Kerr gated Raman spectroscopy of LiPF 6 salt and LiPF 6 -based organic carbonate electrolyte for Li-ion batteries
Abstract
Fluorescent species are formed during cycling of lithium ion batteries as a result of electrolyte decomposition due to the instability of the non-aqueous electrolytes and side reactions that occur at the electrode surface. The increase in the background fluorescence due to the presence of these components makes it harder to analyse data due to the spectroscopic overlap of Raman scattering and fluorescence. Herein, Kerr gated Raman spectroscopy was shown to be an effective technique for the isolation of the scattering effect from the fluorescence enabling the collection of the Raman spectra of LiPF6 salt and LiPF6-based organic carbonate electrolyte, without the interference of the fluorescence component. Kerr gated Raman was able to identify POF3 on the LiPF6 particle surface, after the addition of trace water.
- Authors:
-
[1];
[1]
- Stephenson Institute for Renewable Energy, Department of Chemistry, University of Liverpool, Liverpool, UK
- Central Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory, Didcot, UK
- Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, USA
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1562988
- Alternate Identifier(s):
- OSTI ID: 1572059
- Grant/Contract Number:
- AC02-05CH11231f; AC02-05CH11231
- Resource Type:
- Published Article
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP
- Additional Journal Information:
- Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Volume: 21 Journal Issue: 43; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Cabo-Fernandez, Laura, Neale, Alex R., Braga, Filipe, Sazanovich, Igor V., Kostecki, Robert, and Hardwick, Laurence J. Kerr gated Raman spectroscopy of LiPF 6 salt and LiPF 6 -based organic carbonate electrolyte for Li-ion batteries. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9CP02430A.
Cabo-Fernandez, Laura, Neale, Alex R., Braga, Filipe, Sazanovich, Igor V., Kostecki, Robert, & Hardwick, Laurence J. Kerr gated Raman spectroscopy of LiPF 6 salt and LiPF 6 -based organic carbonate electrolyte for Li-ion batteries. United Kingdom. https://doi.org/10.1039/C9CP02430A
Cabo-Fernandez, Laura, Neale, Alex R., Braga, Filipe, Sazanovich, Igor V., Kostecki, Robert, and Hardwick, Laurence J. Thu .
"Kerr gated Raman spectroscopy of LiPF 6 salt and LiPF 6 -based organic carbonate electrolyte for Li-ion batteries". United Kingdom. https://doi.org/10.1039/C9CP02430A.
@article{osti_1562988,
title = {Kerr gated Raman spectroscopy of LiPF 6 salt and LiPF 6 -based organic carbonate electrolyte for Li-ion batteries},
author = {Cabo-Fernandez, Laura and Neale, Alex R. and Braga, Filipe and Sazanovich, Igor V. and Kostecki, Robert and Hardwick, Laurence J.},
abstractNote = {Fluorescent species are formed during cycling of lithium ion batteries as a result of electrolyte decomposition due to the instability of the non-aqueous electrolytes and side reactions that occur at the electrode surface. The increase in the background fluorescence due to the presence of these components makes it harder to analyse data due to the spectroscopic overlap of Raman scattering and fluorescence. Herein, Kerr gated Raman spectroscopy was shown to be an effective technique for the isolation of the scattering effect from the fluorescence enabling the collection of the Raman spectra of LiPF6 salt and LiPF6-based organic carbonate electrolyte, without the interference of the fluorescence component. Kerr gated Raman was able to identify POF3 on the LiPF6 particle surface, after the addition of trace water.},
doi = {10.1039/C9CP02430A},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 43,
volume = 21,
place = {United Kingdom},
year = {Thu Nov 07 00:00:00 EST 2019},
month = {Thu Nov 07 00:00:00 EST 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C9CP02430A
https://doi.org/10.1039/C9CP02430A
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 23 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Efficient Rejection of Fluorescence from Raman Spectra Using Picosecond Kerr Gating
journal, December 1999
- Matousek, P.; Towrie, M.; Stanley, A.
- Applied Spectroscopy, Vol. 53, Issue 12
Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF 6 , LiBF 4 , LiDFOB, LiBOB, and LiTFSI
journal, January 2018
- Parimalam, Bharathy S.; Lucht, Brett L.
