Tunable multiferroic order parameters in Sr1-xBaxMn1-yTiyO3

Chapagain, Kamal; Brown, Dennis E.; Kolesnik, Stanislaw; Lapidus, Saul; Haberl, Bianca; Molaison, Jamie; Lin, Chuanlong; Kenney-Benson, Curtis; Park, Changyong; Pietosa, Jaroslaw; Markiewicz, Ewa; Andrzejewski, Bartlomiej; Lynn, Jeffrey W.; Rosenkranz, Stephan; Dabrowski, Bogdan; Chmaissem, Omar

doi:10.1103/PhysRevMaterials.3.084401

Title: Tunable multiferroic order parameters in $S r_{1 - x} B a_{x} M n_{1 - y} T i_{y} O_{3}$

Abstract

Responding to the rapidly increasing demand for efficient energy usage and increased speed and functionality of electronic and spintronic devices, multiferroic oxides have recently emerged as key materials capable of tackling this multifaceted challenge. In this paper, we describe the development of single-site manganese-based multiferroic perovskite materials with modest amounts of nonmagnetic Ti substituted at the magnetic Mn site in Sr_1-xBa_xMn_1-yTi_yO₃ (SBMTO). Significantly enhanced properties were achieved with ferroelectric-type structural transition temperatures boosted to ~430 K. Ferroelectric distortions with large spontaneous polarization values of ~30 mu C cm², derived from a point charge model, are similar in magnitude to those of the prototypical nonmagnetic BaTiO₃. Temperature dependence of the system's properties was investigated by synchrotron x-ray powder diffraction and neutron powder diffraction at ambient and high pressures. Various relationships were determined between the structural and magnetic properties, Ba and Ti contents, and T_N and T_C. Most importantly, our results demonstrate the large coupling between the magnetic and ferroelectric order parameters and the wide tunability of this coupling by slight variations of the material's stoichiometry.

Authors:

^[1]; Brown, Dennis E. ^[1]; Kolesnik, Stanislaw ^[1]; Lapidus, Saul ^[2]; Haberl, Bianca ^[3]; Molaison, Jamie ^[3]; Lin, Chuanlong ^[4]; Kenney-Benson, Curtis ^[2]; Park, Changyong ^[2]; Pietosa, Jaroslaw ^[5]; Markiewicz, Ewa ^[6]; Andrzejewski, Bartlomiej ^[6]; Lynn, Jeffrey W. ^[7]; Rosenkranz, Stephan ^[2]; Dabrowski, Bogdan ^[5]; Chmaissem, Omar ^[8]

Northern Illinois Univ., DeKalb, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Carnegie Inst. of Washington, Washington, DC (United States); Center for High Pressure Science and Technology Advanced Research, Beijing (China)
Polish Academy of Sciences, Warsaw (Poland)
Polish Academy of Sciences, Poznan (Poland)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
Northern Illinois Univ., DeKalb, IL (United States); Argonne National Lab. (ANL), Lemont, IL (United States)

Publication Date:: 2019-08-01

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

OSTI Identifier:: 1559937

Alternate Identifier(s):: OSTI ID: 1546839; OSTI ID: 1606702

Grant/Contract Number:: AC02-06CH11357; AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review Materials

Additional Journal Information:: Journal Volume: 3; Journal Issue: 8; Journal ID: ISSN 2475-9953

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Chapagain, Kamal, Brown, Dennis E., Kolesnik, Stanislaw, Lapidus, Saul, Haberl, Bianca, Molaison, Jamie, Lin, Chuanlong, Kenney-Benson, Curtis, Park, Changyong, Pietosa, Jaroslaw, Markiewicz, Ewa, Andrzejewski, Bartlomiej, Lynn, Jeffrey W., Rosenkranz, Stephan, Dabrowski, Bogdan, and Chmaissem, Omar. Tunable multiferroic order parameters in Sr1-xBaxMn1-yTiyO3.  United States: N. p., 2019. 
Web.  doi:10.1103/PhysRevMaterials.3.084401.

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                    Chapagain, Kamal, Brown, Dennis E., Kolesnik, Stanislaw, Lapidus, Saul, Haberl, Bianca, Molaison, Jamie, Lin, Chuanlong, Kenney-Benson, Curtis, Park, Changyong, Pietosa, Jaroslaw, Markiewicz, Ewa, Andrzejewski, Bartlomiej, Lynn, Jeffrey W., Rosenkranz, Stephan, Dabrowski, Bogdan, & Chmaissem, Omar. Tunable multiferroic order parameters in Sr1-xBaxMn1-yTiyO3.  United States.  https://doi.org/10.1103/PhysRevMaterials.3.084401

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                    Chapagain, Kamal, Brown, Dennis E., Kolesnik, Stanislaw, Lapidus, Saul, Haberl, Bianca, Molaison, Jamie, Lin, Chuanlong, Kenney-Benson, Curtis, Park, Changyong, Pietosa, Jaroslaw, Markiewicz, Ewa, Andrzejewski, Bartlomiej, Lynn, Jeffrey W., Rosenkranz, Stephan, Dabrowski, Bogdan, and Chmaissem, Omar. Thu .  
"Tunable multiferroic order parameters in Sr1-xBaxMn1-yTiyO3".  United States.  https://doi.org/10.1103/PhysRevMaterials.3.084401.  https://www.osti.gov/servlets/purl/1559937.

