Laser-induced oxygen vacancies in FeCo2O4 nanoparticles for boosting oxygen evolution and reduction

Kang-Wen, Qiu; Xi, Cong; Zhang, Yan; Zhang, Rui; Li, Zhe; Sheng, Gu-Rong; Liu, Hui; Dong, Cun-Ku; Chen, Yong-Jun; Du, Xi-Wen

doi:10.1039/c9cc04283k

Title: Laser-induced oxygen vacancies in FeCo₂O₄ nanoparticles for boosting oxygen evolution and reduction

Journal Article · 28 June 2019 · ChemComm

DOI: https://doi.org/10.1039/c9cc04283k · OSTI ID:1560699

^[1]; Xi, Cong ^[1]; Zhang, Yan ^[2]; Zhang, Rui ^[1]; Li, Zhe ^[1]; Sheng, Gu-Rong ^[1]; Liu, Hui ^[1]; Dong, Cun-Ku ^[1]; Chen, Yong-Jun ^[3];

^[1]

Tianjin Unv. (China)
Tianjin Unv. (China); SLAC National Accelerator Lab., Menlo Park, CA (United States)
Hainan Univ., Haikou (China)

In this study, FeCo₂O₄ nanoparticles with abundant oxygen vacancies were produced by laser fragmentation. The oxygen vacancies can lower the thermodynamic energy barriers as well as accelerate the electron transfer, eventually promoting oxygen evolution and reduction reactions simultaneously.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1560699

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 59 Vol. 55; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (23)

