Alkene Hydrosilylation on Oxide-Supported Pt-Ligand Single–Site Catalysts

Chen, Linxiao; Ali, Iyad S.; Sterbinsky, George E.; Gamler, Jocelyn T.  L.; Skrabalak, Sara E.; Tait, Steven L.

doi:10.1002/cctc.201900530

Title: Alkene Hydrosilylation on Oxide-Supported Pt-Ligand Single–Site Catalysts

Journal Article · 20 May 2019 · ChemCatChem

DOI: https://doi.org/10.1002/cctc.201900530 · OSTI ID:1563148

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^[1]; Sterbinsky, George E. ^[2]; Gamler, Jocelyn T. L. ^[3];

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Indiana Univ., Bloomington, IN (United States). Dept. of Chemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Department of ChemistryIndiana University 800 E. Kirkwood Ave., Bloomington Indiana 47405 USA

Heterogeneous single-site catalysts (SSCs), widely regarded as promising next-generation catalysts, blend the easy recovery of traditional heterogeneous catalysts with desired features of homogeneous catalysts: high fraction of active sites and uniform metal centers. We previously reported the synthesis of Pt-ligand SSCs through a novel metal-ligand self-assembly method on MgO, CeO2, and Al2O3 supports (J. Catal. 2018, 365, 303–312). Here, we present their applications in the industriallyrelevant alkene hydrosilylation reaction, with 95% yield achieved under mild conditions. As expected, they exhibit better metal utilization efficiency than traditional heterogeneous Pt catalysts. The comparison with commercial catalysts (Karstedt and Speier) reveals several advantages of these SSCs: higher selectivity, less colloidal Pt formation, less alkene isomerization/hydrogenation, and better tolerance towards functional groups in substrates. Despite some leaching, our catalysts exhibit satisfactory recyclability and the single-site structure remains intact on oxide supports after reaction. Pt single-sites were proved to be the main active sites rather than colloidal Pt formed during the reaction. An induction period is observed in which Pt sites are activated by Cl detachment and replacement by reactant alkenes. The most active species likely involves temporary detachment of Pt from ligand or support. Catalytic performance of Pt SSCs is sensitive to the ligand and support choices, enabling fine tuning of Pt sites. This work highlights the application of heterogeneous SSCs created by the novel metal-ligand self-assembly strategy in an industrially-relevant reaction. It also offers a potential catalyst for future industrial hydrosilylation applications with several improvements over current commercial catalysts.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Indiana Univ., Bloomington, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357; SC0016367

OSTI ID:: 1563148

Alternate ID(s):: OSTI ID: 1515798; OSTI ID: 1772577

Journal Information:: ChemCatChem, Vol. 11, Issue 12; ISSN 1867-3880

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 18 works

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References (84)

