Two regimes of ionization-induced recovery in SrTiO3 under irradiation

Weber, William; Xue, Haizhou; Zarkadoula, Eva; Zhang, Yanwen

doi:10.1016/j.scriptamat.2019.08.013

Title: Two regimes of ionization-induced recovery in SrTiO₃ under irradiation

Abstract

Irradiation of pre-damaged SrTiO₃ with 2 MeV He, 1.2 MeV C, 5 MeV C and 12 MeV O ions reveals two regimes of ionization-induced recovery. For C and O ions, with electronic energy loss between 1.6 and 3 keV/nm, recovery cross-sections range from 0.27 to 0.38 nm², and molecular dynamics confirms recovery related to ionization-induced thermal spikes via electron-phonon coupling. Lastly, at lower electronic energy losses, recovery cross-sections decrease to about 5.5 × 10^-4 nm² for 2 MeV He ions and 1.0 × 10^-5 nm² for 200 keV electrons, which suggests recovery associated with local electronic excitation processes.

Authors:

^[1]; Xue, Haizhou ^[2];

^[1];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)

Publication Date:: 2019-12-01

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1559652

Alternate Identifier(s):: OSTI ID: 1557924

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Scripta Materialia

Additional Journal Information:: Journal Volume: 173; Journal Issue: N/A; Journal ID: ISSN 1359-6462

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Weber, William, Xue, Haizhou, Zarkadoula, Eva, and Zhang, Yanwen. Two regimes of ionization-induced recovery in SrTiO3 under irradiation.  United States: N. p., 2019. 
Web.  doi:10.1016/j.scriptamat.2019.08.013.

Copy to clipboard


                    Weber, William, Xue, Haizhou, Zarkadoula, Eva, & Zhang, Yanwen. Two regimes of ionization-induced recovery in SrTiO3 under irradiation.  United States.  https://doi.org/10.1016/j.scriptamat.2019.08.013

Copy to clipboard


                    Weber, William, Xue, Haizhou, Zarkadoula, Eva, and Zhang, Yanwen. Sun .  
"Two regimes of ionization-induced recovery in SrTiO3 under irradiation".  United States.  https://doi.org/10.1016/j.scriptamat.2019.08.013.  https://www.osti.gov/servlets/purl/1559652.

Copy to clipboard


                    
@article{osti_1559652,

  title        = {Two regimes of ionization-induced recovery in SrTiO3 under irradiation},

  author       = {Weber, William and Xue, Haizhou and Zarkadoula, Eva and Zhang, Yanwen},

  abstractNote = {Irradiation of pre-damaged SrTiO3 with 2 MeV He, 1.2 MeV C, 5 MeV C and 12 MeV O ions reveals two regimes of ionization-induced recovery. For C and O ions, with electronic energy loss between 1.6 and 3 keV/nm, recovery cross-sections range from 0.27 to 0.38 nm2, and molecular dynamics confirms recovery related to ionization-induced thermal spikes via electron-phonon coupling. Lastly, at lower electronic energy losses, recovery cross-sections decrease to about 5.5 × 10-4 nm2 for 2 MeV He ions and 1.0 × 10-5 nm2 for 200 keV electrons, which suggests recovery associated with local electronic excitation processes.},

  doi          = {10.1016/j.scriptamat.2019.08.013},

  journal      = {Scripta Materialia},

  number       = N/A,

  volume       = 173,

  place        = {United States},

  year         = {2019},

  month        = {12}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1016/j.scriptamat.2019.08.013

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 1 work

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

On the conflicting roles of ionizing radiation in ceramics
journal, May 2002

Zinkle, S. J.; Skuratov, V. A.; Hoelzer, D. T.
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 191, Issue 1-4
DOI: 10.1016/S0168-583X(02)00648-1

The role of electronic energy loss in ion beam modification of materials
journal, February 2015

Weber, William J.; Duffy, Dorothy M.; Thomé, Lionel
Current Opinion in Solid State and Materials Science, Vol. 19, Issue 1
DOI: 10.1016/j.cossms.2014.09.003