Integrating NiCo Alloys with Their Oxides as Efficient Bifunctional Cathode Catalysts for Rechargeable Zinc-Air Batteries Liu, Xien; Park, Minjoon; Kim, Min Gyu Angewandte Chemie International Edition, Vol. 54, Issue 33 https://doi.org/10.1002/anie.201503612	journal	June 2015
Oxygen vacancies enhancing capacitive properties of MnO2 nanorods for wearable asymmetric supercapacitors Zhai, Teng; Xie, Shilei; Yu, Minghao Nano Energy, Vol. 8 https://doi.org/10.1016/j.nanoen.2014.06.013	journal	September 2014
Hierarchically MnO ₂ –Nanosheet Covered Submicrometer-FeCo ₂ O ₄ -Tube Forest as Binder-Free Electrodes for High Energy Density All-Solid-State Supercapacitors Zhu, Baogang; Tang, Shaochun; Vongehr, Sascha ACS Applied Materials & Interfaces, Vol. 8, Issue 7 https://doi.org/10.1021/acsami.5b11367	journal	February 2016
High-Performance Lithium-Ion Battery and Symmetric Supercapacitors Based on FeCo ₂ O ₄ Nanoflakes Electrodes Mohamed, Saad Gomaa; Chen, Chih-Jung; Chen, Chih Kai ACS Applied Materials & Interfaces, Vol. 6, Issue 24 https://doi.org/10.1021/am5068244	journal	December 2014
High-performance non-spinel cobalt–manganese mixed oxide-based bifunctional electrocatalysts for rechargeable zinc–air batteries Liu, Xien; Park, Minjoon; Kim, Min Gyu Nano Energy, Vol. 20 https://doi.org/10.1016/j.nanoen.2015.11.030	journal	February 2016
Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation Bao, Jian; Zhang, Xiaodong; Fan, Bo Angewandte Chemie, Vol. 127, Issue 25 https://doi.org/10.1002/ange.201502226	journal	May 2015
Atomic Modulation of FeCo-Nitrogen-Carbon Bifunctional Oxygen Electrodes for Rechargeable and Flexible All-Solid-State Zinc-Air Battery Su, Chang-Yuan; Cheng, Hui; Li, Wei Advanced Energy Materials, Vol. 7, Issue 13 https://doi.org/10.1002/aenm.201602420	journal	February 2017
NiFe Layered Double Hydroxide Nanoparticles on Co,N-Codoped Carbon Nanoframes as Efficient Bifunctional Catalysts for Rechargeable Zinc-Air Batteries Wang, Qing; Shang, Lu; Shi, Run Advanced Energy Materials, Vol. 7, Issue 21 https://doi.org/10.1002/aenm.201700467	journal	July 2017
A top–down strategy towards monodisperse colloidal lead sulphide quantum dots Yang, Jing; Ling, Tao; Wu, Wen-Tian Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2637	journal	April 2013
Top-Down Preparation of Active Cobalt Oxide Catalyst Zhou, Yue; Dong, Cun-Ku; Han, Li−Li ACS Catalysis, Vol. 6, Issue 10 https://doi.org/10.1021/acscatal.6b02416	journal	September 2016
A flexible solid-state electrolyte for wide-scale integration of rechargeable zinc–air batteries Fu, Jing; Zhang, Jing; Song, Xueping Energy & Environmental Science, Vol. 9, Issue 2 https://doi.org/10.1039/C5EE03404C	journal	January 2016
Tunable Bifunctional Activity of Mn _x Co _{3− x} O ₄ Nanocrystals Decorated on Carbon Nanotubes for Oxygen Electrocatalysis Zhao, Tingting; Gadipelli, Srinivas; He, Guanjie ChemSusChem, Vol. 11, Issue 8 https://doi.org/10.1002/cssc.201800049	journal	March 2018
An efficient carbon-based ORR catalyst from low-temperature etching of ZIF-67 with ultra-small cobalt nanoparticles and high yield Guo, Jian; Gadipelli, Srinivas; Yang, Yuchen Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/C8TA10925G	journal	January 2019
Mixed Transition-Metal Oxides: Design, Synthesis, and Energy-Related Applications Yuan, Changzhou; Wu, Hao Bin; Xie, Yi Angewandte Chemie International Edition, Vol. 53, Issue 6 https://doi.org/10.1002/anie.201303971	journal	January 2014
Mesoporous ZnCo2O4 nanoflakes with bifunctional electrocatalytic activities toward efficiencies of rechargeable lithium–oxygen batteries in aprotic media Hung, Tai-Feng; Mohamed, Saad Gomaa; Shen, Chin-Chang Nanoscale, Vol. 5, Issue 24 https://doi.org/10.1039/c3nr04271e	journal	January 2013
Ultrathin Icosahedral Pt-Enriched Nanocage with Excellent Oxygen Reduction Reaction Activity He, Dong Sheng; He, Daping; Wang, Jing Journal of the American Chemical Society, Vol. 138, Issue 5 https://doi.org/10.1021/jacs.5b12530	journal	January 2016
Integrating NiCo Alloys with Their Oxides as Efficient Bifunctional Cathode Catalysts for Rechargeable Zinc-Air Batteries Liu, Xien; Park, Minjoon; Kim, Min Gyu Angewandte Chemie, Vol. 127, Issue 33 https://doi.org/10.1002/ange.201503612	journal	June 2015
Switching effective oxygen reduction and evolution performance by controlled graphitization of a cobalt–nitrogen–carbon framework system Gadipelli, Srinivas; Zhao, Tingting; Shevlin, Stephen A. Energy & Environmental Science, Vol. 9, Issue 5 https://doi.org/10.1039/C6EE00551A	journal	January 2016
ZnCo ₂ O ₄ Quantum Dots Anchored on Nitrogen-Doped Carbon Nanotubes as Reversible Oxygen Reduction/Evolution Electrocatalysts Liu, Zhao-Qing; Cheng, Hui; Li, Nan Advanced Materials, Vol. 28, Issue 19 https://doi.org/10.1002/adma.201506197	journal	March 2016
Rational construction of oxygen vacancies onto tungsten trioxide to improve visible light photocatalytic water oxidation reaction Wang, Yating; Cai, Jinmeng; Wu, Moqing Applied Catalysis B: Environmental, Vol. 239 https://doi.org/10.1016/j.apcatb.2018.08.029	journal	December 2018
Covalent Hybrid of Spinel Manganese–Cobalt Oxide and Graphene as Advanced Oxygen Reduction Electrocatalysts Liang, Yongye; Wang, Hailiang; Zhou, Jigang Journal of the American Chemical Society, Vol. 134, Issue 7 https://doi.org/10.1021/ja210924t	journal	February 2012
Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation Bao, Jian; Zhang, Xiaodong; Fan, Bo Angewandte Chemie International Edition, Vol. 54, Issue 25 https://doi.org/10.1002/anie.201502226	journal	May 2015
Tunable Bifunctional Activity of Mn _x Co _{3− x} O ₄ Nanocrystals Decorated on Carbon Nanotubes for Oxygen Electrocatalysis Zhao, Tingting; Gadipelli, Srinivas; He, Guanjie ChemSusChem, Vol. 11, Issue 8 https://doi.org/10.1002/cssc.201800756	journal	April 2018

Similar Records

Engineering stable Pt nanoparticles and oxygen vacancies on defective TiO₂ via introducing strong electronic metal-support interaction for efficient CO₂ photoreduction

Journal Article · 2019 · Chemical Engineering Journal · OSTI ID:1799888

Lin, Liang-Yi; Kavadiya, Shalinee; He, Xiang; +5 more

Role of Pr-Vacancies and O-Interstitials on the Activity and Stability of (Pr_1−xLn_x)₂NiO₄ (Ln = La, Nd, Pm, Sm, Gd, Tb, Dy, and Ho) towards Oxygen Reduction Reactions: A DFT Study

Journal Article · 2021 · Journal of the Electrochemical Society · OSTI ID:1980863

Zhang, Yanxing; Wang, Wei; Wang, Yudong; +5 more

Reactivity from excited state {sup 4}FeO{sup +} + CO sampled through reaction of ground state {sup 4}FeCO{sup +} + N{sub 2}O

Journal Article · 2016 · Journal of Chemical Physics · OSTI ID:22660745

Ard, Shaun G.; Shuman, Nicholas S.; Martinez, Oscar; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE

Title: Laser-induced oxygen vacancies in FeCo2O4 nanoparticles for boosting oxygen evolution and reduction

Citation Formats

References (23)

Similar Records

Related Subjects

Title: Laser-induced oxygen vacancies in FeCo₂O₄ nanoparticles for boosting oxygen evolution and reduction