Platinum(II) Complexes with Thioether-Functionalized Benzimidazolin-2-ylidene Ligands: Synthesis, Structural Characterization, and Application in Hydroelementation Reactions Bernhammer, Jan C.; Huynh, Han Vinh Organometallics, Vol. 33, Issue 1 https://doi.org/10.1021/om400929t	journal	December 2013
Catalytically Active Single-Atom Sites Fabricated from Silver Particles Huang, Zhiwei; Gu, Xiao; Cao, Qingqing Angewandte Chemie International Edition, Vol. 51, Issue 17 https://doi.org/10.1002/anie.201109065	journal	March 2012
Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes Morris, Robert H. Chemical Society Reviews, Vol. 38, Issue 8 https://doi.org/10.1039/b806837m	journal	January 2009
The effect of metal colloid morphology on catalytic activity: Further proof of the intermediacy of colloids in the rhodium-catalyzed hydrosilylation reaction Lewis, Larry N.; Uriarte, Richard J.; Lewis, Nathan Journal of Molecular Catalysis, Vol. 66, Issue 1 https://doi.org/10.1016/0304-5102(91)85025-W	journal	May 1991
Study of polysiloxanes containing epoxy groups Feng, Shengyu; Cui, Mengzhong Reactive and Functional Polymers, Vol. 45, Issue 2 https://doi.org/10.1016/S1381-5148(00)00013-4	journal	September 2000
Highly Active and Selective Platinum(0)-Carbene Complexes. Efficient, Catalytic Hydrosilylation of Functionalised Olefins Markó, István E.; Stérin, Sébastien; Buisine, Olivier Advanced Synthesis & Catalysis, Vol. 346, Issue 12 https://doi.org/10.1002/adsc.200404048	journal	October 2004
Fluorosilicones as High Temperature Elastomers Pierce, Ogden R.; Kim, Yung K. Rubber Chemistry and Technology, Vol. 44, Issue 5 https://doi.org/10.5254/1.3544816	journal	November 1971
Regioselective Synthesis of Multifunctional Hybrid Polysiloxanes Achieved by Pt−Nanocluster Catalysis Chauhan, Bhanu P. S.; Rathore, Jitendra S. Journal of the American Chemical Society, Vol. 127, Issue 16 https://doi.org/10.1021/ja042824c	journal	April 2005
Pt-Ni alloy catalysts for highly selective anti-Markovnikov alkene hydrosilylation Li, Qiang; Ji, Shufang; Li, Mufan Science China Materials, Vol. 61, Issue 10 https://doi.org/10.1007/s40843-018-9282-1	journal	May 2018
Expanded ring N-heterocyclic carbene complexes of zero valent platinum dvtms (divinyltetramethyldisiloxane): Highly efficient hydrosilylation catalysts Dunsford, Jay J.; Cavell, Kingsley J.; Kariuki, Benson Journal of Organometallic Chemistry, Vol. 696, Issue 1 https://doi.org/10.1016/j.jorganchem.2010.08.045	journal	January 2011
Polyether synthesis: From activated or metal-free anionic ring-opening polymerization of epoxides to functionalization Brocas, Anne-Laure; Mantzaridis, Christos; Tunc, Deniz Progress in Polymer Science, Vol. 38, Issue 6 https://doi.org/10.1016/j.progpolymsci.2012.09.007	journal	June 2013
Ligand-tailored single-site silica supported titanium catalysts: Synthesis, characterization and towards cyanosilylation reaction Xu, Wei; Li, Yani; Yu, Bo Journal of Solid State Chemistry, Vol. 221 https://doi.org/10.1016/j.jssc.2014.10.011	journal	January 2015
Catalytically Active Single-Atom Sites Fabricated from Silver Particles Huang, Zhiwei; Gu, Xiao; Cao, Qingqing Angewandte Chemie, Vol. 124, Issue 17 https://doi.org/10.1002/ange.201109065	journal	March 2012
Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation Bart, Suzanne C.; Lobkovsky, Emil; Chirik, Paul J. Journal of the American Chemical Society, Vol. 126, Issue 42 https://doi.org/10.1021/ja046753t	journal	October 2004
