tai-ni; Lu, Chenyang; Velisa, Gihan
Acta Materialia, Vol. 151
DOI: 10.1016/j.actamat.2018.03.054

Interstitial migration behavior and defect evolution in ion irradiated pure nickel and Ni-xFe binary alloys
journal, October 2018

Lu, Chenyang; Yang, Taini; Niu, Liangliang
Journal of Nuclear Materials, Vol. 509
DOI: 10.1016/j.jnucmat.2018.07.006

Tailoring the physical properties of Ni-based single-phase equiatomic alloys by modifying the chemical complexity
journal, February 2016

Jin, K.; Sales, B. C.; Stocks, G. M.
Scientific Reports, Vol. 6, Issue 1
DOI: 10.1038/srep20159

New ion beam materials laboratory for materials modification and irradiation effects research
journal, November 2014

Zhang, Y.; Crespillo, M. L.; Xue, H.
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 338
DOI: 10.1016/j.nimb.2014.07.028

Direct Observation of Defect Range and Evolution in Ion-Irradiated Single Crystalline Ni and Ni Binary Alloys
journal, February 2016

Lu, Chenyang; Jin, Ke; Béland, Laurent K.
Scientific Reports, Vol. 6, Issue 1
DOI: 10.1038/srep19994

Void swelling in high dose ion-irradiated reduced activation ferritic–martensitic steels
journal, July 2015

Wang, Xu; Monterrosa, Anthony M.; Zhang, Feifei
Journal of Nuclear Materials, Vol. 462
DOI: 10.1016/j.jnucmat.2015.03.050

Influence of irradiation temperature on void swelling in NiCoFeCrMn and NiCoFeCrPd
journal, January 2019

Yang, Tai-ni; Lu, Chenyang; Velisa, Gihan
Scripta Materialia, Vol. 158
DOI: 10.1016/j.scriptamat.2018.08.021

Enhanced void swelling in NiCoFeCrPd high-entropy alloy by indentation-induced dislocations
journal, August 2018

Lu, Chenyang; Yang, Taini; Jin, Ke
Materials Research Letters, Vol. 6, Issue 10
DOI: 10.1080/21663831.2018.1504136

Application of STEM characterization for investigating radiation effects in BCC Fe-based alloys
journal, April 2015

Parish, Chad M.; Field, Kevin G.; Certain, Alicia G.
Journal of Materials Research, Vol. 30, Issue 9
DOI: 10.1557/jmr.2015.32

Designing Radiation Resistance in Materials for Fusion Energy
journal, July 2014

Zinkle, S. J.; Snead, L. L.
Annual Review of Materials Research, Vol. 44, Issue 1
DOI: 10.1146/annurev-matsci-070813-113627

Similar Records in DOE PAGES and OSTI.GOV collections:

Enhanced void swelling in NiCoFeCrPd high-entropy alloy by indentation-induced dislocations

Journal Article Lu, Chenyang ; Yang, Taini ; Jin, Ke ; ... - Materials Research Letters

The role of dislocations on ion irradiation-induced void formation is studied in a high-entropy alloy (HEA) NiCoFeCrPd. Despite previous observations that show high-entropy alloys are swelling resistant due to a high defect recombination rate, the swelling is enhanced with increasing density of pre-existing dislocations at low strain levels that shortened transient duration before the onset of void swelling. Under certain irradiation conditions, a high density of dislocations may carry the material closer to the sink-dominated regime. Finally, compared to another HEA NiCoFeCrMn, NiCoFeCrPd has a smaller loop size and higher loop density due to the stronger lattice distortion.
Cited by 4
https://doi.org/10.1080/21663831.2018.1504136

Full Text Available
Influence of irradiation temperature on void swelling in NiCoFeCrMn and NiCoFeCrPd

Journal Article Yang, Tai-ni ; Lu, Chenyang ; Velisa, Gihan ; ... - Scripta Materialia