Synergy of elastic and inelastic energy loss on ion track formation in SrTiO3
journal, January 2015

Weber, William J.; Zarkadoula, Eva; Pakarinen, Olli H.
Scientific Reports, Vol. 5, Issue 1
DOI: 10.1038/srep07726

Two-stage synergy of electronic energy loss with defects in LiTaO 3 under ion irradiation
journal, March 2018

Sellami, Neila; Crespillo, Miguel L.; Zhang, Yanwen
Materials Research Letters, Vol. 6, Issue 6
DOI: 10.1080/21663831.2018.1455753

High-κ gate dielectrics: Current status and materials properties considerations
journal, May 2001

Wilk, G. D.; Wallace, R. M.; Anthony, J. M.
Journal of Applied Physics, Vol. 89, Issue 10
DOI: 10.1063/1.1361065

Room-temperature ferroelectricity in strained SrTiO₃
journal, August 2004

Haeni, J. H.; Irvin, P.; Chang, W.
Nature, Vol. 430, Issue 7001, p. 758-761
DOI: 10.1038/nature02773

Electronic transport in doped ${SrTiO}_{3}$ : Conduction mechanisms and potential applications
journal, April 2010

Spinelli, A.; Torija, M. A.; Liu, C.
Physical Review B, Vol. 81, Issue 15
DOI: 10.1103/PhysRevB.81.155110

Persistent optically induced magnetism in oxygen-deficient strontium titanate
journal, March 2014

Rice, W. D.; Ambwani, P.; Bombeck, M.
Nature Materials, Vol. 13, Issue 5
DOI: 10.1038/nmat3914

Highly conductive nanolayers on strontium titanate produced by preferential ion-beam etching
journal, July 2005

Reagor, David W.; Butko, Vladimir Y.
Nature Materials, Vol. 4, Issue 8, p. 593-596
DOI: 10.1038/nmat1402

Tuning the Interface Conductivity of LaAlO ₃ /SrTiO ₃ Using Ion Beams: Implications for Patterning
journal, November 2013

Mathew, Sinu; Annadi, Anil; Chan, Taw Kuei
ACS Nano, Vol. 7, Issue 12
DOI: 10.1021/nn4028135

Damage evolution and waveguide formation in SrTiO3 crystal irradiated by tens of MeV Si ions
journal, September 2017

Liu, Y.; Huang, Q.; Qiao, M.
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 406
DOI: 10.1016/j.nimb.2016.12.023

Recent Advances on Carrier and Exciton Self-Trapping in Strontium Titanate: Understanding the Luminescence Emissions
journal, February 2019

Crespillo, Miguel; Graham, Joseph; Agulló-López, Fernando
Crystals, Vol. 9, Issue 2
DOI: 10.3390/cryst9020095

Role of the microstructure in the neutron and gamma-ray irradiation stability of solution-derived Ba0.5Sr0.5TiO3 thin films
journal, April 2015

Glinšek, Sebastjan; Pečnik, Tanja; Cindro, Vladimir
Acta Materialia, Vol. 88
DOI: 10.1016/j.actamat.2015.01.028

Materials Science of High-Level Nuclear Waste Immobilization
journal, January 2009

Weber, William J.; Navrotsky, Alexandra; Stefanovsky, Sergey
MRS Bulletin, Vol. 34, Issue 1
DOI: 10.1557/mrs2009.12

Dose rate and temperature effects in radiation disorder creation in SrTiO3
journal, November 2002

Sabathier, C.; Chaumont, J.; Krupa, J. -C
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 196, Issue 3-4
DOI: 10.1016/S0168-583X(02)01332-0

Response of strontium titanate to ion and electron irradiation
journal, May 2009

Zhang, Y.; Lian, J.; Zhu, Z.
Journal of Nuclear Materials, Vol. 389, Issue 2
DOI: 10.1016/j.jnucmat.2009.02.014

