Low-dimensional perovskite nanoplatelet synthesis using in situ photophysical monitoring to establish controlled growth
Abstract
Perovskite nanoparticles have attracted the attention of research groups around the world for their impressive photophysical properties, facile synthesis and versatile surface chemistry. Here, we report a synthetic route that takes advantage of a suite of soluble precursors to generate CsPbBr3 perovskite nanoplatelets with fine control over size, thickness and optical properties. We demonstrate near unit cell precision, creating well characterized materials with sharp, narrow emission lines at 430, 460 and 490 nm corresponding to nanoplatelets that are 2, 4, and 6 unit cells thick, respectively. Nanoplatelets were characterized with optical spectroscopy, atomic force microscopy, scanning electron microscopy and transmission electron microscopy to explicitly correlate growth conditions, thickness and resulting photophysical properties. Detailed in situ photoluminescence spectroscopic studies were carried out to understand and optimize particle growth by correlating light emission with nanoplatelet growth across a range of synthetic conditions. It was found that nanoplatelet thickness and emission wavelength increase as the ratio of oleic acid to oleyl amine or the reaction temperature is increased. Using this information, we control the lateral size, width and corresponding emission wavelength of the desired nanoplatelets by modulating the temperature and ratios of the ligand.
- Authors:
-
[4];
[1];
[1];
[1]
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Ecole Polytechnique Fédérale de Lausanne, Lausanne (Switzerland)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS)
- OSTI Identifier:
- 1564046
- Alternate Identifier(s):
- OSTI ID: 1529707
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nanoscale
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 37; Journal ID: ISSN 2040-3364
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Do, Mai, Kim, Irene, Kolaczkowski, Matthew A., Kang, Jun, Kamat, Gaurav A., Yuan, Zhenghao, Barchi, Nicola S., Wang, Lin -Wang, Liu, Yi, Jurow, Matthew J., and Sutter-Fella, Carolin M. Low-dimensional perovskite nanoplatelet synthesis using in situ photophysical monitoring to establish controlled growth. United States: N. p., 2019.
Web. doi:10.1039/c9nr04010b.
Do, Mai, Kim, Irene, Kolaczkowski, Matthew A., Kang, Jun, Kamat, Gaurav A., Yuan, Zhenghao, Barchi, Nicola S., Wang, Lin -Wang, Liu, Yi, Jurow, Matthew J., & Sutter-Fella, Carolin M. Low-dimensional perovskite nanoplatelet synthesis using in situ photophysical monitoring to establish controlled growth. United States. https://doi.org/10.1039/c9nr04010b
Do, Mai, Kim, Irene, Kolaczkowski, Matthew A., Kang, Jun, Kamat, Gaurav A., Yuan, Zhenghao, Barchi, Nicola S., Wang, Lin -Wang, Liu, Yi, Jurow, Matthew J., and Sutter-Fella, Carolin M. Tue .
"Low-dimensional perovskite nanoplatelet synthesis using in situ photophysical monitoring to establish controlled growth". United States. https://doi.org/10.1039/c9nr04010b. https://www.osti.gov/servlets/purl/1564046.
@article{osti_1564046,
title = {Low-dimensional perovskite nanoplatelet synthesis using in situ photophysical monitoring to establish controlled growth},
author = {Do, Mai and Kim, Irene and Kolaczkowski, Matthew A. and Kang, Jun and Kamat, Gaurav A. and Yuan, Zhenghao and Barchi, Nicola S. and Wang, Lin -Wang and Liu, Yi and Jurow, Matthew J. and Sutter-Fella, Carolin M.},
abstractNote = {Perovskite nanoparticles have attracted the attention of research groups around the world for their impressive photophysical properties, facile synthesis and versatile surface chemistry. Here, we report a synthetic route that takes advantage of a suite of soluble precursors to generate CsPbBr3 perovskite nanoplatelets with fine control over size, thickness and optical properties. We demonstrate near unit cell precision, creating well characterized materials with sharp, narrow emission lines at 430, 460 and 490 nm corresponding to nanoplatelets that are 2, 4, and 6 unit cells thick, respectively. Nanoplatelets were characterized with optical spectroscopy, atomic force microscopy, scanning electron microscopy and transmission electron microscopy to explicitly correlate growth conditions, thickness and resulting photophysical properties. Detailed in situ photoluminescence spectroscopic studies were carried out to understand and optimize particle growth by correlating light emission with nanoplatelet growth across a range of synthetic conditions. It was found that nanoplatelet thickness and emission wavelength increase as the ratio of oleic acid to oleyl amine or the reaction temperature is increased. Using this information, we control the lateral size, width and corresponding emission wavelength of the desired nanoplatelets by modulating the temperature and ratios of the ligand.},
doi = {10.1039/c9nr04010b},
journal = {Nanoscale},
number = 37,
volume = 11,
place = {United States},
year = {Tue Jun 18 00:00:00 EDT 2019},
month = {Tue Jun 18 00:00:00 EDT 2019}
}
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Figure 1: UV absorption and PL spectra of (a) 2 unit cell, (b) 4 unit cell and (c) 6 unit cell thick CsPbBr3 nanoplates showing quantum size effects. AFM topography images of CsPbBr3 nanoplates (d) 2 unit cells, (e) 4 unit cells and (f) 6 unit cells thick. The whitemore »
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Works referencing / citing this record:
Revealing the Dynamics of Hybrid Metal Halide Perovskite Formation via Multimodal In Situ Probes
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