Here, using ion irradiation and transmission electron microscopy, temperature dependent void swelling and dislocation loop evolution in equiatomic NiCoFeCrMn and NiCoFeCrPd high entropy alloys were investigated. Voids were observed in all tested conditions. An order higher of swelling was observed in both HEAs as temperature increased from 420 to 580 °C. Alloying with Pd was found to have a stronger suppression effect on void and dislocation loop growth than alloying with Mn. Possible contributions to the swelling resistance were explored, including localized lattice distortion and higher defect migration barrier in NiCoFeCrPd. Additionally, no phase decomposition was observed in either alloy.
Cited by 3
https://doi.org/10.1016/j.scriptamat.2018.08.021

Full Text Available
High radiation tolerance of an ultrastrong nanostructured NiCoCr alloy with stable dispersed nanooxides and fine grain structure

Journal Article Lu, Chenyang ; Li, Mingyang ; Xiu, Pengyuan ; ... - Journal of Nuclear Materials

The present paper reports the irradiation behavior of nanostructured NiCoCr medium entropy alloy enhanced by Y-Hf-O nanooxides and fine grains produced by powder metallurgy. Ion beam irradiation to a peak dose of 130 dpa at 580°C produced neither detectable void swelling nor irradiation-induced hardening, in contrast to significant void swelling and property degradation of single phase NiCoCr concentrated solid-solution alloy under the similar irradiation condition. The dispersed nanooxides and high density of grain boundaries act as defect sinks that effectively annihilate irradiation-induced interstitials and vacancies. Furthermore, high-density nanooxides maintain their crystalline structures and stabilize the grain boundaries during irradiation.
https://doi.org/10.1016/j.jnucmat.2021.153316

Full Text Available
Solving the strength-ductility tradeoff in the medium-entropy NiCoCr alloy via interstitial strengthening of carbon

Journal Article Shang, Yy Y. ; Wu, Yuan ; He, Jy ; ... - Intermetallics

Interstitial solid strengthening is an effective strategy to harden metallic materials, however, it usually deteriorates the ductility. In this work, we report that addition of carbon into the medium-entropy NiCoCr alloy successfully enhances the strength at no expense of ductility. It was found that up to 0.75 at.% carbon was completely solid-solutionized in (NiCoCr_)100-xC_x(x = 0, 0.10, 0.25, 0.50 and 0.75 at.%) without formation of any carbides. With the increase of carbon content from 0 to 0.75 at.%, the yield and fracture strength were increased from 242 to 347 MPa to 727 and 862 MPa, respectively, whilst the ductility keptmore »« less
Cited by 11
https://doi.org/10.1016/j.intermet.2018.12.009

Full Text Available
Effects of temperature on the irradiation responses of Al_0.1CoCrFeNi high entropy alloy

Journal Article Yang, Tengfei ; Xia, Songqin ; Guo, Wei ; ... - Scripta Materialia

Structural damage and chemical segregation in Al_0.1CoCrFeNi high entropy alloy irradiated at elevated temperatures are studied using transmission electron microscopy (TEM) and atom probe tomography (APT). Irradiation-induced defects include dislocation loops, long dislocations and stacking-fault tetrahedra, but no voids can be observed. Furthermore, as irradiation temperature increases, defect density is decreased but defect size is increased, which is induced by increasing defect mobility. Finally, APT characterization reveals that ion irradiation at elevated temperatures can induce an enrichment of Ni and Co as well as a depletion of Fe and Cr at defect clusters, mainly including dislocation loops and long dislocations.
Cited by 13
https://doi.org/10.1016/j.scriptamat.2017.09.025

Full Text Available

Similar Records

Title: Irradiation effects of medium-entropy alloy NiCoCr with and without pre-indentation

Abstract

Citation Formats

Microstructural development in equiatomic multicomponent alloys journal, July 2004

Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes journal, May 2004

Relative effects of enthalpy and entropy on the phase stability of equiatomic high-entropy alloys journal, April 2013

Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off journal, May 2016

A fracture-resistant high-entropy alloy for cryogenic applications journal, September 2014

Radiation-induced segregation on defect clusters in single-phase concentrated solid-solution alloys journal, April 2017

Microstructural stability and mechanical behavior of FeNiMnCr high entropy alloy under ion irradiation journal, July 2016

Effects of temperature on the irradiation responses of Al0.1CoCrFeNi high entropy alloy journal, February 2018