Homogeneous Catalysis. II. The Mechanism of the Hydrosilation of Olefins Catalyzed by Group VIII Metal Complexes ¹ Chalk, A. J.; Harrod, J. F. Journal of the American Chemical Society, Vol. 87, Issue 1 https://doi.org/10.1021/ja01079a004	journal	January 1965
Rational Design of a Well-Defined Soluble Calcium Hydride Complex Harder, Sjoerd; Brettar, Julie Angewandte Chemie International Edition, Vol. 45, Issue 21 https://doi.org/10.1002/anie.200601013	journal	May 2006
Isolated, well-defined organovanadium( iii ) on silica: single-site catalyst for hydrogenation of alkenes and alkynes Sohn, H.; Camacho-Bunquin, J.; Langeslay, R. R. Chemical Communications, Vol. 53, Issue 53 https://doi.org/10.1039/C7CC01876B	journal	January 2017
Single-atom catalysis of CO oxidation using Pt1/FeOx Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1095	journal	July 2011
Discovering Partially Charged Single-Atom Pt for Enhanced Anti-Markovnikov Alkene Hydrosilylation Chen, Yuanjun; Ji, Shufang; Sun, Wenming Journal of the American Chemical Society, Vol. 140, Issue 24 https://doi.org/10.1021/jacs.8b03121	journal	May 2018
Lewis Acid-Assisted Anionic Ring-Opening Polymerization of Epoxide by the Aluminum Complexes of Porphyrin, Phthalocyanine, Tetraazaannulene, and Schiff Base as Initiators Sugimoto, Hiroshi; Kawamura, Chikara; Kuroki, Masakatsu Macromolecules, Vol. 27, Issue 8 https://doi.org/10.1021/ma00086a006	journal	April 1994
First Titanium-Catalyzed a nti -1,4-Hydrosilylation of Dienes Bareille, Laurianne; Becht, Sabine; Cui, Jin Lan Organometallics, Vol. 24, Issue 24 https://doi.org/10.1021/om050533m	journal	November 2005
Ein stabiler “Single-site”-Palladiumkatalysator für Hydrierungen Vilé, Gianvito; Albani, Davide; Nachtegaal, Maarten Angewandte Chemie, Vol. 127, Issue 38 https://doi.org/10.1002/ange.201505073	journal	July 2015
Olefin Isomerization and Hydrosilylation Catalysis by Lewis Acidic Organofluorophosphonium Salts Pérez, Manuel; Hounjet, Lindsay J.; Caputo, Christopher B. Journal of the American Chemical Society, Vol. 135, Issue 49 https://doi.org/10.1021/ja410379x	journal	November 2013
Dense organic catalytic membranes for fine chemical synthesis Vankelecom, I. F. J.; Jacobs, P. A. Catalysis Today, Vol. 56, Issue 1-3 https://doi.org/10.1016/S0920-5861(99)00271-0	journal	February 2000
Use of functionalized PEG with 4-aminobenzoic acid stabilized platinum nanoparticles as an efficient catalyst for the hydrosilylation of alkenes Bai, Ying; Zhang, Shufang; Deng, Yuan Journal of Colloid and Interface Science, Vol. 394 https://doi.org/10.1016/j.jcis.2012.11.048	journal	March 2013
New Bis(dialkynyldisiloxane)triplatinum(0) Cluster: Synthesis, Structure, and Catalytic Activity in Olefin-Hydrosilylation Reactions Marciniec, Bogdan; Posała, Krystian; Kownacki, Ireneusz ChemCatChem, Vol. 4, Issue 12 https://doi.org/10.1002/cctc.201200319	journal	September 2012
Palladium- and platinum-catalyzed coupling reactions of allyloxy aromatics with hydridosilanes and hydridosiloxanes: Novel liquid crystalline/organosilane materials Sellinger, Alan; Laine, Richard M.; Chu, Vano Journal of Polymer Science Part A: Polymer Chemistry, Vol. 32, Issue 16 https://doi.org/10.1002/pola.1994.080321608	journal	December 1994
Diethyl sulfide stabilization of platinum-complex catalysts for hydrosilylation of olefins Downing, Christopher M.; Kung, Harold H. Catalysis Communications, Vol. 12, Issue 12 https://doi.org/10.1016/j.catcom.2011.03.041	journal	July 2011
