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Title: Review—Electrochemical Measurements in Molten Salt Systems: A Guide and Perspective

Journal Article · · Journal of the Electrochemical Society
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [2]
  1. Idaho National Lab. (INL), Idaho Falls, ID (United States). Pyrochemistry and Molten Salt Systems Dept.
  2. Idaho National Lab. (INL), Idaho Falls, ID (United States). Material Minimization, Security & International Safeguards Dept.

Practical information is provided on electrochemical measurements in molten salt systems. The emphasis is on chloride and fluoride systems, but the principles are applicable to any high temperature molten salt or molten oxide electrolyte system. Considerations are given to topics such as the functionality of electrochemical measurement equipment, reference electrodes, materials selection and chemical compatibility, interpretation of electrochemical measurement signals, molten salt properties, and laboratory practices.

Research Organization:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE)
Grant/Contract Number:
AC07-05ID14517
OSTI ID:
1559943
Report Number(s):
INL/JOU-19-54206-Rev000; TRN: US2000436
Journal Information:
Journal of the Electrochemical Society, Vol. 166, Issue 13; ISSN 0013-4651
Publisher:
The Electrochemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

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A Robust Alumina Membrane Reference Electrode for High Temperature Molten Salts journal January 2012
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Dynamic Reference Electrode development for redox potential measurements in fluoride molten salt at high temperature text January 2016
Dynamic Reference Electrode development for redox potential measurements in fluoride molten salt at high temperature text January 2016

Figures / Tables (14)