Amorphization due to electronic energy deposition in defective strontium titanate
journal, April 2017

Xue, Haizhou; Zarkadoula, Eva; Liu, Peng
Acta Materialia, Vol. 127
DOI: 10.1016/j.actamat.2017.01.051

Synergistically-enhanced ion track formation in pre-damaged strontium titanate by energetic heavy ions
journal, May 2018

Xue, Haizhou; Zarkadoula, Eva; Sachan, Ritesh
Acta Materialia, Vol. 150
DOI: 10.1016/j.actamat.2018.03.027

Swift heavy ion track formation in SrTiO ₃ and TiO ₂ under random, channeling and near-channeling conditions
journal, April 2017

Karlušić, M.; Jakšić, M.; Lebius, H.
Journal of Physics D: Applied Physics, Vol. 50, Issue 20
DOI: 10.1088/1361-6463/aa678c

Effect of doping on the radiation response of conductive Nb–SrTiO3
journal, May 2013

Li, Weixing; Rodriguez, Matias D.; Kluth, Patrick
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 302
DOI: 10.1016/j.nimb.2013.03.010

Revealing ionization-induced dynamic recovery in ion-irradiated SrTiO3
journal, May 2018

Velişa, Gihan; Wendler, Elke; Xue, Haizhou
Acta Materialia, Vol. 149
DOI: 10.1016/j.actamat.2018.02.038

Study of ion beam induced epitaxial crystallization of SrTiO3
journal, April 2000

Oyoshi, K.; Hishita, S.; Haneda, H.
Journal of Applied Physics, Vol. 87, Issue 7
DOI: 10.1063/1.372365

New ion beam materials laboratory for materials modification and irradiation effects research
journal, November 2014

Zhang, Y.; Crespillo, M. L.; Xue, H.
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 338
DOI: 10.1016/j.nimb.2014.07.028

Accumulation and thermal recovery of disorder in Au2+-irradiated SrTiO3
journal, February 2001

Thevuthasan, S.; Jiang, W.; Shutthanandan, V.
Journal of Nuclear Materials, Vol. 289, Issue 1-2
DOI: 10.1016/S0022-3115(00)00699-1

Predictive modeling of synergistic effects in nanoscale ion track formation
journal, January 2015

Zarkadoula, Eva; Pakarinen, Olli H.; Xue, Haizhou
Physical Chemistry Chemical Physics, Vol. 17, Issue 35
DOI: 10.1039/C5CP02382C

Synergy of inelastic and elastic energy loss: Temperature effects and electronic stopping power dependence
journal, January 2016

Zarkadoula, Eva; Xue, Haizhou; Zhang, Yanwen
Scripta Materialia, Vol. 110
DOI: 10.1016/j.scriptamat.2015.05.044

DL_POLY_3: new dimensions in molecular dynamics simulations via massive parallelism
journal, January 2006

Todorov, Ilian T.; Smith, William; Trachenko, Kostya
Journal of Materials Chemistry, Vol. 16, Issue 20, p. 1911-1918
DOI: 10.1039/b517931a

Phase stability and interfacial structures in the SrO–SrTiO ₃ system
journal, March 1997

Mccoy, Michael A.; Grimes, Robin W.; Lee, William E.
Philosophical Magazine A, Vol. 75, Issue 3
DOI: 10.1080/01418619708207205

Coupled electronic and atomic effects on defect evolution in silicon carbide under ion irradiation
journal, December 2017

Zhang, Yanwen; Xue, Haizhou; Zarkadoula, Eva
Current Opinion in Solid State and Materials Science, Vol. 21, Issue 6
DOI: 10.1016/j.cossms.2017.09.003

Visible-light-accelerated oxygen vacancy migration in strontium titanate
journal, September 2015

Li, Y.; Lei, Y.; Shen, B. G.
Scientific Reports, Vol. 5, Issue 1
DOI: 10.1038/srep14576

Works referencing / citing this record:

Molecular dynamics simulations of the response of pre-damaged SrTiO ₃ and KTaO ₃ to fast heavy ions
journal, January 2020

Zarkadoula, Eva; Zhang, Yanwen; Weber, William J.
AIP Advances, Vol. 10, Issue 1
DOI: 10.1063/1.5133061

Similar Records in DOE PAGES and OSTI.GOV collections:

Track formation in SiO[sub 2] quartz and the thermal-spike mechanism

Journal Article Meftah, A ; Brisard, F ; Costantini, J M ; ... - Physical Review, B: Condensed Matter; (United States)

[alpha]-quartz has been irradiated with heavy ions: [sup 19]F, [sup 32]S, and [sup 63]Cu at an energy of about 1 MeV/amu in order to cover a range of electronic stopping powers [ital dE]/[ital dx] between 2.4 and 9 keV/nm and [sup 58]Ni, [sup 86]Kr, [sup 128]Te, [sup 129]Xe, [sup 181]Ta, and [sup 208]Pb between 1 and 5.8 MeV/amu for [ital dE]/[ital dx][gt]7 keV/nm. The extent of the induced damage is determined using Rutherford backscattering ion channeling with a 2-MeV [sup 4]He beam. The damage cross section [ital A] is obtained using a Poisson law [ital F][sub [ital d]]=1[minus]exp([minus][ital A][phi][ital t]),more »« less
https://doi.org/10.1103/PhysRevB.49.12457
/sub 1//sup 1/H/sup +/- and /sub 2//sup 4/He/sup +/-induced M-shell x-ray-production cross sections for selected elements in the rare-earth region

Journal Article Mehta, R ; Duggan, J L ; Price, J L ; ... - Phys. Rev. A; (United States)

The measurements of M-shell x-ray-production cross sections induced by /sub 1//sup 1/H/sup +/ and /sub 2//sup 4/He/sup +/ ions are compared to the first-Born-approximation and ECPSSR (energy loss, Coulomb-deflection effects; perturbed-stationary-state approximation, with relativistic corrections) theories. Most of the reported experimental data were measured in our laboratory and the other measurements were taken from the literature. The data from our laboratory were for incident H/sup +/ and He/sup +/ ions in the energy range from 0.25 to 2.5 MeV. The M-shell x-ray-production cross sections were measured for the following thin targets: /sub 59/Pr, /sub 60/Nd, /sub 63/Eu, /sub 64/Gd, /submore »« less
https://doi.org/10.1103/PhysRevA.28.3217
Diffusion and impurity segregation in hydrogen-implanted silicon carbide

Journal Article Barcz, A., E-mail: barcz@ite.waw.pl ; Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw ; Kozubal, M. ; ... - Journal of Applied Physics

Diffusion and segregation behavior of hydrogen and oxygen in silicon carbide subjected to H implantation and subsequent annealing were studied with a number of analytical techniques including Secondary Ion Mass Spectrometry (SIMS), Rutherford backscattering spectrometry in channeling geometry, field emission scanning electron microscopy, optical microscopy, cross-sectional transmission electron microscopy, and atomic force microscopy. H{sup +} implantation was carried out with energies of 200 keV, 500 keV, or 1 MeV to doses of 1 × 10{sup 16}, 1 × 10{sup 17}, or 2 × 10{sup 17} ion/cm{sup 2}, and thermal treatment was conducted in flowing argon for 1 to 2 h at temperatures of 740, 780, 1000, or 1100 °C. Themore »« less
https://doi.org/10.1063/1.4882996
Role of atomic-level defects and electronic energy loss on amorphization in LiNbO₃ single crystals

Journal Article Sellami, N. ; Crespillo, M. L. ; Xue, H. ; ... - Journal of Physics. D, Applied Physics