A Facile Preparation and Polymerization of 1,1-Difunctionalized Disiloxanes Mori, Atsunori; Sato, Hiroyoshi; Mizuno, Katsuya Chemistry Letters, Vol. 25, Issue 7 https://doi.org/10.1246/cl.1996.517	journal	July 1996
Cyanoethylation of Trichlorosilane. II. α-Addition Nozakura, Shunichi; Konotsune, Shiro Bulletin of the Chemical Society of Japan, Vol. 29, Issue 3 https://doi.org/10.1246/bcsj.29.326	journal	March 1956
Redox-active on-surface polymerization of single-site divalent cations from pure metals by a ketone-functionalized phenanthroline Skomski, Daniel; Tempas, Christopher D.; Bukowski, Gregory S. The Journal of Chemical Physics, Vol. 142, Issue 10 https://doi.org/10.1063/1.4906894	journal	February 2015
Ir-catalyzed hydrosilylation reaction of allyl acetate with octakis(dimethylsiloxy)octasilsesquioxane and related hydrosilanes Igarashi, Masayasu; Matsumoto, Tomohiro; Kobayashi, Toshiaki Journal of Organometallic Chemistry, Vol. 752 https://doi.org/10.1016/j.jorganchem.2013.11.035	journal	February 2014
On the mechanism of metal colloid catalyzed hydrosilylation: proposed explanations for electronic effects and oxygen cocatalysis Lewis, Larry N. Journal of the American Chemical Society, Vol. 112, Issue 16 https://doi.org/10.1021/ja00172a014	journal	August 1990
A Strategy for the Synthesis of Well-Defined Iron Catalysts and Application to Regioselective Diene Hydrosilylation Wu, Jessica Y.; Stanzl, Benjamin N.; Ritter, Tobias Journal of the American Chemical Society, Vol. 132, Issue 38 https://doi.org/10.1021/ja106853y	journal	September 2010
Theoretical Study of Platinum(0)-Catalyzed Hydrosilylation of Ethylene. Chalk−Harrod Mechanism or Modified Chalk−Harrod Mechanism Sakaki, Shigeyoshi; Mizoe, Nobuteru; Sugimoto, Manabu Organometallics, Vol. 17, Issue 12 https://doi.org/10.1021/om980190a	journal	June 1998
The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts Speier, John L.; Webster, James A.; Barnes, Garrett H. Journal of the American Chemical Society, Vol. 79, Issue 4 https://doi.org/10.1021/ja01561a054	journal	February 1957
Poly(vinylsilane): a precursor to silicon carbide. 1. Preparation and characterization Boury, Bruno.; Corriu, Robert J. P.; Leclercq, Dominique. Organometallics, Vol. 10, Issue 5 https://doi.org/10.1021/om00051a043	journal	May 1991
Chiral Bis(pyridylimino)isoindoles: A Highly Modular Class of Pincer Ligands for Enantioselective Catalysis Langlotz, Björn K.; Wadepohl, Hubert; Gade, Lutz H. Angewandte Chemie International Edition, Vol. 47, Issue 25 https://doi.org/10.1002/anie.200801150	journal	June 2008
Pentacarbonyliron(0) photocatalyzed reactions of trialkylsilanes with alkenes A. Schroeder, Mark; S. Wrighton, Mark Journal of Organometallic Chemistry, Vol. 128, Issue 3 https://doi.org/10.1016/S0022-328X(00)92207-1	journal	March 1977
Synthesis and characterization of UV-curable polydimethylsiloxane epoxy acrylate Wang, Weizhi European Polymer Journal, Vol. 39, Issue 6 https://doi.org/10.1016/S0014-3057(02)00374-9	journal	June 2003
Fluorosilicones as High Temperature Elastomers Pierce, Ogden R.; Kim, Yung K. Journal of Elastoplastics, Vol. 3, Issue 2 https://doi.org/10.1177/009524437100300201	journal	April 1971
Selective and Efficient Platinum(0)-Carbene Complexes As Hydrosilylation Catalysts Markó, István E.; Stérin, Sébastien; Buisine, Olivier Science, Vol. 298, Issue 5591 https://doi.org/10.1126/science.1073338	journal	October 2002