- Journal of The Electrochemical Society, Vol. 165, Issue 2
Breakdown of Kasha’s Rule in a Ubiquitous, Naturally Occurring, Wide Bandgap Aluminosilicate (Feldspar)
journal, January 2018
- Prasad, Amit Kumar; Jain, Mayank
- Scientific Reports, Vol. 8, Issue 1
Review of Fluorescence Suppression Techniques in Raman Spectroscopy
journal, January 2015
- Wei, Dong; Chen, Shuo; Liu, Quan
- Applied Spectroscopy Reviews, Vol. 50, Issue 5
Ageing mechanisms in lithium-ion batteries
journal, September 2005
- Vetter, J.; Novák, P.; Wagner, M. R.
- Journal of Power Sources, Vol. 147, Issue 1-2
Time-resolved SERS study of the oxygen reduction reaction in ionic liquid electrolytes for non-aqueous lithium–oxygen cells
journal, January 2018
- Radjenovic, Petar M.; Hardwick, Laurence J.
- Faraday Discussions, Vol. 206
Initial stages of thermal decomposition of LiPF6-based lithium ion battery electrolytes by detailed Raman and NMR spectroscopy
journal, January 2013
- Wilken, Susanne; Treskow, Marcel; Scheers, Johan
- RSC Advances, Vol. 3, Issue 37
Dual Fluorescence through Kasha’s Rule Breaking: An Unconventional Photomechanism for Intracellular Probe Design
journal, May 2015
- Brancato, Giuseppe; Signore, Giovanni; Neyroz, Paolo
- The Journal of Physical Chemistry B, Vol. 119, Issue 20
Quantitative investigation of the decomposition of organic lithium ion battery electrolytes with LC-MS/MS
journal, January 2017
- Schultz, Carola; Vedder, Sven; Streipert, Benjamin
- RSC Advances, Vol. 7, Issue 45
Infrared spectroscopy of instantaneous decomposition products of LiPF6-based lithium battery electrolytes
journal, October 2012
- Wilken, Susanne; Johansson, Patrik; Jacobsson, Per
- Solid State Ionics, Vol. 225
Hydrolysis of LiPF 6 in Carbonate-Based Electrolytes for Lithium-Ion Batteries and in Aqueous Media
journal, April 2018
- Stich, Michael; Göttlinger, Mara; Kurniawan, Mario
- The Journal of Physical Chemistry C, Vol. 122, Issue 16
Crystal Structure and Spectroscopic Investigations of POF 3 : Crystal Structure and Spectroscopic Investigations of POF
journal, November 2013
- Feller, Michael; Lux, Karin; Kornath, Andreas
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 640, Issue 1
New Process of Synthesizing LiPF6 in Organic Solvent for Electrolyte
journal, July 2015
- Kamiya, Jumpei; Mitsui, Toshinori; Ooe, Meguru
- ECS Meeting Abstracts, Vol. MA2015-02, Issue 1
Mechanistic insights into lithium ion battery electrolyte degradation – a quantitative NMR study
journal, January 2016
- Wiemers-Meyer, S.; Winter, M.; Nowak, S.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 38
Ultra: A Unique Instrument for Time-Resolved Spectroscopy
journal, December 2010
- Greetham, Gregory M.; Burgos, Pierre; Cao, Qian
- Applied Spectroscopy, Vol. 64, Issue 12
On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries
journal, September 1999
- Aurbach, D.; Markovsky, B.; Weissman, I.
- Electrochimica Acta, Vol. 45, Issue 1-2
Fluorescence background suppression in Raman spectroscopy using combined Kerr gated and shifted excitation Raman difference techniques
journal, January 2002
- Matousek, P.; Towrie, M.; Parker, A. W.
- Journal of Raman Spectroscopy, Vol. 33, Issue 4
Fluorescence suppression in resonance Raman spectroscopy using a high-performance picosecond Kerr gate
journal, January 2001
- Matousek, P.; Towrie, M.; Ma, C.
- Journal of Raman Spectroscopy, Vol. 32, Issue 12
The Study of Surface Film Formation on Noble-Metal Electrodes in Alkyl Carbonates/Li Salt Solutions, Using Simultaneous in Situ AFM, EQCM, FTIR, and EIS
journal, April 1999
- Aurbach, D.; Moshkovich, M.; Cohen, Y.