Understanding complex non-equilibrium defect processes, where multiple irradiation mechanisms may take place simultaneously, is a long standing subject in material science. The separate and combined effects of elastic and inelastic energy loss are a very complicated and challenging topic. In this work, LiNbO₃ has been irradiated with 0.9 MeV Si⁺ and 8 MeV O³⁺, which are representative of regimes where nuclear (S _n) and electronic (S _e) energy loss are dominant, respectively. The evolution of damage has been investigated by Rutherford backscattering spectrometry (RBS) in channeling configuration. Pristine samples were irradiated with 0.9 MeV Si⁺ ions to create different pre-existingmore »« less
Cited by 3
https://doi.org/10.1088/1361-6463/aa7a9e

Full Text Available
Structural transition and recovery of Ge implanted β-Ga₂O₃

Journal Article Anber, Elaf A. ; Foley, Daniel ; Lang, Andrew C. ; ... - Applied Physics Letters

Ion implantation-induced effects were studied in Ge implanted β-Ga₂O₃ with the fluence and energy of 3 × 10¹³ cm^-2/60 keV, 5 × 10¹³ cm^-2/100 keV, and 7 × 10¹³ cm^-2/200 keV using analytical electron microscopy via scanning/transmission electron microscopy, electron energy loss spectroscopy, and precession electron diffraction via TopSpin. Imaging shows an isolated band of damage after Ge implantation, which extends ~130 nm from the sample surface and corresponds to the projected range of the ions. Electron diffraction demonstrates that the entirety of the damage band is the κ phase, indicating an implantation-induced phase transition from β to κ-Ga₂O₃. Post-implantationmore »« less
https://doi.org/10.1063/5.0022170

Full Text Available

Similar Records

Title: Two regimes of ionization-induced recovery in SrTiO3 under irradiation

Abstract

Citation Formats

On the conflicting roles of ionizing radiation in ceramics journal, May 2002

The role of electronic energy loss in ion beam modification of materials journal, February 2015

Synergy of elastic and inelastic energy loss on ion track formation in SrTiO3 journal, January 2015

Two-stage synergy of electronic energy loss with defects in LiTaO 3 under ion irradiation journal, March 2018

High-κ gate dielectrics: Current status and materials properties considerations journal, May 2001

Room-temperature ferroelectricity in strained SrTiO3 journal, August 2004

Electronic transport in doped SrTiO 3 : Conduction mechanisms and potential applications journal, April 2010

Persistent optically induced magnetism in oxygen-deficient strontium titanate journal, March 2014

Highly conductive nanolayers on strontium titanate produced by preferential ion-beam etching journal, July 2005

Tuning the Interface Conductivity of LaAlO 3 /SrTiO 3 Using Ion Beams: Implications for Patterning journal, November 2013

Damage evolution and waveguide formation in SrTiO3 crystal irradiated by tens of MeV Si ions journal, September 2017

Recent Advances on Carrier and Exciton Self-Trapping in Strontium Titanate: Understanding the Luminescence Emissions journal, February 2019

Role of the microstructure in the neutron and gamma-ray irradiation stability of solution-derived Ba0.5Sr0.5TiO3 thin films journal, April 2015

Materials Science of High-Level Nuclear Waste Immobilization journal, January 2009

Dose rate and temperature effects in radiation disorder creation in SrTiO3 journal, November 2002

Response of strontium titanate to ion and electron irradiation journal, May 2009

Amorphization due to electronic energy deposition in defective strontium titanate journal, April 2017

Synergistically-enhanced ion track formation in pre-damaged strontium titanate by energetic heavy ions journal, May 2018

Swift heavy ion track formation in SrTiO 3 and TiO 2 under random, channeling and near-channeling conditions journal, April 2017

Effect of doping on the radiation response of conductive Nb–SrTiO3 journal, May 2013

Revealing ionization-induced dynamic recovery in ion-irradiated SrTiO3 journal, May 2018

Study of ion beam induced epitaxial crystallization of SrTiO3 journal, April 2000

New ion beam materials laboratory for materials modification and irradiation effects research journal, November 2014

Accumulation and thermal recovery of disorder in Au2+-irradiated SrTiO3 journal, February 2001

