DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The role of nanoparticle size and ligand coverage in size focusing of colloidal metal nanoparticles

Journal Article · · Nanoscale Advances
DOI: https://doi.org/10.1039/C9NA00348G · OSTI ID:1562321
 [1];  [1]; ORCiD logo [2];  [3]; ORCiD logo [4];  [5]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemical Engineering, Virginia Polytechnic Institute and State University, Blacksburg, USA
  2. Department of Chemical Engineering, University of Pittsburgh, Pittsburgh, USA
  3. Advanced Photon Source, Argonne National Laboratory, Argonne, USA
  4. X-ray Science Division, Argonne National Laboratory, Argonne, USA
  5. Environmental Molecular Science Laboratory, Pacific Northwest National Laboratory, Richland, USA

In situ SAXS and population balance modeling (PBM) are used to discover the mechanism(s) of size focusing during Pd nanoparticle synthesis.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-06CH11357; AC05-76RL01830
OSTI ID:
1562321
Report Number(s):
PNNL-SA--161898
Journal Information:
Nanoscale Advances, Journal Name: Nanoscale Advances Journal Issue: 10 Vol. 1; ISSN 2516-0230; ISSN NAADAI
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (96)

Investigation of Indium Phosphide Nanocrystal Synthesis Using a High-Temperature and High-Pressure Continuous Flow Microreactor journal December 2010
Noble-Metal Nanocrystals with Concave Surfaces: Synthesis and Applications journal May 2012
Manipulating Local Ligand Environments for the Controlled Nucleation of Metal Nanoparticles and their Assembly into Nanodendrites journal October 2012
Hydrotalcite-Supported Gold Catalyst for the Oxidant-Free Dehydrogenation of Benzyl Alcohol: Studies on Support and Gold Size Effects journal December 2010
Preparation of monodispersed colloidal particles journal January 1987
Insights into the modeling of adsorption isotherm systems journal January 2010
Quickstep: Fast and accurate density functional calculations using a mixed Gaussian and plane waves approach journal April 2005
Quantitative Analysis of Thiolated Ligand Exchange on Gold Nanoparticles Monitored by 1 H NMR Spectroscopy journal February 2015
Chemistry and Structure of Silver Molecular Nanoparticles journal November 2018
In Situ Quick X-ray Absorption Fine Structure and Small-Angle X-ray Scattering Study of Metal Nanoparticle Growth in Water-in-Oil Microemulsions during Photoreduction journal April 2016
Enhanced Nanoparticle Size Control by Extending LaMer’s Mechanism journal August 2015
Size-Controlled Synthesis of Sub-10-nanometer Citrate-Stabilized Gold Nanoparticles and Related Optical Properties. journal February 2016
Experimental Evaluation of Kinetic and Thermodynamic Reaction Parameters of Colloidal Nanocrystals journal May 2016
Just Add Ligands: Self-Sustained Size Focusing of Colloidal Semiconductor Nanocrystals journal February 2018
Tuning Precursor Reactivity toward Nanometer-Size Control in Palladium Nanoparticles Studied by in Situ Small Angle X-ray Scattering journal January 2018
Small Angle X-ray Scattering for Nanoparticle Research journal April 2016
Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities journal September 2016
Synthesis of 1 nm Pd Nanoparticles in a Microfluidic Reactor: Insights from in Situ X-ray Absorption Fine Structure Spectroscopy and Small-Angle X-ray Scattering journal May 2015
Trade-Off between Accuracy and Universality in Linear Energy Relations for Alcohol Dehydrogenation on Transition Metals journal June 2015
Fast and Slow Ligand Exchange at the Surface of Colloidal Gold Nanoparticles journal January 2016
Simultaneous SAXS/WAXS/UV–Vis Study of the Nucleation and Growth of Nanoparticles: A Test of Classical Nucleation Theory journal July 2015
Gaining Control over Radiolytic Synthesis of Uniform Sub-3-nanometer Palladium Nanoparticles: Use of Aromatic Liquids in the Electron Microscope journal February 2016
Digestive Ripening: A Fine Chemical Machining Process on the Nanoscale journal June 2017
Dust Effects on Nucleation Kinetics and Nanoparticle Product Size Distributions: Illustrative Case Study of a Prototype Ir(0) n Transition-Metal Nanoparticle Formation System journal June 2017
