skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Ambient Synthesis of Single‐Atom Catalysts from Bulk Metal via Trapping of Atoms by Surface Dangling Bonds

Authors:
 [1];  [2];  [3];  [1];  [4];  [5];  [1];  [6];  [1];  [1];  [1];  [1];  [1];  [5];  [7];  [4];  [8];  [9]; ORCiD logo [1]
  1. Department of ChemistryHefei National Laboratory for Physical Sciences at the MicroscaleiChEM (Collaborative Innovation Center of Chemistry for Energy Materials)University of Science and Technology of China Hefei 230026 China
  2. X‐ray Science DivisionArgonne National Laboratory 9700 South Cass Avenue Lemont IL 60439 USA
  3. Provincial Key Laboratory of Oil and Gas Chemical TechnologyCollege of Chemistry and Chemical EngineeringNortheast Petroleum University Daqing 163318 P. R. China
  4. Institute of PhysicsChinese Academy of Sciences Beijing 100190 P. R. China
  5. Hefei National Laboratory for Physical Sciences at the MicroscaleUniversity of Science and Technology of China Hefei 230026 China
  6. USTC Center for Micro and Nanoscale Research and FabricationUniversity of Science and Technology of China Hefei 230026 China
  7. National Synchrotron Radiation LaboratoryUniversity of Science and Technology of China Hefei 230026 China
  8. Center for Electron Microscopy and Tianjin Key Lab of Advanced Functional Porous MaterialsInstitute for New Energy Materials and Low‐Carbon TechnologiesSchool of MaterialsTianjin University of Technology Tianjin 300384 China
  9. Institute of High Energy Physics Beijing 100049 China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1561358
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials Journal Volume: 31 Journal Issue: 44; Journal ID: ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Qu, Yunteng, Wang, Liguang, Li, Zhijun, Li, Peng, Zhang, Qinghua, Lin, Yue, Zhou, Fangyao, Wang, Huijuan, Yang, Zhengkun, Hu, Yidong, Zhu, Mengzhao, Zhao, Xuyan, Han, Xiao, Wang, Chengming, Xu, Qian, Gu, Lin, Luo, Jun, Zheng, Lirong, and Wu, Yuen. Ambient Synthesis of Single‐Atom Catalysts from Bulk Metal via Trapping of Atoms by Surface Dangling Bonds. Germany: N. p., 2019. Web. doi:10.1002/adma.201904496.
Qu, Yunteng, Wang, Liguang, Li, Zhijun, Li, Peng, Zhang, Qinghua, Lin, Yue, Zhou, Fangyao, Wang, Huijuan, Yang, Zhengkun, Hu, Yidong, Zhu, Mengzhao, Zhao, Xuyan, Han, Xiao, Wang, Chengming, Xu, Qian, Gu, Lin, Luo, Jun, Zheng, Lirong, & Wu, Yuen. Ambient Synthesis of Single‐Atom Catalysts from Bulk Metal via Trapping of Atoms by Surface Dangling Bonds. Germany. doi:10.1002/adma.201904496.
Qu, Yunteng, Wang, Liguang, Li, Zhijun, Li, Peng, Zhang, Qinghua, Lin, Yue, Zhou, Fangyao, Wang, Huijuan, Yang, Zhengkun, Hu, Yidong, Zhu, Mengzhao, Zhao, Xuyan, Han, Xiao, Wang, Chengming, Xu, Qian, Gu, Lin, Luo, Jun, Zheng, Lirong, and Wu, Yuen. Wed . "Ambient Synthesis of Single‐Atom Catalysts from Bulk Metal via Trapping of Atoms by Surface Dangling Bonds". Germany. doi:10.1002/adma.201904496.
@article{osti_1561358,
title = {Ambient Synthesis of Single‐Atom Catalysts from Bulk Metal via Trapping of Atoms by Surface Dangling Bonds},
author = {Qu, Yunteng and Wang, Liguang and Li, Zhijun and Li, Peng and Zhang, Qinghua and Lin, Yue and Zhou, Fangyao and Wang, Huijuan and Yang, Zhengkun and Hu, Yidong and Zhu, Mengzhao and Zhao, Xuyan and Han, Xiao and Wang, Chengming and Xu, Qian and Gu, Lin and Luo, Jun and Zheng, Lirong and Wu, Yuen},
abstractNote = {},
doi = {10.1002/adma.201904496},
journal = {Advanced Materials},
number = 44,
volume = 31,
place = {Germany},
year = {2019},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/adma.201904496

Citation Metrics:
Cited by: 16 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts
journal, June 2018


Heterogeneous Electrocatalyst with Molecular Cobalt Ions Serving as the Center of Active Sites
journal, January 2017

  • Wang, Jiong; Ge, Xiaoming; Liu, Zhaolin
  • Journal of the American Chemical Society, Vol. 139, Issue 5
  • DOI: 10.1021/jacs.6b10307

Ionic Exchange of Metal–Organic Frameworks to Access Single Nickel Sites for Efficient Electroreduction of CO 2
journal, June 2017

  • Zhao, Changming; Dai, Xinyao; Yao, Tao
  • Journal of the American Chemical Society, Vol. 139, Issue 24
  • DOI: 10.1021/jacs.7b02736

Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials
journal, August 2015

  • Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa
  • Nature Materials, Vol. 14, Issue 9
  • DOI: 10.1038/nmat4367

Direct observation of noble metal nanoparticles transforming to thermally stable single atoms
journal, July 2018


Controllable synthesis of RGO/Fe x O y nanocomposites as high-performance anode materials for lithium ion batteries
journal, January 2014

  • Dong, Xiangmao; Li, Li; Zhao, Chongjun
  • J. Mater. Chem. A, Vol. 2, Issue 25
  • DOI: 10.1039/c4ta01804d

Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation
journal, September 2017

  • Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu
  • Journal of the American Chemical Society, Vol. 139, Issue 40
  • DOI: 10.1021/jacs.7b06514

Single-Atom Electrocatalysts
journal, October 2017

  • Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong
  • Angewandte Chemie International Edition, Vol. 56, Issue 45
  • DOI: 10.1002/anie.201703864

A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature
journal, December 2015


Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms
journal, October 2018


Resistant in Alkaline Media Core-Shell Photocatalyst of Fe (TiO2/ Al2O3) for Degradation of Water Pollutant
journal, April 2018

  • Hossein Haghighaty, Amir; Moradi Dehaghi, Shahram
  • Oriental Journal of Chemistry, Vol. 34, Issue 2
  • DOI: 10.13005/ojc/340256

Single-Atom Pd 1 /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene
journal, August 2015

  • Yan, Huan; Cheng, Hao; Yi, Hong
  • Journal of the American Chemical Society, Vol. 137, Issue 33
  • DOI: 10.1021/jacs.5b06485

Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation
journal, July 2017

  • Zhang, Zailei; Zhu, Yihan; Asakura, Hiroyuki
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms16100

Single‐Atom Fe‐N x ‐C as an Efficient Electrocatalyst for Zinc–Air Batteries
journal, February 2019

  • Han, Junxing; Meng, Xiaoyi; Lu, Liang
  • Advanced Functional Materials, Vol. 29, Issue 41
  • DOI: 10.1002/adfm.201808872

Enhanced oxygen reduction with single-atomic-site iron catalysts for a zinc-air battery and hydrogen-air fuel cell
journal, December 2018


Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis
journal, April 2013

  • Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar300361m

Efficient hydrogen peroxide generation using reduced graphene oxide-based oxygen reduction electrocatalysts
journal, March 2018


Atomically dispersed iron hydroxide anchored on Pt for preferential oxidation of CO in H2
journal, January 2019


Rational Design of Transition Metal-Based Materials for Highly Efficient Electrocatalysis
journal, September 2018


Single-atom catalysis of CO oxidation using Pt1/FeOx
journal, July 2011

  • Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng
  • Nature Chemistry, Vol. 3, Issue 8
  • DOI: 10.1038/nchem.1095

A Sacrificial Coating Strategy Toward Enhancement of Metal–Support Interaction for Ultrastable Au Nanocatalysts
journal, December 2016

  • Zhan, Wangcheng; He, Qian; Liu, Xiaofei
  • Journal of the American Chemical Society, Vol. 138, Issue 49
  • DOI: 10.1021/jacs.6b10472

Unveiling the high-activity origin of single-atom iron catalysts for oxygen reduction reaction
journal, June 2018

  • Yang, Liu; Cheng, Daojian; Xu, Haoxiang
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 26
  • DOI: 10.1073/pnas.1800771115

Remarkable Performance of Ir 1 /FeO x Single-Atom Catalyst in Water Gas Shift Reaction
journal, October 2013

  • Lin, Jian; Wang, Aiqin; Qiao, Botao
  • Journal of the American Chemical Society, Vol. 135, Issue 41
  • DOI: 10.1021/ja408574m

Thermally stable single-atom platinum-on-ceria catalysts via atom trapping
journal, July 2016


Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
journal, August 2017


Thermal Emitting Strategy to Synthesize Atomically Dispersed Pt Metal Sites from Bulk Pt Metal
journal, March 2019

  • Qu, Yunteng; Chen, Bingxu; Li, Zhijun
  • Journal of the American Chemical Society, Vol. 141, Issue 11
  • DOI: 10.1021/jacs.8b09834

Metal (Hydr)oxides@Polymer Core–Shell Strategy to Metal Single-Atom Materials
journal, August 2017

  • Zhang, Maolin; Wang, Yang-Gang; Chen, Wenxing
  • Journal of the American Chemical Society, Vol. 139, Issue 32
  • DOI: 10.1021/jacs.7b05372

General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities
journal, January 2018


Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts
journal, August 2016

  • Yin, Peiqun; Yao, Tao; Wu, Yuen
  • Angewandte Chemie International Edition, Vol. 55, Issue 36
  • DOI: 10.1002/anie.201604802

Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts
journal, September 2015


Stabilizing a Platinum 1 Single-Atom Catalyst on Supported Phosphomolybdic Acid without Compromising Hydrogenation Activity
journal, May 2016

  • Zhang, Bin; Asakura, Hiroyuki; Zhang, Jia
  • Angewandte Chemie International Edition, Vol. 55, Issue 29
  • DOI: 10.1002/anie.201602801

Activation of surface lattice oxygen in single-atom Pt/CeO 2 for low-temperature CO oxidation
journal, December 2017


Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts
journal, March 2017


Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts
journal, March 2019