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@article{osti_1559937,

  title        = {Tunable multiferroic order parameters in Sr1-xBaxMn1-yTiyO3},

  author       = {Chapagain, Kamal and Brown, Dennis E. and Kolesnik, Stanislaw and Lapidus, Saul and Haberl, Bianca and Molaison, Jamie and Lin, Chuanlong and Kenney-Benson, Curtis and Park, Changyong and Pietosa, Jaroslaw and Markiewicz, Ewa and Andrzejewski, Bartlomiej and Lynn, Jeffrey W. and Rosenkranz, Stephan and Dabrowski, Bogdan and Chmaissem, Omar},

  abstractNote = {Responding to the rapidly increasing demand for efficient energy usage and increased speed and functionality of electronic and spintronic devices, multiferroic oxides have recently emerged as key materials capable of tackling this multifaceted challenge. In this paper, we describe the development of single-site manganese-based multiferroic perovskite materials with modest amounts of nonmagnetic Ti substituted at the magnetic Mn site in Sr1-xBaxMn1-yTiyO3 (SBMTO). Significantly enhanced properties were achieved with ferroelectric-type structural transition temperatures boosted to ~430 K. Ferroelectric distortions with large spontaneous polarization values of ~30 mu C cm2, derived from a point charge model, are similar in magnitude to those of the prototypical nonmagnetic BaTiO3. Temperature dependence of the system's properties was investigated by synchrotron x-ray powder diffraction and neutron powder diffraction at ambient and high pressures. Various relationships were determined between the structural and magnetic properties, Ba and Ti contents, and TN and TC. Most importantly, our results demonstrate the large coupling between the magnetic and ferroelectric order parameters and the wide tunability of this coupling by slight variations of the material's stoichiometry.},

  doi          = {10.1103/PhysRevMaterials.3.084401},

  journal      = {Physical Review Materials},

  number       = 8,

  volume       = 3,

  place        = {United States},

  year         = {2019},

  month        = {8}

}

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https://doi.org/10.1103/PhysRevMaterials.3.084401

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Figures / Tables:

FIG. 1: Room temperature c/a ratio as a function of the Ba and Ti content: Perovskite and hexagonal phases are denoted by circles and squares, respectively. The c/a values are listed next to the symbols. The letters HC and H inside the circles indicate temperature-dependent cycles of synchrotron data collectedmore »

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Title: Tunable multiferroic order parameters in S r 1 - x B a x M n 1 - y T i y O 3

Abstract

Citation Formats

Figures / Tables:

Soft phonon mode coupled with antiferromagnetic order in incipient-ferroelectric Mott insulators Sr 1 − x Ba x MnO 3 journal, September 2012

Mantid—Data analysis and visualization package for neutron scattering and μ SR experiments journal, November 2014

A phenomenological thermodynamic potential for BaTiO3 single crystals journal, September 2005

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal, September 1976

Tolerance factor rules for Sr1−x−yCaxBayMnO3 perovskites journal, January 2003

Relationship between structural parameters and the Néel temperature in Sr 1 − x Ca x MnO 3 ( 0 <~ x <~ 1 ) and Sr 1 − y Ba y MnO 3 ( y <~ 0 . 2 ) journal, September 2001

Why Are There so Few Magnetic Ferroelectrics? journal, July 2000

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Optimizing phase and microstructure of chemical solution-deposited bismuth ferrite (BiFeO3) thin films to reduce DC leakage journal, October 2012

New developments in micro-X-ray diffraction and X-ray absorption spectroscopy for high-pressure research at 16-BM-D at the Advanced Photon Source journal, July 2015

The origin of ferroelectricity in magnetoelectric YMnO3 journal, February 2004

Non- d 0 Mn-driven ferroelectricity in antiferromagnetic BaMnO 3 journal, May 2009

Strain Engineering a Multiferroic Monodomain in Thin-Film Bi Fe O 3 journal, February 2019

Phase equilibria and structural relations in the system BaMnO3−x journal, August 1971

Origin of ferroelectricity in perovskite oxides journal, July 1992

DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration journal, May 2015

Neutron scattering studies of the ferroelectric distortion and spin dynamics in the type-1 multiferroic perovskite Sr 0.56 Ba 0.44 MnO 3 journal, October 2014

