Sequential catalysis controls selectivity in electrochemical CO2 reduction on Cu

Lum, Yanwei; Ager, Joel W.

doi:10.1039/c8ee01501e

Title: Sequential catalysis controls selectivity in electrochemical CO₂ reduction on Cu

Journal Article · 06 July 2018 · Energy & Environmental Science

DOI: https://doi.org/10.1039/c8ee01501e · OSTI ID:1560561

^[1];

^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Joint Center for Artificial Photosynthesis and Materials Science Division; Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering

Electrochemical reduction of CO₂ in aqueous media is a strategy for sustainable production of fuels and commodity chemicals. Cu is the only catalyst which converts CO₂ to significant quantities of hydrocarbons and oxygenates. Here we demonstrate that oxygenate products can be favored over hydrocarbons by positioning a local source of CO generated by a CO producing catalyst (Au or Ag) in close proximity to a Cu catalyst. Use of a bimetallic device comprising interdigitated and independently controllable lines of Au and Cu allows the local CO concentration to be modulated. Notably, diffusional simulations show that the saturation concentration of CO can be exceeded locally. Actuating both the Au and Cu lines increases the oxygenate to ethylene ratio compared to actuating Cu only. Increasing the relative area of CO-producing Au relative to Cu also increases this ratio. These insights are translated into a second bimetallic system comprising Cu dots/lines patterned directly onto a Ag substrate, allowing for the distance between Cu and the CO generating metal to be precisely controlled. Controlling the relative areas of Ag and Cu allows for tuning of the oxygenate to ethylene ratio from 0.59 to 2.39 and an increase in oxygenate faradaic efficiency from 21.4% to 41.4%, while maintaining the selectivity to C₂/C₃ products in the 50–65% range. We attribute this change in selectivity to be due to an increased *CO coverage on Cu. Finally, by utilizing diffusional transport of CO to the Cu, a sequential catalysis pathway is created which allows for the control of oxygenate selectivity in aqueous CO₂ reduction.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-05CH11231; SC0004993; CHE-080405

OSTI ID:: 1560561

Alternate ID(s):: OSTI ID: 1460876

Journal Information:: Energy & Environmental Science, Vol. 11, Issue 10; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 137 works

Citation information provided by
Web of Science

References (74)

Theoretical Considerations on the Electroreduction of CO to C ₂ Species on Cu(100) Electrodes Calle-Vallejo, Federico; Koper, Marc T. M. Angewandte Chemie International Edition, Vol. 52, Issue 28 https://doi.org/10.1002/anie.201301470	journal	June 2013
Atomistic Mechanisms Underlying Selectivities in C ₁ and C ₂ Products from Electrochemical Reduction of CO on Cu(111) Xiao, Hai; Cheng, Tao; Goddard, William A. Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b06846	journal	December 2016
Facet Dependence of CO ₂ Reduction Paths on Cu Electrodes Luo, Wenjia; Nie, Xiaowa; Janik, Michael J. ACS Catalysis, Vol. 6, Issue 1 https://doi.org/10.1021/acscatal.5b01967	journal	December 2015
A Highly Selective Copper-Indium Bimetallic Electrocatalyst for the Electrochemical Reduction of Aqueous CO ₂ to CO Rasul, Shahid; Anjum, Dalaver H.; Jedidi, Abdesslem Angewandte Chemie International Edition, Vol. 54, Issue 7 https://doi.org/10.1002/anie.201410233	journal	December 2014
Nanostructured Metallic Electrocatalysts for Carbon Dioxide Reduction Lu, Qi; Rosen, Jonathan; Jiao, Feng ChemCatChem, Vol. 7, Issue 1 https://doi.org/10.1002/cctc.201402669	journal	October 2014
Electroreduction of Carbon Dioxide to Hydrocarbons Using Bimetallic Cu–Pd Catalysts with Different Mixing Patterns Ma, Sichao; Sadakiyo, Masaaki; Heima, Minako Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b10740	journal	December 2016
Electrochemical Detection of Protons Produced in an Electrode Reaction Using Interdigitated Microarray Electrodes Ojima, Hiroyuki; Umeda, Minoru; Mohamedi, Mohamed Electroanalysis, Vol. 15, Issue 21 https://doi.org/10.1002/elan.200302721	journal	November 2003
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper Li, Christina W.; Ciston, Jim; Kanan, Matthew W. Nature, Vol. 508, Issue 7497 https://doi.org/10.1038/nature13249	journal	April 2014
Extraordinary Hydrogen Evolution and Oxidation Reaction Activity from Carbon Nanotubes and Graphitic Carbons Das, Rajib Kumar; Wang, Yan; Vasilyeva, Svetlana V. ACS Nano, Vol. 8, Issue 8 https://doi.org/10.1021/nn5030225	journal	July 2014
CO-CO coupling on Cu facets: Coverage, strain and field effects Sandberg, Robert B.; Montoya, Joseph H.; Chan, Karen Surface Science, Vol. 654 https://doi.org/10.1016/j.susc.2016.08.006	journal	December 2016
Ethylene Hydrogenation over Platinum Nanoparticle Array Model Catalysts Fabricated by Electron Beam Lithography: Determination of Active Metal Surface Area Grunes, Jeff; Zhu, Ji; Anderson, Erik A. The Journal of Physical Chemistry B, Vol. 106, Issue 44 https://doi.org/10.1021/jp021641e	journal	November 2002
Cascade Catalysis for the Homogeneous Hydrogenation of CO ₂ to Methanol Huff, Chelsea A.; Sanford, Melanie S. Journal of the American Chemical Society, Vol. 133, Issue 45 https://doi.org/10.1021/ja208760j	journal	November 2011
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide Zhu, Dong Dong; Liu, Jin Long; Qiao, Shi Zhang Advanced Materials, Vol. 28, Issue 18 https://doi.org/10.1002/adma.201504766	journal	March 2016
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces Kuhl, Kendra P.; Hatsukade, Toru; Cave, Etosha R. Journal of the American Chemical Society, Vol. 136, Issue 40 https://doi.org/10.1021/ja505791r	journal	August 2014
Bubble nucleation from gas cavities — a review Jones, S. F.; Evans, G. M.; Galvin, K. P. Advances in Colloid and Interface Science, Vol. 80, Issue 1 https://doi.org/10.1016/S0001-8686(98)00074-8	journal	February 1999
The influence of pH on the reduction of CO and CO 2 to hydrocarbons on copper electrodes Schouten, Klaas Jan P.; Pérez Gallent, Elena; Koper, Marc T. M. Journal of Electroanalytical Chemistry, Vol. 716 https://doi.org/10.1016/j.jelechem.2013.08.033	journal	March 2014
Fabrication of Pt/Ru Nanoparticle Pair Arrays with Controlled Separation and their Electrocatalytic Properties Wickman, Björn; Seidel, Yvonne E.; Jusys, Zenonas ACS Nano, Vol. 5, Issue 4 https://doi.org/10.1021/nn1021692	journal	March 2011
The Tunable and Highly Selective Reduction Products on Ag@Cu Bimetallic Catalysts Toward CO ₂ Electrochemical Reduction Reaction Chang, Zhiyuan; Huo, Shengjuan; Zhang, Wei The Journal of Physical Chemistry C, Vol. 121, Issue 21 https://doi.org/10.1021/acs.jpcc.7b01586	journal	May 2017
Materials for solar fuels and chemicals Montoya, Joseph H.; Seitz, Linsey C.; Chakthranont, Pongkarn Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4778	journal	December 2016
Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K Cheng, Tao; Xiao, Hai; Goddard, William A. Proceedings of the National Academy of Sciences, Vol. 114, Issue 8 https://doi.org/10.1073/pnas.1612106114	journal	February 2017
Nucleation and growth of electrolytic gas bubbles under microgravity Sakuma, Go; Fukunaka, Yasuhiro; Matsushima, Hisayoshi International Journal of Hydrogen Energy, Vol. 39, Issue 15 https://doi.org/10.1016/j.ijhydene.2014.03.059	journal	May 2014
Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO ₂ over Cu Nanowire Arrays Ma, Ming; Djanashvili, Kristina; Smith, Wilson A. Angewandte Chemie International Edition, Vol. 55, Issue 23 https://doi.org/10.1002/anie.201601282	journal	April 2016
How to Enhance Gas Removal from Porous Electrodes? Kadyk, Thomas; Bruce, David; Eikerling, Michael Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep38780	journal	December 2016
Rotating Ring-Disc Electrode Investigation of the Aprotic Superoxide Radical Electrochemistry on Multi-Crystalline Surfaces and Correlation with Density Functional Theory Modeling: Implications for Lithium-Air Cells Sankarasubramanian, Shrihari; Seo, Jeongwook; Mizuno, Fuminori Journal of The Electrochemical Society, Vol. 163, Issue 10 https://doi.org/10.1149/2.11161610jes	journal	January 2016
Effect of CO ₂ Bubbling into Aqueous Solutions Used for Electrochemical Reduction of CO ₂ for Energy Conversion and Storage Zhong, Heng; Fujii, Katsushi; Nakano, Yoshiaki The Journal of Physical Chemistry C, Vol. 119, Issue 1 https://doi.org/10.1021/jp509043h	journal	December 2014
Ag–Sn Bimetallic Catalyst with a Core–Shell Structure for CO ₂ Reduction Luc, Wesley; Collins, Charles; Wang, Siwen Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b10435	journal	January 2017
New trends in the development of heterogeneous catalysts for electrochemical CO 2 reduction Kumar, Bijandra; Brian, Joseph P.; Atla, Veerendra Catalysis Today, Vol. 270 https://doi.org/10.1016/j.cattod.2016.02.006	journal	July 2016
Trends in electrochemical CO2 reduction activity for open and close-packed metal surfaces Shi, Chuan; Hansen, Heine A.; Lausche, Adam C. Physical Chemistry Chemical Physics, Vol. 16, Issue 10 https://doi.org/10.1039/c3cp54822h	journal	January 2014
Poisoning effect of adsorbed CO during CO ₂ electroreduction on late transition metals Akhade, Sneha A.; Luo, Wenjia; Nie, Xiaowa Phys. Chem. Chem. Phys., Vol. 16, Issue 38 https://doi.org/10.1039/C4CP03340J	journal	January 2014
Importance of Ag–Cu Biphasic Boundaries for Selective Electrochemical Reduction of CO ₂ to Ethanol Lee, Seunghwa; Park, Gibeom; Lee, Jaeyoung ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b02822	journal	November 2017
Controlled electrochemical gas bubble release from electrodes entirely and partially covered with hydrophobic materials Brussieux, C.; Viers, Ph.; Roustan, H. Electrochimica Acta, Vol. 56, Issue 20 https://doi.org/10.1016/j.electacta.2011.04.104	journal	August 2011
The Importance of Cannizzaro-Type Reactions during Electrocatalytic Reduction of Carbon Dioxide Birdja, Yuvraj Y.; Koper, Marc T. M. Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b12008	journal	January 2017
Tuning the Selectivity of Carbon Dioxide Electroreduction toward Ethanol on Oxide-Derived Cu _x Zn Catalysts Ren, Dan; Ang, Bridget Su-Hui; Yeo, Boon Siang ACS Catalysis, Vol. 6, Issue 12 https://doi.org/10.1021/acscatal.6b02162	journal	November 2016
CO ₂ reduction: the quest for electrocatalytic materials Khezri, Bahareh; Fisher, Adrian C.; Pumera, Martin Journal of Materials Chemistry A, Vol. 5, Issue 18 https://doi.org/10.1039/C6TA09875D	journal	January 2017
Sustainable hydrocarbon fuels by recycling CO 2 and H 2 O with renewable or nuclear energy Graves, Christopher; Ebbesen, Sune D.; Mogensen, Mogens Renewable and Sustainable Energy Reviews, Vol. 15, Issue 1 https://doi.org/10.1016/j.rser.2010.07.014	journal	January 2011
Substrate channelling as an approach to cascade reactions Wheeldon, Ian; Minteer, Shelley D.; Banta, Scott Nature Chemistry, Vol. 8, Issue 4 https://doi.org/10.1038/nchem.2459	journal	March 2016
Performance Limits of Photoelectrochemical CO ₂ Reduction Based on Known Electrocatalysts and the Case for Two-Electron Reduction Products Vesborg, Peter C. K.; Seger, Brian Chemistry of Materials, Vol. 28, Issue 24 https://doi.org/10.1021/acs.chemmater.6b03927	journal	December 2016
Monte Carlo simulations of a simple model for the electrocatalytic CO oxidation on platinum Koper, M. T. M.; Jansen, A. P. J.; van Santen, R. A. The Journal of Chemical Physics, Vol. 109, Issue 14 https://doi.org/10.1063/1.477230	journal	October 1998
Thermodynamic and achievable efficiencies for solar-driven electrochemical reduction of carbon dioxide to transportation fuels Singh, Meenesh R.; Clark, Ezra L.; Bell, Alexis T. Proceedings of the National Academy of Sciences, Vol. 112, Issue 45 https://doi.org/10.1073/pnas.1519212112	journal	October 2015
A review of the aqueous electrochemical reduction of CO₂ to hydrocarbons at copper Gattrell, M.; Gupta, N.; Co, A. Journal of Electroanalytical Chemistry, Vol. 594, Issue 1, p. 1-19 https://doi.org/10.1016/j.jelechem.2006.05.013	journal	August 2006
Efficient solar-driven electrochemical CO ₂ reduction to hydrocarbons and oxygenates Gurudayal, Gurudayal; Bullock, James; Srankó, Dávid F. Energy & Environmental Science, Vol. 10, Issue 10 https://doi.org/10.1039/C7EE01764B	journal	January 2017
CO ₂ reduction to acetate in mixtures of ultrasmall (Cu) _n ,(Ag) _m bimetallic nanoparticles Wang, Ying; Wang, Degao; Dares, Christopher J. Proceedings of the National Academy of Sciences, Vol. 115, Issue 2 https://doi.org/10.1073/pnas.1713962115	journal	December 2017
Lateral Diffusion of Thiol Ligands on the Surface of Au Nanoparticles: An Electron Paramagnetic Resonance Study Ionita, Petre; Volkov, Aleksei; Jeschke, Gunnar Analytical Chemistry, Vol. 80, Issue 1 https://doi.org/10.1021/ac071266s	journal	January 2008
Electrochemical Reduction of CO at a Copper Electrode Hori, Yoshio; Takahashi, Ryutaro; Yoshinami, Yuzuru The Journal of Physical Chemistry B, Vol. 101, Issue 36 https://doi.org/10.1021/jp970284i	journal	September 1997
Cu–Sn Bimetallic Catalyst for Selective Aqueous Electroreduction of CO ₂ to CO Sarfraz, Saad; Garcia-Esparza, Angel T.; Jedidi, Abdesslem ACS Catalysis, Vol. 6, Issue 5 https://doi.org/10.1021/acscatal.6b00269	journal	April 2016
Lattice Gas Model for CO Electrooxidation on Pt−Ru Bimetallic Surfaces Koper, M. T. M.; Lukkien, J. J.; Jansen, A. P. J. The Journal of Physical Chemistry B, Vol. 103, Issue 26 https://doi.org/10.1021/jp990520k	journal	July 1999
Nanostructured electrocatalysts with tunable activity and selectivity Mistry, Hemma; Varela, Ana Sofia; Kühl, Stefanie Nature Reviews Materials, Vol. 1, Issue 4 https://doi.org/10.1038/natrevmats.2016.9	journal	March 2016
Tandem Catalysis for CO ₂ Hydrogenation to C ₂ –C ₄ Hydrocarbons Xie, Chenlu; Chen, Chen; Yu, Yi Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b01139	journal	May 2017
Selectivity of CO ₂ Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps Nie, Xiaowa; Esopi, Monica R.; Janik, Michael J. Angewandte Chemie International Edition, Vol. 52, Issue 9 https://doi.org/10.1002/anie.201208320	journal	January 2013
Use of a Dynamic Monte Carlo Simulation in the Study of Nucleation-and-Growth Models for CO Electrochemical Oxidation ^† Korzeniewski, Carol; Kardash, Dawn The Journal of Physical Chemistry B, Vol. 105, Issue 37 https://doi.org/10.1021/jp0114788	journal	September 2001
Bubble Formation at a Gas-Evolving Microelectrode Fernández, Damaris; Maurer, Paco; Martine, Milena Langmuir, Vol. 30, Issue 43 https://doi.org/10.1021/la500234r	journal	April 2014
Building Blocks for High Performance in Electrocatalytic CO ₂ Reduction: Materials, Optimization Strategies, and Device Engineering Larrazábal, Gastón O.; Martín, Antonio J.; Pérez-Ramírez, Javier The Journal of Physical Chemistry Letters, Vol. 8, Issue 16 https://doi.org/10.1021/acs.jpclett.7b01380	journal	August 2017
Electrochemical Reduction of CO ₂ Using Copper Single-Crystal Surfaces: Effects of CO* Coverage on the Selective Formation of Ethylene Huang, Yun; Handoko, Albertus D.; Hirunsit, Pussana ACS Catalysis, Vol. 7, Issue 3 https://doi.org/10.1021/acscatal.6b03147	journal	February 2017
Using Rotating Ring Disc Electrode Voltammetry to Quantify the Superoxide Radical Stability of Aprotic Li–Air Battery Electrolytes Herranz, Juan; Garsuch, Arnd; Gasteiger, Hubert A. The Journal of Physical Chemistry C, Vol. 116, Issue 36 https://doi.org/10.1021/jp304277z	journal	September 2012
The path towards sustainable energy Chu, Steven; Cui, Yi; Liu, Nian Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4834	journal	December 2016
Electrochemical CO ₂ Reduction over Compressively Strained CuAg Surface Alloys with Enhanced Multi-Carbon Oxygenate Selectivity Clark, Ezra L.; Hahn, Christopher; Jaramillo, Thomas F. Journal of the American Chemical Society, Vol. 139, Issue 44 https://doi.org/10.1021/jacs.7b08607	journal	October 2017
Calculation for the cathode surface concentrations in the electrochemical reduction of CO2 in KHCO3 solutions Gupta, N.; Gattrell, M.; MacDougall, B. Journal of Applied Electrochemistry, Vol. 36, Issue 2 https://doi.org/10.1007/s10800-005-9058-y	journal	October 2005
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels Peterson, Andrew A.; Abild-Pedersen, Frank; Studt, Felix Energy & Environmental Science, Vol. 3, Issue 9 https://doi.org/10.1039/c0ee00071j	journal	January 2010
Artificial Photosynthesis for Sustainable Fuel and Chemical Production Kim, Dohyung; Sakimoto, Kelsey K.; Hong, Dachao Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201409116	journal	January 2015
Electroanalysis with interdigitated array microelectrodes Niwa, Osamu Electroanalysis, Vol. 7, Issue 7 https://doi.org/10.1002/elan.1140070702	journal	July 1995
Recycling of carbon dioxide to methanol and derived products – closing the loop Goeppert, Alain; Czaun, Miklos; Jones, John-Paul Chem. Soc. Rev., Vol. 43, Issue 23 https://doi.org/10.1039/C4CS00122B	journal	January 2014
Current Status and Bioinspired Perspective of Electrochemical Conversion of CO ₂ to a Long-Chain Hydrocarbon Yang, Ki Dong; Lee, Chan Woo; Jin, Kyoungsuk The Journal of Physical Chemistry Letters, Vol. 8, Issue 2 https://doi.org/10.1021/acs.jpclett.6b02748	journal	January 2017
H2 evolution at Si-based metal–insulator–semiconductor photoelectrodes enhanced by inversion channel charge collection and H spillover Esposito, Daniel V.; Levin, Igor; Moffat, Thomas P. Nature Materials, Vol. 12, Issue 6 https://doi.org/10.1038/nmat3626	journal	May 2013
Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles Kim, Dohyung; Resasco, Joaquin; Yu, Yi Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5948	journal	September 2014
Mechanistic Explanation of the pH Dependence and Onset Potentials for Hydrocarbon Products from Electrochemical Reduction of CO on Cu (111) Xiao, Hai; Cheng, Tao; Goddard, William A. Journal of the American Chemical Society, Vol. 138, Issue 2 https://doi.org/10.1021/jacs.5b11390	journal	January 2016
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21234j	journal	January 2012
Bioinspired Approach to Multienzyme Cascade System Construction for Efficient Carbon Dioxide Reduction Wang, Xiaoli; Li, Zheng; Shi, Jiafu ACS Catalysis, Vol. 4, Issue 3 https://doi.org/10.1021/cs401096c	journal	January 2014
Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide Kortlever, Ruud; Shen, Jing; Schouten, Klaas Jan P. The Journal of Physical Chemistry Letters, Vol. 6, Issue 20 https://doi.org/10.1021/acs.jpclett.5b01559	journal	September 2015
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels Qiao, Jinli; Liu, Yuyu; Hong, Feng Chem. Soc. Rev., Vol. 43, Issue 2 https://doi.org/10.1039/C3CS60323G	journal	January 2014
Free-Energy Barriers and Reaction Mechanisms for the Electrochemical Reduction of CO on the Cu(100) Surface, Including Multiple Layers of Explicit Solvent at pH 0 Cheng, Tao; Xiao, Hai; Goddard, William A. The Journal of Physical Chemistry Letters, Vol. 6, Issue 23 https://doi.org/10.1021/acs.jpclett.5b02247	journal	November 2015
A Highly Selective Copper-Indium Bimetallic Electrocatalyst for the Electrochemical Reduction of Aqueous CO ₂ to CO Rasul, Shahid; Anjum, Dalaver H.; Jedidi, Abdesslem Angewandte Chemie, Vol. 127, Issue 7 https://doi.org/10.1002/ange.201410233	journal	December 2014
Theoretical Considerations on the Electroreduction of CO to C ₂ Species on Cu(100) Electrodes Calle-Vallejo, Federico; Koper, Marc T. M. Angewandte Chemie, Vol. 125, Issue 28 https://doi.org/10.1002/ange.201301470	journal	June 2013
Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO ₂ over Cu Nanowire Arrays Ma, Ming; Djanashvili, Kristina; Smith, Wilson A. Angewandte Chemie, Vol. 128, Issue 23 https://doi.org/10.1002/ange.201601282	journal	April 2016
Selectivity of CO 2 Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps Nie, Xiaowa; Esopi, Monica R.; Janik, Michael J. Angewandte Chemie, Vol. 125, Issue 9 https://doi.org/10.1002/ange.201208320	journal	January 2013

Cited By (8)

Electrochemistry at Deep‐Sea Hydrothermal Vents: Utilization of the Thermodynamic Driving Force towards the Autotrophic Origin of Life Ooka, Hideshi; McGlynn, Shawn E.; Nakamura, Ryuhei ChemElectroChem, Vol. 6, Issue 5 https://doi.org/10.1002/celc.201801432	journal	January 2019
Electrochemical Carbon Dioxide Splitting Xie, Jiafang; Huang, Yiyin; Wu, Maoxiang ChemElectroChem, Vol. 6, Issue 6 https://doi.org/10.1002/celc.201801716	journal	February 2019
Unveiling Electrochemical Reaction Pathways of CO ₂ Reduction to C _N Species at S‐Vacancies of MoS ₂ Kang, Sungwoo; Han, Seungwu; Kang, Youngho ChemSusChem, Vol. 12, Issue 12 https://doi.org/10.1002/cssc.201900779	journal	May 2019
Rational Design of Ag‐Based Catalysts for the Electrochemical CO ₂ Reduction to CO: A Review Sun, Dalei; Xu, Xiaomin; Qin, Yanling ChemSusChem, Vol. 13, Issue 1 https://doi.org/10.1002/cssc.201902061	journal	December 2019
Mechanistic reaction pathways of enhanced ethylene yields during electroreduction of CO2–CO co-feeds on Cu and Cu-tandem electrocatalysts Wang, Xingli; de Araújo, Jorge Ferreira; Ju, Wen Nature Nanotechnology, Vol. 14, Issue 11 https://doi.org/10.1038/s41565-019-0551-6	journal	October 2019
Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products Gao, Dunfeng; Arán-Ais, Rosa M.; Jeon, Hyo Sang Nature Catalysis, Vol. 2, Issue 3 https://doi.org/10.1038/s41929-019-0235-5	journal	March 2019
From CO ₂ methanation to ambitious long-chain hydrocarbons: alternative fuels paving the path to sustainability Marques Mota, Filipe; Kim, Dong Ha Chemical Society Reviews, Vol. 48, Issue 1 https://doi.org/10.1039/c8cs00527c	journal	January 2019
Selective electrochemical CO ₂ conversion to multicarbon alcohols on highly efficient N-doped porous carbon-supported Cu catalysts Han, Hyunsu; Noh, Yuseong; Kim, Yoongon Green Chemistry, Vol. 22, Issue 1 https://doi.org/10.1039/c9gc03088c	journal	January 2020

Similar Records

Copper sulfide as the cation exchange template for synthesis of bimetallic catalysts for CO₂ electroreduction

Journal Article · 2021 · RSC Advances · OSTI ID:1806235

Li, Jinghan; Li, Junrui; Dun, Chaochao; +5 more

Shape-Controlled Synthesis of Copper Nanocrystals for Plasmonic, Biomedical, and Electrocatalytic Applications

Journal Article · 2022 · Accounts of Materials Research · OSTI ID:2008039

Lyu, Zhiheng; Shang, Yuxin; Xia, Younan

Si photocathode with Ag-supported dendritic Cu catalyst for CO ₂ reduction

Journal Article · 2019 · Energy & Environmental Science · OSTI ID:1603508

Gurudayal, Gurudayal; Beeman, Jeffrey W.; Bullock, James; +7 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Sequential catalysis controls selectivity in electrochemical CO2 reduction on Cu

Citation Formats

References (74)

Cited By (8)

Similar Records

Related Subjects

Title: Sequential catalysis controls selectivity in electrochemical CO₂ reduction on Cu