Synthesis and Utility of Neptunium(III) Hydrocarbyl Complex

Myers, Alexander J.; Tarlton, Michael L.; Kelley, Steven P.; Lukens, Wayne W.; Walensky, Justin R.

doi:10.1002/ange.201906324

Title: Synthesis and Utility of Neptunium(III) Hydrocarbyl Complex

Journal Article · 19 September 2019 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.201906324 · OSTI ID:1562724

Myers, Alexander J. ^[1]; Tarlton, Michael L. ^[1]; Kelley, Steven P. ^[1]; Lukens, Wayne W. ^[2];

^[1]

Department of Chemistry University of Missouri, Columbia 601 S. College Avenue Columbia MO 65211 USA
Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA

Abstract To extend organoactinide chemistry beyond uranium, reported here is the first structurally characterized transuranic hydrocarbyl complex, Np[ η ⁴ ‐Me ₂ NC(H)C ₆ H ₅ ] ₃ ( 1 ), from reaction of NpCl ₄ (DME) ₂ with four equivalents of K[Me ₂ NC(H)C ₆ H ₅ ]. Unlike the U ^III species, the neptunium analogue can be used to access other Np ^III complexes. The reaction of 1 with three equivalents of HE ₂ C(2,6‐Mes ₂ ‐C ₆ H ₃ ) (E=O, S) yields [(2,6‐Mes ₂ ‐C ₆ H ₃ )CE ₂ ] ₃ Np(THF) ₂ , maintaining the trivalent oxidation state.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC-0014174; AC02-05CH11231

OSTI ID:: 1562724

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 131 Journal Issue: 42; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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