- Langmuir, Vol. 15, Issue 8
Coupled LiPF 6 Decomposition and Carbonate Dehydrogenation Enhanced by Highly Covalent Metal Oxides in High-Energy Li-Ion Batteries
journal, October 2018
- Yu, Yang; Karayaylali, Pinar; Katayama, Yu
- The Journal of Physical Chemistry C, Vol. 122, Issue 48
Diagnostic Studies of Polyolefin Separators in High-Power Li-Ion Cells
journal, January 2004
- Kostecki, Robert; Norin, Laura; Song, Xiangyun
- Journal of The Electrochemical Society, Vol. 151, Issue 4
Quantifying Changes to the Electrolyte and Negative Electrode in Aged NMC532/Graphite Lithium-Ion Cells
journal, January 2018
- Thompson, L. M.; Stone, W.; Eldesoky, A.
- Journal of The Electrochemical Society, Vol. 165, Issue 11
In situ quantitative analysis of individual H2O–CO2 fluid inclusions by laser Raman spectroscopy
journal, March 2007
- Azbej, Tristan; Severs, Matthew J.; Rusk, Brian G.
- Chemical Geology, Vol. 237, Issue 3-4
Raman spectroscopy of street samples of cocaine obtained using Kerr gated fluorescence rejection
journal, January 2004
- Littleford, Rachael E.; Matousek, Pavel; Towrie, Michael
- The Analyst, Vol. 129, Issue 6
The Formation Mechanism of Fluorescent Metal Complexes at the Li x Ni 0.5 Mn 1.5 O 4−δ /Carbonate Ester Electrolyte Interface
journal, March 2015
- Jarry, Angélique; Gottis, Sébastien; Yu, Young-Sang
- Journal of the American Chemical Society, Vol. 137, Issue 10
In situ Raman spectroscopy of carbon-coated ZnFe 2 O 4 anode material in Li-ion batteries – investigation of SEI growth
journal, January 2016
- Cabo-Fernandez, Laura; Mueller, Franziska; Passerini, Stefano
- Chemical Communications, Vol. 52, Issue 20
An Investigation of the Effect of Graphite Degradation on Irreversible Capacity in Lithium-ion Cells
journal, January 2008
- Hardwick, Laurence J.; Marcinek, Marek; Beer, Leanne
- Journal of The Electrochemical Society, Vol. 155, Issue 6
UV gated Raman spectroscopy for standoff detection of explosives
journal, July 2008
- Gaft, M.; Nagli, L.
- Optical Materials, Vol. 30, Issue 11, p. 1739-1746
Quantifying capacity loss due to solid-electrolyte-interphase layer formation on silicon negative electrodes in lithium-ion batteries
journal, October 2012
- Nadimpalli, Siva P. V.; Sethuraman, Vijay A.; Dalavi, Swapnil
- Journal of Power Sources, Vol. 215
Effects of Solute–Solvent Hydrogen Bonding on Nonaqueous Electrolyte Structure
journal, July 2015
- Schroder, Kjell W.; Dylla, Anthony G.; Bishop, Logan D. C.
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 15
Solid state vibrational spectroscopy of anhydrous lithium hexafluorophosphate (LiPF6)
journal, October 2012
- Kock, L. D.; Lekgoathi, M. D. S.; Crouse, P. L.
- Journal of Molecular Structure, Vol. 1026
Decomposition of LiPF 6 in High Energy Lithium-Ion Batteries Studied with Online Electrochemical Mass Spectrometry
journal, January 2016
- Guéguen, Aurélie; Streich, Daniel; He, Minglong
- Journal of The Electrochemical Society, Vol. 163, Issue 6
Characterization, purification, and stability of gold nanoparticles
journal, December 2010
- Balasubramanian, Suresh K.; Yang, Liming; Yung, Lin-Yue L.
- Biomaterials, Vol. 31, Issue 34
Hydrolysis of Ethylene Carbonate with Water and Hydroxide under Battery Operating Conditions
journal, January 2016
- Metzger, Michael; Strehle, Benjamin; Solchenbach, Sophie
- Journal of The Electrochemical Society, Vol. 163, Issue 7