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Title: Formation of a uranyl hydroxide hydrate via hydration of [(UO 2 F 2 )(H 2 O)] 7 ·4H 2 O

Abstract

[(UO 2 F 2 )(H 2 O)] 7 ·4H 2 O undergoes a transformation at high humidity to a novel uranyl hydroxide hydrate with structural similarities to schoepite and metaschoepite.

Authors:
 [1]; ORCiD logo [2];  [2];  [2]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1]
  1. National Security Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, USA, Bredesen Center for Interdisciplinary Research and Graduate Education
  2. National Security Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1562317
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 36; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Kirkegaard, Marie C., Spano, Tyler L., Ambrogio, Michael W., Niedziela, J. L., Miskowiec, Andrew, Shields, Ashley E., and Anderson, Brian B. Formation of a uranyl hydroxide hydrate via hydration of [(UO 2 F 2 )(H 2 O)] 7 ·4H 2 O. United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT02835H.
Kirkegaard, Marie C., Spano, Tyler L., Ambrogio, Michael W., Niedziela, J. L., Miskowiec, Andrew, Shields, Ashley E., & Anderson, Brian B. Formation of a uranyl hydroxide hydrate via hydration of [(UO 2 F 2 )(H 2 O)] 7 ·4H 2 O. United Kingdom. doi:10.1039/C9DT02835H.
Kirkegaard, Marie C., Spano, Tyler L., Ambrogio, Michael W., Niedziela, J. L., Miskowiec, Andrew, Shields, Ashley E., and Anderson, Brian B. Tue . "Formation of a uranyl hydroxide hydrate via hydration of [(UO 2 F 2 )(H 2 O)] 7 ·4H 2 O". United Kingdom. doi:10.1039/C9DT02835H.
@article{osti_1562317,
title = {Formation of a uranyl hydroxide hydrate via hydration of [(UO 2 F 2 )(H 2 O)] 7 ·4H 2 O},
author = {Kirkegaard, Marie C. and Spano, Tyler L. and Ambrogio, Michael W. and Niedziela, J. L. and Miskowiec, Andrew and Shields, Ashley E. and Anderson, Brian B.},
abstractNote = {[(UO 2 F 2 )(H 2 O)] 7 ·4H 2 O undergoes a transformation at high humidity to a novel uranyl hydroxide hydrate with structural similarities to schoepite and metaschoepite.},
doi = {10.1039/C9DT02835H},
journal = {Dalton Transactions},
number = 36,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {9}
}

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This content will become publicly available on August 30, 2020
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Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996