Predictive modeling of synergistic effects in nanoscale ion track formation journal, January 2015

Synergy of inelastic and elastic energy loss: Temperature effects and electronic stopping power dependence journal, January 2016

DL_POLY_3: new dimensions in molecular dynamics simulations via massive parallelism journal, January 2006

Phase stability and interfacial structures in the SrO–SrTiO 3 system journal, March 1997

Coupled electronic and atomic effects on defect evolution in silicon carbide under ion irradiation journal, December 2017

Visible-light-accelerated oxygen vacancy migration in strontium titanate journal, September 2015

Molecular dynamics simulations of the response of pre-damaged SrTiO 3 and KTaO 3 to fast heavy ions journal, January 2020

Title: Two regimes of ionization-induced recovery in SrTiO₃ under irradiation

On the conflicting roles of ionizing radiation in ceramics
journal, May 2002

The role of electronic energy loss in ion beam modification of materials
journal, February 2015

Synergy of elastic and inelastic energy loss on ion track formation in SrTiO3
journal, January 2015

Two-stage synergy of electronic energy loss with defects in LiTaO 3 under ion irradiation
journal, March 2018

High-κ gate dielectrics: Current status and materials properties considerations
journal, May 2001

Room-temperature ferroelectricity in strained SrTiO₃
journal, August 2004

Electronic transport in doped ${SrTiO}_{3}$ : Conduction mechanisms and potential applications
journal, April 2010

Persistent optically induced magnetism in oxygen-deficient strontium titanate
journal, March 2014

Highly conductive nanolayers on strontium titanate produced by preferential ion-beam etching
journal, July 2005

Tuning the Interface Conductivity of LaAlO ₃ /SrTiO ₃ Using Ion Beams: Implications for Patterning
journal, November 2013

Damage evolution and waveguide formation in SrTiO3 crystal irradiated by tens of MeV Si ions
journal, September 2017

Recent Advances on Carrier and Exciton Self-Trapping in Strontium Titanate: Understanding the Luminescence Emissions
journal, February 2019

Role of the microstructure in the neutron and gamma-ray irradiation stability of solution-derived Ba0.5Sr0.5TiO3 thin films
journal, April 2015

Materials Science of High-Level Nuclear Waste Immobilization
journal, January 2009

Dose rate and temperature effects in radiation disorder creation in SrTiO3
journal, November 2002

Response of strontium titanate to ion and electron irradiation
journal, May 2009

Amorphization due to electronic energy deposition in defective strontium titanate
journal, April 2017

Synergistically-enhanced ion track formation in pre-damaged strontium titanate by energetic heavy ions
journal, May 2018

Swift heavy ion track formation in SrTiO ₃ and TiO ₂ under random, channeling and near-channeling conditions
journal, April 2017

Effect of doping on the radiation response of conductive Nb–SrTiO3
journal, May 2013

Revealing ionization-induced dynamic recovery in ion-irradiated SrTiO3
journal, May 2018

Study of ion beam induced epitaxial crystallization of SrTiO3
journal, April 2000

New ion beam materials laboratory for materials modification and irradiation effects research
journal, November 2014

Accumulation and thermal recovery of disorder in Au2+-irradiated SrTiO3
journal, February 2001

Predictive modeling of synergistic effects in nanoscale ion track formation
journal, January 2015

Synergy of inelastic and elastic energy loss: Temperature effects and electronic stopping power dependence
journal, January 2016

DL_POLY_3: new dimensions in molecular dynamics simulations via massive parallelism
journal, January 2006

Phase stability and interfacial structures in the SrO–SrTiO ₃ system
journal, March 1997

Coupled electronic and atomic effects on defect evolution in silicon carbide under ion irradiation
journal, December 2017

Visible-light-accelerated oxygen vacancy migration in strontium titanate
journal, September 2015

Molecular dynamics simulations of the response of pre-damaged SrTiO ₃ and KTaO ₃ to fast heavy ions
journal, January 2020