Ligand-Mediated Nanocrystal Growth journal February 2018
Toward a Quantitative Understanding of the Reduction Pathways of a Salt Precursor in the Synthesis of Metal Nanocrystals journal December 2016
Quantitative Analysis of Different Formation Modes of Platinum Nanocrystals Controlled by Ligand Chemistry journal September 2017
Size-, Shape-, and Composition-Dependent Model for Metal Nanoparticle Stability Prediction journal March 2018
Thermochemical Measurements of Cation Exchange in CdSe Nanocrystals Using Isothermal Titration Calorimetry journal August 2018
Unravelling the Mechanisms of Gold–Silver Core–Shell Nanostructure Formation by in Situ TEM Using an Advanced Liquid Cell Design journal October 2018
Palladium Acetate Trimer: Understanding Its Ligand-Induced Dissociation Thermochemistry Using Isothermal Titration Calorimetry, X-ray Absorption Fine Structure, and 31 P Nuclear Magnetic Resonance journal December 2018
A Size Threshold for Enhanced Magnetoresistance in Colloidally Prepared CoFe 2 O 4 Nanoparticle Solids journal August 2018
Turkevich in New Robes: Key Questions Answered for the Most Common Gold Nanoparticle Synthesis journal June 2015
Nucleation Control of Size and Dispersity in Aggregative Nanoparticle Growth. A Study of the Coarsening Kinetics of Thiolate-Capped Gold Nanocrystals journal May 2010
Oxidative Etching and Its Role in Manipulating the Nucleation and Growth of Noble-Metal Nanocrystals journal August 2013
Kinetics and Mechanisms of Aggregative Nanocrystal Growth journal September 2013
Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications journal January 2010
Theory, Production and Mechanism of Formation of Monodispersed Hydrosols journal November 1950
Size-Dependent Dissociation pH of Thiolate Ligands from Cadmium Chalcogenide Nanocrystals journal February 2005
Size/Shape-Controlled Synthesis of Colloidal CdSe Quantum Disks: Ligand and Temperature Effects journal May 2011
Chemisorption of CO and Mechanism of CO Oxidation on Supported Platinum Nanoclusters journal March 2011
Structure Sensitivity of Alkynol Hydrogenation on Shape- and Size-Controlled Palladium Nanocrystals: Which Sites Are Most Active and Selective? journal August 2011
Nucleation is Second Order: An Apparent Kinetically Effective Nucleus of Two for Ir(0) n Nanoparticle Formation from [(1,5-COD)Ir I ·P 2 W 15 Nb 3 O 62 ] 8– Plus Hydrogen journal December 2014
Transition-Metal Nanocluster Size vs Formation Time and the Catalytically Effective Nucleus Number: A Mechanism-Based Treatment journal September 2008
Insights into the Kinetics of Semiconductor Nanocrystal Nucleation and Growth journal April 2009
Mechanism of Gold Nanoparticle Formation in the Classical Citrate Synthesis Method Derived from Coupled In Situ XANES and SAXS Evaluation journal February 2010
Transition Metal Nanocluster Formation Kinetic and Mechanistic Studies. A New Mechanism When Hydrogen Is the Reductant:  Slow, Continuous Nucleation and Fast Autocatalytic Surface Growth journal October 1997
Kinetics of II-VI and III-V Colloidal Semiconductor Nanocrystal Growth:  “Focusing” of Size Distributions journal June 1998
Shape-Controlled Synthesis of Colloidal Metal Nanocrystals: Thermodynamic versus Kinetic Products journal June 2015
Colloidal CdSe Quantum Rings journal July 2016
Nanoparticle Nucleation Is Termolecular in Metal and Involves Hydrogen: Evidence for a Kinetically Effective Nucleus of Three {Ir 3 H 2 x ·P 2 W 15 Nb 3 O 62 } 6– in Ir(0) n Nanoparticle Formation From [(1,5-COD)Ir I ·P 2 W 15 Nb 3 O 62 ] 8– Plus Dihydrogen journal April 2017
On the Size-Dependent Behavior of Nanocrystal−Ligand Bonds journal June 2006
Palladium Nanoparticle Size Effect in 1-Hexyne Selective Hydrogenation journal August 2007
Nucleation and Growth of Metal Nanoparticles during Photoreduction Using In Situ Time-Resolved SAXS Analysis journal June 2011
Ligand and Solvation Effects on the Structural and Electronic Properties of Small Gold Clusters journal February 2014
Coverage-Dependent CO Adsorption Energy from First-Principles Calculations journal March 2009
Size Focusing of Nanoparticles by Thermodynamic Control through Ligand Interactions. Molecular Clusters Compared with Nanoparticles of Metals journal March 2012