Fabrication, characterization, and stability of supported single-atom catalysts Chen, Yaxin; Huang, Zhiwei; Ma, Zhen Catalysis Science & Technology, Vol. 7, Issue 19 https://doi.org/10.1039/C7CY00723J	journal	January 2017
Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism Glaser, Paul B.; Tilley, T. Don Journal of the American Chemical Society, Vol. 125, Issue 45 https://doi.org/10.1021/ja037620v	journal	November 2003
Platinum Oxide (PtO ₂ ): A Potent Hydrosilylation Catalyst Sabourault, Nicolas; Mignani, Gérard; Wagner, Alain Organic Letters, Vol. 4, Issue 13 https://doi.org/10.1021/ol025658r	journal	June 2002
New fluorinated polysiloxanes containing an ester function in the spacer. I. Synthesis and characterization Beyou, Emmanuel; Babin, Pierre; Bennetau, Bernard Journal of Polymer Science Part A: Polymer Chemistry, Vol. 32, Issue 9 https://doi.org/10.1002/pola.1994.080320909	journal	July 1994
Peroxide-Catalyzed Addition of Trichlorosilane to 1-Octene Sommer, L. H.; Pietrusza, E. W.; Whitmore, F. C. Journal of the American Chemical Society, Vol. 69, Issue 1 https://doi.org/10.1021/ja01193a508	journal	January 1947
Rational Design of a Well-Defined Soluble Calcium Hydride Complex Harder, Sjoerd; Brettar, Julie Angewandte Chemie, Vol. 118, Issue 21 https://doi.org/10.1002/ange.200601013	journal	May 2006
Recent advances in catalytic hydrosilylation Marciniec, Bogdan; Guliński, Jacek Journal of Organometallic Chemistry, Vol. 446, Issue 1-2 https://doi.org/10.1016/0022-328X(93)80030-F	journal	March 1993
Platinum(II)-bis-(N-heterocyclic carbene) complexes: synthesis, structure and catalytic activity in the hydrosilylation of alkenes Taige, Maria A.; Ahrens, Sebastian; Strassner, Thomas Journal of Organometallic Chemistry, Vol. 696, Issue 17 https://doi.org/10.1016/j.jorganchem.2011.04.030	journal	August 2011
Chemical Substituent Effects on Morphological Transitions in Styrene−Butadiene−Styrene Triblock Copolymer Grafted with Polyhedral Oligomeric Silsesquioxanes Drazkowski, Daniel B.; Lee, Andre; Haddad, Timothy S. Macromolecules, Vol. 39, Issue 5 https://doi.org/10.1021/ma0518813	journal	March 2006
Highly Efficient B(C ₆ F ₅ ) ₃ -Catalyzed Hydrosilylation of Olefins ^† Rubin, Michael; Schwier, Todd; Gevorgyan, Vladimir The Journal of Organic Chemistry, Vol. 67, Issue 6 https://doi.org/10.1021/jo016279z	journal	March 2002
Selective Formic Acid Dehydrogenation on Pt-Cu Single-Atom Alloys Marcinkowski, Matthew D.; Liu, Jilei; Murphy, Colin J. ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02772	journal	December 2016
A Stable Single-Site Palladium Catalyst for Hydrogenations Vilé, Gianvito; Albani, Davide; Nachtegaal, Maarten Angewandte Chemie International Edition, Vol. 54, Issue 38 https://doi.org/10.1002/anie.201505073	journal	July 2015
Hydrosilylation catalyzed by metal colloids: a relative activity study Lewis, Larry N.; Uriarte, Richard J. Organometallics, Vol. 9, Issue 3 https://doi.org/10.1021/om00117a015	journal	March 1990
Two- and Three-Electron Oxidation of Single-Site Vanadium Centers at Surfaces by Ligand Design Skomski, Daniel; Tempas, Christopher D.; Cook, Brian J. Journal of the American Chemical Society, Vol. 137, Issue 24 https://doi.org/10.1021/jacs.5b03706	journal	June 2015
Heterogeneously supported pseudo-single atom Pt as sustainable hydrosilylation catalyst Zai, Huachao; Zhao, Yizhou; Chen, Shanyu Nano Research, Vol. 11, Issue 5 https://doi.org/10.1007/s12274-017-1879-6	journal	May 2018