Atomic-level heterogeneity and defect dynamics in concentrated solid-solution alloys journal, October 2017

Mechanism of Radiation Damage Reduction in Equiatomic Multicomponent Single Phase Alloys journal, April 2016

Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures journal, December 2014

Reasons for the superior mechanical properties of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi journal, April 2017

The evolution of the deformation substructure in a Ni-Co-Cr equiatomic solid solution alloy journal, June 2017

Dislocation mechanisms and 3D twin architectures generate exceptional strength-ductility-toughness combination in CrCoNi medium-entropy alloy journal, February 2017

Influence of chemical disorder on energy dissipation and defect evolution in advanced alloys journal, August 2016

Effect of alloying elements on defect evolution in Ni-20X binary alloys journal, June 2018

Interstitial migration behavior and defect evolution in ion irradiated pure nickel and Ni-xFe binary alloys journal, October 2018

Tailoring the physical properties of Ni-based single-phase equiatomic alloys by modifying the chemical complexity journal, February 2016

New ion beam materials laboratory for materials modification and irradiation effects research journal, November 2014

Direct Observation of Defect Range and Evolution in Ion-Irradiated Single Crystalline Ni and Ni Binary Alloys journal, February 2016

Void swelling in high dose ion-irradiated reduced activation ferritic–martensitic steels journal, July 2015

Influence of irradiation temperature on void swelling in NiCoFeCrMn and NiCoFeCrPd journal, January 2019

Enhanced void swelling in NiCoFeCrPd high-entropy alloy by indentation-induced dislocations journal, August 2018

Application of STEM characterization for investigating radiation effects in BCC Fe-based alloys journal, April 2015

Designing Radiation Resistance in Materials for Fusion Energy journal, July 2014

Microstructural development in equiatomic multicomponent alloys
journal, July 2004

Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004

Relative effects of enthalpy and entropy on the phase stability of equiatomic high-entropy alloys
journal, April 2013

Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off
journal, May 2016

A fracture-resistant high-entropy alloy for cryogenic applications
journal, September 2014

Radiation-induced segregation on defect clusters in single-phase concentrated solid-solution alloys
journal, April 2017

Microstructural stability and mechanical behavior of FeNiMnCr high entropy alloy under ion irradiation
journal, July 2016

Effects of temperature on the irradiation responses of Al0.1CoCrFeNi high entropy alloy
journal, February 2018

Atomic-level heterogeneity and defect dynamics in concentrated solid-solution alloys
journal, October 2017

Mechanism of Radiation Damage Reduction in Equiatomic Multicomponent Single Phase Alloys
journal, April 2016

Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures
journal, December 2014

Reasons for the superior mechanical properties of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi
journal, April 2017

The evolution of the deformation substructure in a Ni-Co-Cr equiatomic solid solution alloy
journal, June 2017

Dislocation mechanisms and 3D twin architectures generate exceptional strength-ductility-toughness combination in CrCoNi medium-entropy alloy
journal, February 2017

Influence of chemical disorder on energy dissipation and defect evolution in advanced alloys
journal, August 2016

Effect of alloying elements on defect evolution in Ni-20X binary alloys
journal, June 2018

Interstitial migration behavior and defect evolution in ion irradiated pure nickel and Ni-xFe binary alloys
journal, October 2018

Tailoring the physical properties of Ni-based single-phase equiatomic alloys by modifying the chemical complexity
journal, February 2016

New ion beam materials laboratory for materials modification and irradiation effects research
journal, November 2014

Direct Observation of Defect Range and Evolution in Ion-Irradiated Single Crystalline Ni and Ni Binary Alloys
journal, February 2016

Void swelling in high dose ion-irradiated reduced activation ferritic–martensitic steels
journal, July 2015

Influence of irradiation temperature on void swelling in NiCoFeCrMn and NiCoFeCrPd
journal, January 2019

Enhanced void swelling in NiCoFeCrPd high-entropy alloy by indentation-induced dislocations
journal, August 2018

Application of STEM characterization for investigating radiation effects in BCC Fe-based alloys
journal, April 2015

Designing Radiation Resistance in Materials for Fusion Energy
journal, July 2014