Investigation of Catalytic Finite-Size-Effects of Platinum Metal Clusters journal December 2012
On the Mechanism of Metal Nanoparticle Synthesis in the Brust–Schiffrin Method journal July 2013
On the Two-Step Mechanism for Synthesis of Transition-Metal Nanoparticles journal October 2014
Probing in situ the Nucleation and Growth of Gold Nanoparticles by Small-Angle X-ray Scattering journal June 2007
Focusing Nanocrystal Size Distributions via Production Control journal May 2011
Size Dependence of the Adsorption Energy of CO on Metal Nanoparticles: A DFT Search for the Minimum Value journal January 2012
Colloidal Nanocrystals with Inorganic Halide, Pseudohalide, and Halometallate Ligands journal June 2014
Ultrastable silver nanoparticles journal September 2013
Thermodynamic stability of ligand-protected metal nanoclusters journal July 2017
Strongly emissive perovskite nanocrystal inks for high-voltage solar cells journal December 2016
Size-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nanoparticles journal March 2018
Rigid bidentate ligands focus the size of gold nanoparticles journal January 2013
Strongest π–metal orbital coupling in a porphyrin/gold cluster system journal January 2014
Kinetics of cesium lead halide perovskite nanoparticle growth; focusing and de-focusing of size distribution journal January 2016
Dependence on size of supported Rh nanoclusters for CO adsorption journal January 2016
Redox reaction induced Ostwald ripening for size- and shape-focusing of palladium nanocrystals journal January 2015
Size- and shape-dependent catalytic performances of oxidation and reduction reactions on nanocatalysts journal January 2016
Gold nanorods with conjugated polymer ligands: sintering-free conductive inks for printed electronics journal January 2016
Colloidal nanoparticle size control: experimental and kinetic modeling investigation of the ligand–metal binding role in controlling the nucleation and growth kinetics journal January 2017
Continuum tuning of nanoparticle interfacial properties by dynamic covalent exchange journal January 2018
Ligand effect on the catalytic activity of porphyrin-protected gold clusters in the electrochemical hydrogen evolution reaction journal January 2018
The effect of surface coverage on N 2 , NO and N 2 O formation over Pt(111) journal January 2018
Digestive ripening in the formation of monodisperse silver nanospheres journal January 2018
Phase-segregated NiP x @FeP y O z core@shell nanoparticles: ready-to-use nanocatalysts for electro- and photo-catalytic water oxidation through in situ activation by structural transformation and spontaneous ligand removal journal January 2018
Detection and identification of designer drugs by nanoparticle-based NMR chemosensing journal January 2018
Controlled growth of imine-linked two-dimensional covalent organic framework nanoparticles journal January 2019
Preparing water-dispersed palladium nanoparticles via polyelectrolyte nanoreactors journal January 2010
Stability, surface features, and atom leaching of palladium nanoparticles: toward prediction of catalytic functionality journal January 2013
Further considerations on the thermodynamics of chemical equilibria and reaction rates journal January 1936
The Growth of Uniform Colloidal Dispersions journal April 1951
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal April 2010
The thermodynamics of nitrogen adsorption on nickel clusters: Ni19–Ni71 journal March 1998
Simple theory for the electronic and atomic structure of small clusters journal July 1983
Effect of particle size and surface structure on adsorption of O and OH on platinum nanoparticles: A first-principles study journal February 2008
Generalized Gradient Approximation Made Simple journal October 1996
Improvements and considerations for size distribution retrieval from small-angle scattering data by Monte Carlo methods journal February 2013
McSAS : software for the retrieval of model parameter distributions from scattering patterns journal May 2015
The role of electron irradiation history in liquid cell transmission electron microscopy journal April 2018
Real-Time Imaging of Pt3Fe Nanorod Growth in Solution journal May 2012