One-Pot Pyrolysis to N-Doped Graphene with High-Density Pt Single Atomic Sites as Heterogeneous Catalyst for Alkene Hydrosilylation Zhu, Youqi; Cao, Tai; Cao, Chuanbao ACS Catalysis, Vol. 8, Issue 11 https://doi.org/10.1021/acscatal.8b02624	journal	September 2018
Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium Leich, Valeri; Spaniol, Thomas P.; Maron, Laurent Chemical Communications, Vol. 50, Issue 18 https://doi.org/10.1039/c3cc49308c	journal	January 2014
In Situ Determination of the Active Catalyst in Hydrosilylation Reactions Using Highly Reactive Pt(0) Catalyst Precursors Stein, Judith; Lewis, L. N.; Gao, Y. Journal of the American Chemical Society, Vol. 121, Issue 15 https://doi.org/10.1021/ja9825377	journal	April 1999
Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view Troegel, Dennis; Stohrer, Jürgen Coordination Chemistry Reviews, Vol. 255, Issue 13-14 https://doi.org/10.1016/j.ccr.2010.12.025	journal	July 2011
Novel liquid crystalline resins based on MQ siloxanes Ganicz, Tomasz; Pakuła, Tadeusz; Stańczyk, Włodzimierz A. Journal of Organometallic Chemistry, Vol. 691, Issue 23 https://doi.org/10.1016/j.jorganchem.2006.07.043	journal	November 2006
Single-Atom Pd ₁ /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene Yan, Huan; Cheng, Hao; Yi, Hong Journal of the American Chemical Society, Vol. 137, Issue 33 https://doi.org/10.1021/jacs.5b06485	journal	August 2015
Platinum nanoparticles in suspension are as efficient as Karstedt's complex for alkene hydrosilylation Galeandro-Diamant, Thomas; Zanota, Marie-Line; Sayah, Reine Chemical Communications, Vol. 51, Issue 90 https://doi.org/10.1039/C5CC05675F	journal	January 2015
Synthesis and photocrosslinking of benzyl acrylate substituted polydimethylsiloxanes Iojoiu, Cristina; Abadie, Marc J. M.; Harabagiu, Valeria European Polymer Journal, Vol. 36, Issue 10 https://doi.org/10.1016/S0014-3057(99)00287-6	journal	October 2000
Synthesis and structural characterization of a new polysiloxane with second-order nonlinear optical effect Li, Zhen; Qin, Jingui; Yang, Zhou Journal of Applied Polymer Science, Vol. 94, Issue 2 https://doi.org/10.1002/app.20942	journal	January 2004
Thermally initiated cationic polymerization and properties of epoxy siloxane Morita, Yasumasa; Tajima, Seitarou; Suzuki, Hiroshi Journal of Applied Polymer Science, Vol. 100, Issue 3 https://doi.org/10.1002/app.22603	journal	January 2006
Asymmetric Catalysis of Epoxide Ring-Opening Reactions Jacobsen, Eric N. Accounts of Chemical Research, Vol. 33, Issue 6 https://doi.org/10.1021/ar960061v	journal	June 2000
Platinum Catalysis Revisited—Unraveling Principles of Catalytic Olefin Hydrosilylation Meister, Teresa K.; Riener, Korbinian; Gigler, Peter ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b02624	journal	January 2016
Synthesis of platinum single-site centers through metal-ligand self-assembly on powdered metal oxide supports Chen, Linxiao; Sterbinsky, George E.; Tait, Steven L. Journal of Catalysis, Vol. 365 https://doi.org/10.1016/j.jcat.2018.07.004	journal	September 2018
Pt-catalyzed hydrosilylation of ethylene. A theoretical study of the reaction mechanism Sakaki, Shigeyoshi; Mizoe, Nobuteru; Sugimoto, Manabu Coordination Chemistry Reviews, Vol. 190-192 https://doi.org/10.1016/S0010-8545(99)00130-7	journal	September 1999
Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism Hu, Bo; “Bean” Getsoian, Andrew; Schweitzer, Neil M. Journal of Catalysis, Vol. 322 https://doi.org/10.1016/j.jcat.2014.10.018	journal	February 2015
Redox Isomeric Surface Structures Are Preferred over Odd-Electron Pt ¹⁺ Tempas, Christopher D.; Skomski, Daniel; Cook, Brian J. Chemistry - A European Journal, Vol. 24, Issue 59 https://doi.org/10.1002/chem.201802943	journal	September 2018
Effect of triarylphosphane ligands on the rhodium-catalyzed hydrosilylation of alkene: Rhodium-catalyzed hydrosilylation of styrene Xue, Mei; Li, Jiayun; Peng, Jiajian Applied Organometallic Chemistry, Vol. 28, Issue 2 https://doi.org/10.1002/aoc.3092	journal	January 2014
Chiral Bis(pyridylimino)isoindoles: A Highly Modular Class of Pincer Ligands for Enantioselective Catalysis Langlotz, Björn K.; Wadepohl, Hubert; Gade, Lutz H. Angewandte Chemie, Vol. 120, Issue 25 https://doi.org/10.1002/ange.200801150	journal	June 2008
Silicone waxes—synthesis via hydrosilylation in homo- and heterogeneous systems Maciejewski, Hieronim; Wawrzyńczak, Agata; Dutkiewicz, Michał Journal of Molecular Catalysis A: Chemical, Vol. 257, Issue 1-2 https://doi.org/10.1016/j.molcata.2006.04.039	journal	September 2006
Comparative single atom heterogeneous catalysts (SAHCs) on different platforms: a theoretical approach Fako, Edvin; Łodziana, Zbigniew; López, Núria Catalysis Science & Technology, Vol. 7, Issue 19 https://doi.org/10.1039/C7CY01136A	journal	January 2017
Redox-Active On-Surface Assembly of Metal–Organic Chains with Single-Site Pt(II) Skomski, Daniel; Tempas, Christopher D.; Smith, Kevin A. Journal of the American Chemical Society, Vol. 136, Issue 28 https://doi.org/10.1021/ja504850f	journal	July 2014
Rhenium-mediated dehydrogenative silylation and highly regioselective hydrosilylation of nitrile substituted olefins Dong, Hailin; Jiang, Yanfeng; Berke, Heinz Journal of Organometallic Chemistry, Vol. 750 https://doi.org/10.1016/j.jorganchem.2013.10.052	journal	January 2014
Platinum-catalyzed hydrosilylation of alkynes Lewis, Larry N.; Sy, Karen G.; Bryant, Garold L. Organometallics, Vol. 10, Issue 10 https://doi.org/10.1021/om00056a055	journal	October 1991
Platinum-catalyzed hydrosilylation - colloid formation as the essential step Lewis, Larry N.; Lewis, Nathan. Journal of the American Chemical Society, Vol. 108, Issue 23 https://doi.org/10.1021/ja00283a016	journal	November 1986
The New Tetrafunctional π Acceptor Ligand 3,6-Bis(2′-pyrimidyl)-1,2,4,5-tetrazine (bmtz): Diruthenium Complexes of bmtz and of its 1,4-Dihydro Form Kaim, Wolfgang; Fees, Jörg Zeitschrift für Naturforschung B, Vol. 50, Issue 1 https://doi.org/10.1515/znb-1995-0123	journal	January 1995
“A posteriori” modification of carbosilane dendrimers and dendrons: their activation in core and branch positions Tuchbreiter, Arno; Werner, Helmut; Gade, Lutz H. Dalton Trans., Issue 8 https://doi.org/10.1039/B501069A	journal	January 2005
First Titanium-Catalyzed anti-1,4-Hydrosilylation of Dienes. Bareille, Laurianne; Becht, Sabine; Cui, Jin Lan ChemInform, Vol. 37, Issue 14 https://doi.org/10.1002/chin.200614180	journal	April 2006

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
X-ray absorption spectroscopy
X-ray photoelectron spectroscopy
heterogeneous catalysis
hydrosilylation
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Title: Alkene Hydrosilylation on Oxide-Supported Pt-Ligand Single–Site Catalysts

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