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Title: Uncorrelated Bi off-centering and the insulator-to-metal transition in ruthenium A 2 Ru 2 O 7 pyrochlores

Authors:
; ORCiD logo; ; ORCiD logo; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1562328
Grant/Contract Number:  
89233218CNA000001
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Review Materials
Additional Journal Information:
Journal Name: Physical Review Materials Journal Volume: 3 Journal Issue: 9; Journal ID: ISSN 2475-9953
Publisher:
American Physical Society
Country of Publication:
United States
Language:
English

Citation Formats

Laurita, Geneva, Puggioni, Danilo, Hickox-Young, Daniel, Rondinelli, James M., Gaultois, Michael W., Page, Katharine, Lamontagne, Leo K., and Seshadri, Ram. Uncorrelated Bi off-centering and the insulator-to-metal transition in ruthenium A 2 Ru 2 O 7 pyrochlores. United States: N. p., 2019. Web. doi:10.1103/PhysRevMaterials.3.095003.
Laurita, Geneva, Puggioni, Danilo, Hickox-Young, Daniel, Rondinelli, James M., Gaultois, Michael W., Page, Katharine, Lamontagne, Leo K., & Seshadri, Ram. Uncorrelated Bi off-centering and the insulator-to-metal transition in ruthenium A 2 Ru 2 O 7 pyrochlores. United States. doi:10.1103/PhysRevMaterials.3.095003.
Laurita, Geneva, Puggioni, Danilo, Hickox-Young, Daniel, Rondinelli, James M., Gaultois, Michael W., Page, Katharine, Lamontagne, Leo K., and Seshadri, Ram. Tue . "Uncorrelated Bi off-centering and the insulator-to-metal transition in ruthenium A 2 Ru 2 O 7 pyrochlores". United States. doi:10.1103/PhysRevMaterials.3.095003.
@article{osti_1562328,
title = {Uncorrelated Bi off-centering and the insulator-to-metal transition in ruthenium A 2 Ru 2 O 7 pyrochlores},
author = {Laurita, Geneva and Puggioni, Danilo and Hickox-Young, Daniel and Rondinelli, James M. and Gaultois, Michael W. and Page, Katharine and Lamontagne, Leo K. and Seshadri, Ram},
abstractNote = {},
doi = {10.1103/PhysRevMaterials.3.095003},
journal = {Physical Review Materials},
number = 9,
volume = 3,
place = {United States},
year = {2019},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1103/PhysRevMaterials.3.095003

Citation Metrics:
Cited by: 3 works
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Works referenced in this record:

Electrical Resistivity of SrRuO 3
journal, August 1969

  • Noro, Yoshihiko; Miyahara, Syôhei
  • Journal of the Physical Society of Japan, Vol. 27, Issue 2
  • DOI: 10.1143/JPSJ.27.518A

Effective ionic radii in oxides and fluorides
journal, May 1969

  • Shannon, R. D.; Prewitt, C. T.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 25, Issue 5
  • DOI: 10.1107/S0567740869003220

Lone pairs in insulating pyrochlores: Ice rules and high-k behavior
journal, March 2006


Structural disorder, magnetism, and electrical and thermoelectric properties of pyrochlore Nd 2 Ru 2 O 7
journal, April 2013

  • Gaultois, Michael W.; Barton, Phillip T.; Birkel, Christina S.
  • Journal of Physics: Condensed Matter, Vol. 25, Issue 18
  • DOI: 10.1088/0953-8984/25/18/186004

PDFgetN : a user-friendly program to extract the total scattering structure factor and the pair distribution function from neutron powder diffraction data
journal, August 2000

  • Peterson, P. F.; Gutmann, M.; Proffen, Th.
  • Journal of Applied Crystallography, Vol. 33, Issue 4
  • DOI: 10.1107/S0021889800007123

Structural and Electronic Factors Governing the Metallic and Nonmetallic Properties of the PyrochloresA2Ru2O7−y
journal, July 1997

  • Lee, K. -S.; Seo, D. -K.; Whangbo, M. -H.
  • Journal of Solid State Chemistry, Vol. 131, Issue 2
  • DOI: 10.1006/jssc.1997.7497

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Particle size effects in thick film resistors
journal, July 1982

  • Carcia, P. F.; Ferretti, A.; Suna, A.
  • Journal of Applied Physics, Vol. 53, Issue 7
  • DOI: 10.1063/1.331364

Electronic Band Structure of the Pyrochlore Ruthenium Oxides A 2 Ru 2 O 7 ( A = B i , Tl and Y)
journal, February 2000

  • Ishii, Fumiyuki; Oguchi, Tamio
  • Journal of the Physical Society of Japan, Vol. 69, Issue 2
  • DOI: 10.1143/JPSJ.69.526

EXPGUI , a graphical user interface for GSAS
journal, April 2001


Synthesis of a metallic mesoporous pyrochlore as a catalyst for lithium–O2 batteries
journal, November 2012

  • Oh, Si Hyoung; Black, Robert; Pomerantseva, Ekaterina
  • Nature Chemistry, Vol. 4, Issue 12, p. 1004-1010
  • DOI: 10.1038/nchem.1499

Transport properties of quasi-one-dimensional KRu 4 O 8
journal, April 2009


New ternary oxides of mercury with the pyrochlore structure
journal, September 1968


