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Title: CuS and Cu 2S as Cathode Materials for Lithium Batteries: A Review [A Review on CuS and Cu 2S as Cathode Materials for Lithium Batteries]

Abstract

Nowadays, lithium-ion batteries (LIBs) take a very important role for energy storage. LIBs are dominant in consumer electronics, and they have also entered the market of hybrid electric vehicles (HEVs), plug-in HEVs, and pure EVs. However, state-of-the-art LIBs are electrochemically intercalation-based and are still limited in energy density and power rates. To address these challenges and others (e. g. safety issues and cost), conversion-based copper sulfides (Cu xS, 1≤x≤2) have been investigated as alternative cathodes for improved electrochemical performance, that is, higher energy density, better cycling stability, and enhanced rate capability. In this paper, we summarize the recent research progress on Cu xS to gain a better understanding of the material's electrochemical mechanisms and develop feasible strategies for improving its performance.

Authors:
 [1];  [2]; ORCiD logo [3]
  1. Univ. of Arkansas, Fayetteville, AR (United States); Georgia Inst. of Technology, Atlanta, GA (United States)
  2. Argonne National Lab. (ANL), Lemont, IL (United States)
  3. Univ. of Arkansas, Fayetteville, AR (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V). Battery Materials Research (BMR) Program
OSTI Identifier:
1559979
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
ChemElectroChem
Additional Journal Information:
Journal Volume: 6; Journal Issue: 11; Journal ID: ISSN 2196-0216
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; conversion; copper sulfides; electrochemistry; energy storage; lithium batteries

Citation Formats

Jiang, Kyle, Chen, Zonghai, and Meng, Xiangbo. CuS and Cu2S as Cathode Materials for Lithium Batteries: A Review [A Review on CuS and Cu2S as Cathode Materials for Lithium Batteries]. United States: N. p., 2019. Web. doi:10.1002/celc.201900066.
Jiang, Kyle, Chen, Zonghai, & Meng, Xiangbo. CuS and Cu2S as Cathode Materials for Lithium Batteries: A Review [A Review on CuS and Cu2S as Cathode Materials for Lithium Batteries]. United States. doi:10.1002/celc.201900066.
Jiang, Kyle, Chen, Zonghai, and Meng, Xiangbo. Wed . "CuS and Cu2S as Cathode Materials for Lithium Batteries: A Review [A Review on CuS and Cu2S as Cathode Materials for Lithium Batteries]". United States. doi:10.1002/celc.201900066.
@article{osti_1559979,
title = {CuS and Cu2S as Cathode Materials for Lithium Batteries: A Review [A Review on CuS and Cu2S as Cathode Materials for Lithium Batteries]},
author = {Jiang, Kyle and Chen, Zonghai and Meng, Xiangbo},
abstractNote = {Nowadays, lithium-ion batteries (LIBs) take a very important role for energy storage. LIBs are dominant in consumer electronics, and they have also entered the market of hybrid electric vehicles (HEVs), plug-in HEVs, and pure EVs. However, state-of-the-art LIBs are electrochemically intercalation-based and are still limited in energy density and power rates. To address these challenges and others (e. g. safety issues and cost), conversion-based copper sulfides (CuxS, 1≤x≤2) have been investigated as alternative cathodes for improved electrochemical performance, that is, higher energy density, better cycling stability, and enhanced rate capability. In this paper, we summarize the recent research progress on CuxS to gain a better understanding of the material's electrochemical mechanisms and develop feasible strategies for improving its performance.},
doi = {10.1002/celc.201900066},
journal = {ChemElectroChem},
number = 11,
volume = 6,
place = {United States},
year = {2019},
month = {2}
}

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