Engineering Multiferroism in CaMnO 3 journal, March 2009

Double-Focusing Thermal Triple-Axis Spectrometer at the NCNR journal, January 2012

Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite journal, February 2005

Multiferroic properties of stretchable BiFeO 3 nano-composite film journal, February 2015

Multiferroicity: the coupling between magnetic and polarization orders journal, July 2009

Universal Octahedral-Site Distortion in Orthorhombic Perovskite Oxides journal, February 2005

Ferroelectric transition in Y Mn O 3 from first principles journal, September 2005

Compression curves of transition metals in the Mbar range: Experiments and projector augmented-wave calculations journal, September 2008

Spin-phonon coupling in epitaxial S r 0.6 B a 0.4 Mn O 3 thin films journal, February 2017

Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures journal, March 2003

Structures of the ferroelectric phases of barium titanate journal, March 1993

Magnetic structures and dynamics of multiferroic systems obtained with neutron scattering journal, July 2016

Magnetic control of ferroelectric polarization journal, November 2003

Towards a magnetoelectric memory journal, June 2008

Spectroscopic studies of the ferroelectric and magnetic phase transitions in multiferroic Sr 1− x Ba x MnO 3 journal, March 2016

Epitaxial-Strain-Induced Multiferroicity in SrMnO 3 from First Principles journal, May 2010

EXPGUI , a graphical user interface for GSAS journal, April 2001

Multi-ferroic magnetoelectrics journal, January 1994

A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory journal, September 2018

Displacement-Type Ferroelectricity with Off-Center Magnetic Ions in Perovskite Sr 1 − x Ba x MnO 3 journal, September 2011

Strain-induced tetragonal distortions and multiferroic properties in polycrystalline Sr 1 − x B a x Mn O 3 ( x = 0.43 − 0.45 ) perovskites journal, May 2018

Crystal structures, charge and oxygen-vacancy ordering in oxygen deficient perovskites SrMnOx (x<2.7) journal, May 2007

Strain-controlled oxygen vacancy formation and ordering in CaMnO 3 journal, August 2013

Observation of coupled magnetic and electric domains journal, October 2002

Classifying multiferroics: Mechanisms and effects journal, March 2009

Electric polarization of Sr 0.5 Ba 0.5 MnO 3 : A multiferroic Mott insulator journal, December 2014

Novel Properties of Atomically Arranged Perovskites journal, January 2007

Multiferroics progress and prospects in thin films journal, January 2007

Multiferroics: a magnetic twist for ferroelectricity journal, January 2007

Microscopic Origin of Large Negative Magnetoelectric Coupling in Sr 1 / 2 Ba 1 / 2 MnO 3 journal, September 2012

Lattice Effects on the Magnetoresistance in Doped LaMn O 3 journal, July 1995

Domain Structure and Dielectric Response of Barium Titanate Single Crystals journal, June 1948

The COMPRES/GSECARS gas-loading system for diamond anvil cells at the Advanced Photon Source journal, September 2008

Critical thickness for ferroelectricity in perovskite ultrathin films journal, April 2003

Cation disorder and size effects in magnetoresistive manganese oxide perovskites journal, December 1996

Magnetocapacitance effect in multiferroic BiMnO 3 journal, May 2003

Electric Control of Spin Helicity in a Magnetic Ferroelectric journal, April 2007

Strain-controlled oxygen vacancy formation and ordering in CaMnO₃ text, January 2013

Neutron Scattering Studies of the Ferroelectric Distortion and Spin Dynamics in the Type-1 Multiferroic Perovskite Sr0.56Ba0.44MnO3 text, January 2014

Title: Tunable multiferroic order parameters in $S r_{1 - x} B a_{x} M n_{1 - y} T i_{y} O_{3}$

Soft phonon mode coupled with antiferromagnetic order in incipient-ferroelectric Mott insulators Sr $_{1 - x}$ Ba $_{x}$ MnO $_{3}$
journal, September 2012

Mantid—Data analysis and visualization package for neutron scattering and $μ$ SR experiments
journal, November 2014

A phenomenological thermodynamic potential for BaTiO3 single crystals
journal, September 2005

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Tolerance factor rules for Sr1−x−yCaxBayMnO3 perovskites
journal, January 2003

Relationship between structural parameters and the Néel temperature in ${Sr}_{1 - x} {Ca}_{x} {MnO}_{3}$ $(0 <~ x <~ 1)$ and ${Sr}_{1 - y} {Ba}_{y} {MnO}_{3}$ $(y <~ 0.2)$
journal, September 2001

Why Are There so Few Magnetic Ferroelectrics?
journal, July 2000

Online remote control systems for static and dynamic compression and decompression using diamond anvil cells
journal, July 2015

Optimizing phase and microstructure of chemical solution-deposited bismuth ferrite (BiFeO3) thin films to reduce DC leakage
journal, October 2012

