DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Impact of interfaces on the radiation response and underlying defect recovery mechanisms in nanostructured Cu-Fe-Ag

Journal Article · · Materials & Design

Newest developments in nuclear fission and fusion technology as well as planned long-distance space missions demand novel materials to withstand harsh, irradiative environments. Radiation-induced hardening and embrittlement are a concern that can lead to failure of materials deployed in these applications. Here the underlying mechanisms are accommodation and clustering of lattice defects created by the incident radiation particles. Interfaces, such as free surfaces, phase and grain boundaries, are known for trapping and annihilating defects and therefore preventing these radiation-induced defects from forming clusters. In this work, differently structured nanocomposite materials based on Cu-Fe-Ag were fabricated using a novel solid-state route, combining severe plastic deformation with thermal and electrochemical treatments. The influence of different interface types and spacings on radiation effects in these materials was investigated using nanoindentation. Interface-rich bulk nanocomposites showed a slight decrease in hardness after irradiation, whereas the properties of a nanoporous material remain mostly unchanged. An explanation for this different material behavior and its link to recovery mechanisms at interfaces is attempted in this work, paving a concept towards radiation resistant materials.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA); European Research Council (ERC)
Grant/Contract Number:
89233218CNA000001
OSTI ID:
1561077
Report Number(s):
LA-UR-18-31142; TRN: US2000585
Journal Information:
Materials & Design, Vol. 160, Issue C; ISSN 0264-1275
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 18 works
Citation information provided by
Web of Science

References (92)

