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Title: Observation of second harmonic generation in doped polymeric carbon monoxide

Abstract

Second harmonic generation (SHG) experiments were conducted on samples of a novel material: doped polymeric CO (dp-CO) that were synthesized via synchrotron X-ray irradiation of SrC 2O 4 and high pressure. The goal of the study was to first ascertain if the novel material is rugged enough to handle high levels of radiation to enable the possible use as future sensors or optoelectronic devices. Three samples were tested. Two of the smaller samples that were synthesized in a diamond anvil cell (DAC) and recovered at ambient conditions rapidly decompose/degraded in the presence of the strong 3.6 x10 9 mW/cm 2 intensity optical beam. The larger sample that was synthesized in a Paris-Edinburgh cell at 3 GPa after 1.5 hours of hard x-ray white beam irradiation and also recovered to ambient conditions was not damaged by a 6.1 x 10 9 mW/cm 2 strength optical beam and exhibited second harmonic generation. This lends credence that this novel material (when synthesized under select conditions) may offer utility as a rugged radiation hardened and easy to manufacture nonlinear optical device.

Authors:
 [1];  [2];  [2];  [1];  [1];  [1];  [2]
  1. Univ. of Nevada Las Vegas (UNLV), Las Vegas, NV (United States)
  2. Univ. of Belgrade, Belgrade (Serbia)
Publication Date:
Research Org.:
Univ. of Nevada, Las Vegas, NV (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1560790
Alternate Identifier(s):
OSTI ID: 1561396
Grant/Contract Number:  
NA0002912; FC08-01NV14049; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Materials Letters
Additional Journal Information:
Journal Volume: 256; Journal Issue: C; Journal ID: ISSN 0167-577X
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; X-rays; high pressure; second harmonic generation; SrC2O4; optical sensor

Citation Formats

Pravica, Michael G., Rabasovic, Mihailo D., Krmpot, Aleksandar J., Cifligu, Petrika, Harris, Blake, Evlyukhin, Egor, and Nikolic, Marko G. Observation of second harmonic generation in doped polymeric carbon monoxide. United States: N. p., 2019. Web. doi:10.1016/j.matlet.2019.126629.
Pravica, Michael G., Rabasovic, Mihailo D., Krmpot, Aleksandar J., Cifligu, Petrika, Harris, Blake, Evlyukhin, Egor, & Nikolic, Marko G. Observation of second harmonic generation in doped polymeric carbon monoxide. United States. doi:10.1016/j.matlet.2019.126629.
Pravica, Michael G., Rabasovic, Mihailo D., Krmpot, Aleksandar J., Cifligu, Petrika, Harris, Blake, Evlyukhin, Egor, and Nikolic, Marko G. Sat . "Observation of second harmonic generation in doped polymeric carbon monoxide". United States. doi:10.1016/j.matlet.2019.126629.
@article{osti_1560790,
title = {Observation of second harmonic generation in doped polymeric carbon monoxide},
author = {Pravica, Michael G. and Rabasovic, Mihailo D. and Krmpot, Aleksandar J. and Cifligu, Petrika and Harris, Blake and Evlyukhin, Egor and Nikolic, Marko G.},
abstractNote = {Second harmonic generation (SHG) experiments were conducted on samples of a novel material: doped polymeric CO (dp-CO) that were synthesized via synchrotron X-ray irradiation of SrC2O4 and high pressure. The goal of the study was to first ascertain if the novel material is rugged enough to handle high levels of radiation to enable the possible use as future sensors or optoelectronic devices. Three samples were tested. Two of the smaller samples that were synthesized in a diamond anvil cell (DAC) and recovered at ambient conditions rapidly decompose/degraded in the presence of the strong 3.6 x109 mW/cm2 intensity optical beam. The larger sample that was synthesized in a Paris-Edinburgh cell at 3 GPa after 1.5 hours of hard x-ray white beam irradiation and also recovered to ambient conditions was not damaged by a 6.1 x 109 mW/cm2 strength optical beam and exhibited second harmonic generation. This lends credence that this novel material (when synthesized under select conditions) may offer utility as a rugged radiation hardened and easy to manufacture nonlinear optical device.},
doi = {10.1016/j.matlet.2019.126629},
journal = {Materials Letters},
number = C,
volume = 256,
place = {United States},
year = {2019},
month = {9}
}

Journal Article:
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This content will become publicly available on September 7, 2020
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