Atomic displacements in the charge ice pyrochlore Bi 2 Ti 2 O 6 O studied by neutron total scattering
journal, April 2010


Metallic state induced in Eu 2 Ru 2 O 7 by hole creation and orbital overlap in the t 2 g bands
journal, April 2012

  • Muñoz-Perez, S.; Cobas, R.; Cadogan, J. M.
  • Journal of Applied Physics, Vol. 111, Issue 7
  • DOI: 10.1063/1.3687147

Thermoelectric properties of the Bi2−xYxRu2O7 (x=0–2) pyrochlores
journal, April 2003


Synthesis and structural study of stoichiometric Bi2Ti2O7 pyrochlore
journal, January 2004


Effect of disorder on the temperature dependence of the resistivity of Sr Ru O 3
journal, April 2008


Magnetoresistance, noise properties and the Koshino-Taylor effect in the quasi-1D oxide KRu 4 O 8
journal, March 2012


Crystal Structure and Electrical Properties of the Pyrochlore Ruthenate Bi2-xYxRu2O7
journal, January 1993

  • Kanno, R.; Takeda, Y.; Yamamoto, T.
  • Journal of Solid State Chemistry, Vol. 102, Issue 1
  • DOI: 10.1006/jssc.1993.1012

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011


Spin glass behavior in metallic pyrochlore ruthenate Ca 2 Ru 2 O 7
journal, January 2009


Thermoelectric properties of Ln2−xBixRu2O7 pyrochlores (Ln=Nd and Yb)
journal, November 2001


PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals
journal, July 2007


Electrochemistry of ruthenates. Part 1.—Oxygen reduction on pyrochlore ruthenates
journal, January 1983

  • Egdell, Russell G.; Goodenough, John B.; Hamnett, Andrew
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 79, Issue 4
  • DOI: 10.1039/f19837900893

Oxide pyrochlores — A review
journal, January 1983

  • Subramanian, M. A.; Aravamudan, G.; Subba Rao, G. V.
  • Progress in Solid State Chemistry, Vol. 15, Issue 2
  • DOI: 10.1016/0079-6786(83)90001-8

Superconductivity in a layered perovskite without copper
journal, December 1994

  • Maeno, Y.; Hashimoto, H.; Yoshida, K.
  • Nature, Vol. 372, Issue 6506
  • DOI: 10.1038/372532a0

Influence of Structural Disorder on Hollandites A x Ru 4 O 8 (A + = K, Rb, Rb 1– x Na x )
journal, March 2016


A new family of bismuth — Precious metal pyrochlores
journal, August 1971


Electronic characterization of alkali ruthenium hollandites: KRu4O8, RbRu4O8 and Cs0.8Li0.2Ru4O8
journal, September 2004


Incoherent Bi off-centering in Bi 2 Ti 2 O 6 O and Bi 2 Ru 2 O 6 O : Insulator versus metal
journal, August 2011


Static disorder from lone-pair electrons in pyrochlores
journal, November 2002


Quasi-one-dimensional electronic structure of hollandite ruthenate K 2 Ru 8 O 16
journal, May 2011


Structural and Electronic Properties of the Ru Pyrochlores Bi 2- y Yb y Ru 2 O 7- δ
journal, October 2003

  • Li, Leqing; Kennedy, Brendan J.
  • Chemistry of Materials, Vol. 15, Issue 21
  • DOI: 10.1021/cm034503q

The electrical properties of A2[Ru2−xAx]O7−y (A = Pb or Bi) pyrochlores as a function of composition and temperature
journal, January 1988


The Intriguing Superconductivity of Strontium Ruthenate
journal, January 2001

  • Maeno, Yoshiteru; Rice, T. Maurice; Sigrist, Manfred
  • Physics Today, Vol. 54, Issue 1
  • DOI: 10.1063/1.1349611

Spin Ice State in Frustrated Magnetic Pyrochlore Materials
journal, November 2001


Building a high resolution total scattering powder diffractometer - upgrade of NPD at MLNSC
journal, December 2002

  • Proffen, T.; Egami, T.; Billinge, S. J. L.
  • Applied Physics A: Materials Science & Processing, Vol. 74, Issue 0
  • DOI: 10.1007/s003390201929

Electronic properties of the metallic pyrochlore ruthenates Pb 2 Ru 2 O 6.5 and Bi 2 Ru 2 O 7
journal, May 2006


Rationale for mixing exact exchange with density functional approximations
journal, December 1996

  • Perdew, John P.; Ernzerhof, Matthias; Burke, Kieron
  • The Journal of Chemical Physics, Vol. 105, Issue 22, p. 9982-9985
  • DOI: 10.1063/1.472933

Electrical and magnetic properties of the complete solid solution series between SrRuO 3 and LaRhO 3 : Filling t 2 g versus tilting
journal, February 2011


Structural and Bonding Trends in Ruthenium Pyrochlores
journal, November 1996


Ordering and Antiferromagnetism in Ferrites
journal, May 1956


Improved tetrahedron method for Brillouin-zone integrations
journal, June 1994


Preparation and electrical conductivity of Bi2Ru2O7 single crystals
journal, September 1984


Magnetic Interactions in Ternary Ruthenium Oxides
journal, September 1966

  • Callaghan, Alan; Moeller, Carl W.; Ward, Roland
  • Inorganic Chemistry, Vol. 5, Issue 9
  • DOI: 10.1021/ic50043a023