Nanoporous Gold by Alloy Corrosion: Method-Structure-Property Relationships journal January 2017
Defect-interface interactions journal October 2015
Opportunities and Challenges for Materials Innovation in Nuclear Energy journal January 2013
Radiation-induced softening of Fe-Mo alloy under high- temperature electron irradiation journal April 2016
Realization and Characterization of Porous Gold for Increased Protein Coverage on Acoustic Sensors journal August 2004
The formation of supersaturated solid solutions in Fe–Cu alloys deformed by high-pressure torsion journal February 2012
Grain size threshold for enhanced irradiation resistance in nanocrystalline and ultrafine tungsten journal February 2017
Irradiation softening in pure iron single crystals journal August 1973
Radiation damage tolerant nanomaterials journal November 2013
Advanced materials for fusion technology journal November 2005
Fusion materials science: Overview of challenges and recent progress journal May 2005
Structural materials challenges for advanced reactor systems journal March 2009
Materials challenges in nuclear energy journal February 2013
Radiation effects on spacecraft materials journal April 2009
Radiation Effects in Solids journal December 1953
The Displacement of Atoms in Solids by Radiation journal January 1955
MATERIALS SCIENCE: How Does Radiation Damage Materials? journal November 2007
The radiation damage tolerance of ultra-high strength nanolayered composites journal September 2007
Interface Structure and Radiation Damage Resistance in Cu-Nb Multilayer Nanocomposites journal April 2008
Nanostructured metals under irradiation journal June 2009
Efficient Annealing of Radiation Damage Near Grain Boundaries via Interstitial Emission journal March 2010
Are Nanoporous Materials Radiation Resistant? journal June 2011
Surface effects on the radiation response of nanoporous Au foams journal November 2012
Effect of grain boundary character on sink efficiency journal October 2012
Design of Radiation Tolerant Materials Via Interface Engineering journal September 2013
Radiation damage tolerant nanomaterials journal November 2013
In situ study of defect migration kinetics in nanoporous Ag with enhanced radiation tolerance journal January 2014
The relationship between grain boundary structure, defect mobility and grain boundary sink efficiency journal March 2015
Defect-interface interactions journal October 2015
Damage-tolerant nanotwinned metals with nanovoids under radiation environments journal April 2015
In Situ Study of Defect Migration Kinetics and Self-Healing of Twin Boundaries in Heavy Ion Irradiated Nanotwinned Metals journal April 2015
Superior radiation-resistant nanoengineered austenitic 304L stainless steel for applications in extreme radiation environments journal January 2015
Grain size threshold for enhanced irradiation resistance in nanocrystalline and ultrafine tungsten journal February 2017
Achieving Radiation Tolerance through Non-Equilibrium Grain Boundary Structures journal September 2017
Radiation tolerance of nanotwinned metals – An atomistic perspective journal February 2018
Radiation damage in nanostructured materials journal July 2018
In situ studies on irradiation resistance of nanoporous Au through temperature-jump tests journal January 2018
Electrical and optical properties of Sb:SnO2 thin films obtained by the sol-gel method journal February 1997
Synthesis and characterization of electrodeposited nanocrystalline nickel–iron alloys journal April 2003
Microstructural design of hard coatings journal November 2006
Structural and thermodynamic properties of nanocrystalline fcc metals prepared by mechanical attrition journal July 1992
The synthesis and structure of nanocrystalline materials produced by mechanical attrition: A review journal March 1993
Synthesis of nanostructured materials by mechanical milling: problems and opportunities journal January 1997
Bulk nanostructured materials from severe plastic deformation journal March 2000
ARB (Accumulative Roll-Bonding) and other new Techniques to Produce Bulk Ultrafine Grained Materials journal May 2003
Challenges and advances in nanocomposite processing techniques journal November 2006
Saturation of Fragmentation During Severe Plastic Deformation journal June 2010
Advantages and Limitations of HPT: A Review journal June 2008
Surface-Stress Induced Macroscopic Bending of Nanoporous Gold Cantilevers journal May 2004
Realization and Characterization of Porous Gold for Increased Protein Coverage on Acoustic Sensors journal August 2004
Metallic Mesoporous Nanocomposites for Electrocatalysis journal June 2004
Fabrication and thermo-mechanical behavior of ultra-fine porous copper journal September 2014
Interface dominated mechanical properties of ultra-fine grained and nanoporous Au at elevated temperatures journal December 2016
Evolution of nanoporosity in dealloying journal March 2001
An Atomistic Description of Dealloying journal January 2004
Stabilized Nanoporous Metals by Dealloying Ternary Alloy Precursors journal December 2008
Nanoporous Metals by Alloy Corrosion: Formation and Mechanical Properties journal August 2009
Fabrication of crack-free nanoporous gold blanket thin films by potentiostatic dealloying journal November 2010
Nanoporous Gold by Alloy Corrosion: Method-Structure-Property Relationships journal January 2017
Heavily drawn Cu–Fe–Ag and Cu–Fe–Cr microcomposites journal June 2001
Effect of Ag on the microstructure and properties of Cu–Fe in situ composites journal November 2005
Deformation processing and strength/conductivity properties of Cu–Fe–Ag microcomposites journal February 2005
Strength of deformation processed Cu–Fe–Ag in situ composites journal February 2007
Investigation of giant magnetoresistance in magnetic, concentrated, nanostructured alloys journal April 1993
Investigation of the ternary phase diagram of mechanically alloyed FeCuAg journal April 1997
Thermal analysis of metastable Fe-Cu-Ag prepared by mechanical alloying journal February 1998
The formation of supersaturated solid solutions in Fe–Cu alloys deformed by high-pressure torsion journal February 2012
Deformation-Induced Supersaturation in Immiscible Material Systems during High-Pressure Torsion : Deformation-Induced Supersaturation journal December 2016
The influence of ∑3 twin boundaries on the formation of radiation-induced defect clusters in nanotwinned Cu journal June 2011
He+ ion irradiation response of Fe–TiO2 multilayers journal April 2013
Application of small-scale testing for investigation of ion-beam-irradiated materials journal October 2012
Small scale mechanical testing of irradiated materials journal April 2015
Space radiation dosimetry in low-Earth orbit and beyond journal September 2001
An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments journal June 1992
The correlation of indentation experiments journal April 1970
Microstructural evolution of the deformed volume beneath microindents in tungsten and copper journal June 2006
Scaling equation for yield strength of nanoporous open-cell foams journal February 2007
Mechanical response of nanoporous gold journal May 2013
Mechanical properties of bulk single crystalline nanoporous gold investigated by millimetre-scale tension and compression testing journal January 2014
Nanoporous Gold—Testing Macro-scale Samples to Probe Small-scale Mechanical Behavior journal September 2015
Irradiation softening in pure iron single crystals journal August 1973
Radiation tolerant nanocrystalline ZrN films under high dose heavy-ion irradiations journal April 2015
Radiation-induced changes in the structure and mechanical properties of Fe–Mo alloy under electron irradiation journal May 2017
Hardening by Annealing and Softening by Deformation in Nanostructured Metals journal April 2006
Mechanical properties of nanocrystalline materials journal May 2006
Deformation in nanocrystalline metals journal May 2006
Footprints of plastic deformation in nanocrystalline metals journal June 2008
Unprecedented grain size effect on stacking fault width journal September 2013
Stacking fault emission from grain boundaries: Material dependencies and grain size effects journal April 2014
Dislocation emission from deformation-distorted grain boundaries in ultrafine-grained materials journal April 2014
Dislocation Ledge Sources: Dispelling the Myth of Frank–Read Source Importance journal January 2016
Grain boundary complexions and the strength of nanocrystalline metals: Dislocation emission and propagation journal June 2018