skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on September 10, 2020

Title: Effect of chemical environment on the radiation chemistry of N , N -di-(2-ethylhexyl)butyramide (DEHBA) and plutonium retention

Abstract

Gamma-radiolysis of the ligand DEHBA is accelerated under biphasic acidic conditions and yields one or more plutonium complexing degradation products.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1]; ORCiD logo [4]; ORCiD logo [4];  [4]; ORCiD logo [4]
  1. Idaho National Laboratory, Center for Radiation Chemistry Research, Idaho Falls, USA
  2. Idaho National Laboratory, Center for Radiation Chemistry Research, Idaho Falls, USA, KTH Royal Institute of Technology
  3. California State University Long Beach, Department of Chemistry and Biochemistry, Long Beach, USA
  4. CEA, DEN, DMRC, Univ Montpellier, France
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1562165
Grant/Contract Number:  
AC07-05ID14517; NE0008406
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 38; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Horne, Gregory P., Zarzana, Christopher A., Grimes, Travis S., Rae, Cathy, Ceder, Joakim, Mezyk, Stephen P., Mincher, Bruce J., Charbonnel, Marie-Christine, Guilbaud, Philippe, Saint-Louis, George, and Berthon, Laurence. Effect of chemical environment on the radiation chemistry of N , N -di-(2-ethylhexyl)butyramide (DEHBA) and plutonium retention. United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT02383F.
Horne, Gregory P., Zarzana, Christopher A., Grimes, Travis S., Rae, Cathy, Ceder, Joakim, Mezyk, Stephen P., Mincher, Bruce J., Charbonnel, Marie-Christine, Guilbaud, Philippe, Saint-Louis, George, & Berthon, Laurence. Effect of chemical environment on the radiation chemistry of N , N -di-(2-ethylhexyl)butyramide (DEHBA) and plutonium retention. United Kingdom. doi:10.1039/C9DT02383F.
Horne, Gregory P., Zarzana, Christopher A., Grimes, Travis S., Rae, Cathy, Ceder, Joakim, Mezyk, Stephen P., Mincher, Bruce J., Charbonnel, Marie-Christine, Guilbaud, Philippe, Saint-Louis, George, and Berthon, Laurence. Tue . "Effect of chemical environment on the radiation chemistry of N , N -di-(2-ethylhexyl)butyramide (DEHBA) and plutonium retention". United Kingdom. doi:10.1039/C9DT02383F.
@article{osti_1562165,
title = {Effect of chemical environment on the radiation chemistry of N , N -di-(2-ethylhexyl)butyramide (DEHBA) and plutonium retention},
author = {Horne, Gregory P. and Zarzana, Christopher A. and Grimes, Travis S. and Rae, Cathy and Ceder, Joakim and Mezyk, Stephen P. and Mincher, Bruce J. and Charbonnel, Marie-Christine and Guilbaud, Philippe and Saint-Louis, George and Berthon, Laurence},
abstractNote = {Gamma-radiolysis of the ligand DEHBA is accelerated under biphasic acidic conditions and yields one or more plutonium complexing degradation products.},
doi = {10.1039/C9DT02383F},
journal = {Dalton Transactions},
number = 38,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on September 10, 2020
Publisher's Version of Record

Save / Share: