Lithium aluminum–layered double hydroxide chlorides (LDH): Formation enthalpies and energetics for lithium ion capture
Abstract
Abstract Layered aluminum double hydroxide chloride sorbents, LiCl∙Al 2 ( OH ) 6 . nH 2 O, Li‐ LDH , have shown promising application in selective Li extraction from geothermal brines. Maintaining LiCl uptake capacity and retaining a long cycle life are critical to widespread application of sorbent materials. To elucidate the energetics of Li capture, enthalpies of LDH with different Li content have been measured by acid solution calorimetry. The formation enthalpies generally become less exothermic as the Li content increases, which indicates that Li intercalation destabilizes the structure, and the enthalpies seem to approach a limit after the Li content x = 2Li/Al exceeds 1. To improve stability, metal doping of the aluminum LDH structure with iron was performed. Introduction of a metal with greater electron density but a similar ionic radius was postulated to improve the stability of the LDH crystal structure. The calorimetric results from Fe‐doped LDH samples corroborate this as they are more exothermic than LDH ‐lacking Fe. This suggests that Fe doping is an effective way to stabilize the LDH phase.
- Authors:
-
- Univ. of California, Davis, CA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); The Univ. of Tennessee, Knoxville, TN (United States)
- Rutgers Univ., Piscataway, NJ (United States)
- Alger Alternative Energy, LLC, Brawley, CA (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1560502
- Alternate Identifier(s):
- OSTI ID: 1787126
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Ceramic Society
- Additional Journal Information:
- Journal Volume: 102; Journal Issue: 5; Journal ID: ISSN 0002-7820
- Publisher:
- American Ceramic Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; heat capacity; high‐temperature calorimetry; lithium aluminum hydroxide chloride; lithium extraction; sorbents
Citation Formats
Wu, Lili, Li, Ling, Evans, Samuel F., Eskander, Tessa A., Moyer, Bruce A., Hu, Zhichao, Antonick, Paul J., Harrison, Stephen, Paranthaman, M. Parans, Riman, Richard, and Navrotsky, Alexandra. Lithium aluminum–layered double hydroxide chlorides (LDH): Formation enthalpies and energetics for lithium ion capture. United States: N. p., 2018.
Web. doi:10.1111/jace.16150.
Wu, Lili, Li, Ling, Evans, Samuel F., Eskander, Tessa A., Moyer, Bruce A., Hu, Zhichao, Antonick, Paul J., Harrison, Stephen, Paranthaman, M. Parans, Riman, Richard, & Navrotsky, Alexandra. Lithium aluminum–layered double hydroxide chlorides (LDH): Formation enthalpies and energetics for lithium ion capture. United States. https://doi.org/10.1111/jace.16150
Wu, Lili, Li, Ling, Evans, Samuel F., Eskander, Tessa A., Moyer, Bruce A., Hu, Zhichao, Antonick, Paul J., Harrison, Stephen, Paranthaman, M. Parans, Riman, Richard, and Navrotsky, Alexandra. Sat .
"Lithium aluminum–layered double hydroxide chlorides (LDH): Formation enthalpies and energetics for lithium ion capture". United States. https://doi.org/10.1111/jace.16150. https://www.osti.gov/servlets/purl/1560502.
@article{osti_1560502,
title = {Lithium aluminum–layered double hydroxide chlorides (LDH): Formation enthalpies and energetics for lithium ion capture},
author = {Wu, Lili and Li, Ling and Evans, Samuel F. and Eskander, Tessa A. and Moyer, Bruce A. and Hu, Zhichao and Antonick, Paul J. and Harrison, Stephen and Paranthaman, M. Parans and Riman, Richard and Navrotsky, Alexandra},
abstractNote = {Abstract Layered aluminum double hydroxide chloride sorbents, LiCl∙Al 2 ( OH ) 6 . nH 2 O, Li‐ LDH , have shown promising application in selective Li extraction from geothermal brines. Maintaining LiCl uptake capacity and retaining a long cycle life are critical to widespread application of sorbent materials. To elucidate the energetics of Li capture, enthalpies of LDH with different Li content have been measured by acid solution calorimetry. The formation enthalpies generally become less exothermic as the Li content increases, which indicates that Li intercalation destabilizes the structure, and the enthalpies seem to approach a limit after the Li content x = 2Li/Al exceeds 1. To improve stability, metal doping of the aluminum LDH structure with iron was performed. Introduction of a metal with greater electron density but a similar ionic radius was postulated to improve the stability of the LDH crystal structure. The calorimetric results from Fe‐doped LDH samples corroborate this as they are more exothermic than LDH ‐lacking Fe. This suggests that Fe doping is an effective way to stabilize the LDH phase.},
doi = {10.1111/jace.16150},
journal = {Journal of the American Ceramic Society},
number = 5,
volume = 102,
place = {United States},
year = {Sat Oct 13 00:00:00 EDT 2018},
month = {Sat Oct 13 00:00:00 EDT 2018}
}
Web of Science
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