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Title: Chemically controlled crystal growth of (CH 3NH 3) 2 AgInBr 6

Abstract

We report the successful crystal growth of a previously unknown mixed-metal organic compound (CH 3NH 3) 2AgInBr 6. This phase, which is not obtained by direct combination of reactants, is crystallized through the use of Pb 2+ (from CH 3NH 3PbBr 3) to modulate the soluble intermediates and force formation of (CH 3NH 3) 2AgInBr 6. Lastly, our results provide insights into mechanism and design-driven crystal growth and discovery of new halide materials that are chemically related to perovskites with photovoltaic and related applications.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]
  1. Johns Hopkins Univ., Baltimore, MD (United States). Inst. for Quantum Matter
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
  3. Department of Chemistry; Department of Physics and Astronomy; Institute for Quantum Matter; Johns Hopkins University; Baltimore
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1559738
Alternate Identifier(s):
OSTI ID: 1455078
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
CrystEngComm
Additional Journal Information:
Journal Volume: 20; Journal Issue: 39; Journal ID: ISSN 1466-8033
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Tran, Thao T., Quintero, Michael A., Arpino, Kathryn E., Kelly, Zachary A., Panella, Jessica R., Wang, Xiaoping, and McQueen, Tyrel M. Chemically controlled crystal growth of (CH3NH3) 2 AgInBr6. United States: N. p., 2018. Web. doi:10.1039/C8CE00702K.
Tran, Thao T., Quintero, Michael A., Arpino, Kathryn E., Kelly, Zachary A., Panella, Jessica R., Wang, Xiaoping, & McQueen, Tyrel M. Chemically controlled crystal growth of (CH3NH3) 2 AgInBr6. United States. doi:10.1039/C8CE00702K.
Tran, Thao T., Quintero, Michael A., Arpino, Kathryn E., Kelly, Zachary A., Panella, Jessica R., Wang, Xiaoping, and McQueen, Tyrel M. Wed . "Chemically controlled crystal growth of (CH3NH3) 2 AgInBr6". United States. doi:10.1039/C8CE00702K. https://www.osti.gov/servlets/purl/1559738.
@article{osti_1559738,
title = {Chemically controlled crystal growth of (CH3NH3) 2 AgInBr6},
author = {Tran, Thao T. and Quintero, Michael A. and Arpino, Kathryn E. and Kelly, Zachary A. and Panella, Jessica R. and Wang, Xiaoping and McQueen, Tyrel M.},
abstractNote = {We report the successful crystal growth of a previously unknown mixed-metal organic compound (CH3NH3)2AgInBr6. This phase, which is not obtained by direct combination of reactants, is crystallized through the use of Pb2+ (from CH3NH3PbBr3) to modulate the soluble intermediates and force formation of (CH3NH3)2AgInBr6. Lastly, our results provide insights into mechanism and design-driven crystal growth and discovery of new halide materials that are chemically related to perovskites with photovoltaic and related applications.},
doi = {10.1039/C8CE00702K},
journal = {CrystEngComm},
number = 39,
volume = 20,
place = {United States},
year = {2018},
month = {6}
}

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