New developments in micro-X-ray diffraction and X-ray absorption spectroscopy for high-pressure research at 16-BM-D at the Advanced Photon Source
journal, July 2015

The origin of ferroelectricity in magnetoelectric YMnO3
journal, February 2004

Non- $d^{0}$ Mn-driven ferroelectricity in antiferromagnetic ${BaMnO}_{3}$
journal, May 2009

Strain Engineering a Multiferroic Monodomain in Thin-Film ${Bi Fe O}_{3}$
journal, February 2019

Phase equilibria and structural relations in the system BaMnO3−x
journal, August 1971

Origin of ferroelectricity in perovskite oxides
journal, July 1992

DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration
journal, May 2015

Neutron scattering studies of the ferroelectric distortion and spin dynamics in the type-1 multiferroic perovskite ${Sr}_{0.56} {Ba}_{0.44} {MnO}_{3}$
journal, October 2014

Engineering Multiferroism in ${CaMnO}_{3}$
journal, March 2009

Double-Focusing Thermal Triple-Axis Spectrometer at the NCNR
journal, January 2012

Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite
journal, February 2005

Multiferroic properties of stretchable BiFeO ₃ nano-composite film
journal, February 2015

Multiferroicity: the coupling between magnetic and polarization orders
journal, July 2009

Universal Octahedral-Site Distortion in Orthorhombic Perovskite Oxides
journal, February 2005

Ferroelectric transition in $Y Mn O_{3}$ from first principles
journal, September 2005

Compression curves of transition metals in the Mbar range: Experiments and projector augmented-wave calculations
journal, September 2008

Spin-phonon coupling in epitaxial $S r_{0.6} B a_{0.4} Mn O_{3}$ thin films
journal, February 2017

Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures
journal, March 2003

Structures of the ferroelectric phases of barium titanate
journal, March 1993

Magnetic structures and dynamics of multiferroic systems obtained with neutron scattering
journal, July 2016

Magnetic control of ferroelectric polarization
journal, November 2003

Towards a magnetoelectric memory
journal, June 2008

Spectroscopic studies of the ferroelectric and magnetic phase transitions in multiferroic Sr _{1− x} Ba _x MnO ₃
journal, March 2016

Epitaxial-Strain-Induced Multiferroicity in ${SrMnO}_{3}$ from First Principles
journal, May 2010

EXPGUI , a graphical user interface for GSAS
journal, April 2001

Multi-ferroic magnetoelectrics
journal, January 1994

A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory
journal, September 2018

Displacement-Type Ferroelectricity with Off-Center Magnetic Ions in Perovskite ${Sr}_{1 - x} {Ba}_{x} {MnO}_{3}$
journal, September 2011

Strain-induced tetragonal distortions and multiferroic properties in polycrystalline ${Sr}_{1 - x} B a_{x} Mn O_{3}$ ( $x = 0.43 - 0.45$ ) perovskites
journal, May 2018

Crystal structures, charge and oxygen-vacancy ordering in oxygen deficient perovskites SrMnOx (x<2.7)
journal, May 2007

Strain-controlled oxygen vacancy formation and ordering in CaMnO $_{3}$
journal, August 2013

Observation of coupled magnetic and electric domains
journal, October 2002

Classifying multiferroics: Mechanisms and effects
journal, March 2009

Electric polarization of ${Sr}_{0.5} {Ba}_{0.5} {MnO}_{3}$ : A multiferroic Mott insulator
journal, December 2014

Novel Properties of Atomically Arranged Perovskites
journal, January 2007

Multiferroics progress and prospects in thin films
journal, January 2007

Multiferroics: a magnetic twist for ferroelectricity
journal, January 2007

Microscopic Origin of Large Negative Magnetoelectric Coupling in ${Sr}_{1 / 2} {Ba}_{1 / 2} {MnO}_{3}$
journal, September 2012

Lattice Effects on the Magnetoresistance in Doped LaMn $O_{3}$
journal, July 1995

Domain Structure and Dielectric Response of Barium Titanate Single Crystals
journal, June 1948

The COMPRES/GSECARS gas-loading system for diamond anvil cells at the Advanced Photon Source
journal, September 2008

Critical thickness for ferroelectricity in perovskite ultrathin films
journal, April 2003

Cation disorder and size effects in magnetoresistive manganese oxide perovskites
journal, December 1996

Magnetocapacitance effect in multiferroic ${BiMnO}_{3}$
journal, May 2003

Electric Control of Spin Helicity in a Magnetic Ferroelectric
journal, April 2007

Strain-controlled oxygen vacancy formation and ordering in CaMnO₃
text, January 2013

Neutron Scattering Studies of the Ferroelectric Distortion and Spin Dynamics in the Type-1 Multiferroic Perovskite Sr0.56Ba0.44MnO3
text, January 2014