Shedding light on the atomic-scale structure of amorphous silica–alumina and its Brønsted acid sites
Abstract
Advanced solid-state NMR methods, using dynamic nuclear polarization (DNP), are applied to probe the atomic-scale bulk structure of amorphous silica–alumina catalysts prepared by flame-spray pyrolysis, and the structure of their Brønsted acid sites.
- Authors:
-
[1];
[1];
[3];
[2];
[4]
- US DOE, Ames Laboratory, Ames, USA
- Laboratory for Catalysis Engineering, School of Chemical and Biomolecular Engineering & Sydney Nano Institute, University of Sydney, Sydney, Australia
- Institute for Chemical and Bioengineering, Department of Chemistry and Applied Bioscience, ETH Zürich, HCI, Switzerland
- US DOE, Ames Laboratory, Ames, USA, Department of Chemistry
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1559344
- Alternate Identifier(s):
- OSTI ID: 1561968
- Report Number(s):
- IS-J-10031
Journal ID: ISSN 1463-9076; PPCPFQ
- Grant/Contract Number:
- AC02-07CH11358; DP150103842; DP180104010
- Resource Type:
- Published Article
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP
- Additional Journal Information:
- Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Volume: 21 Journal Issue: 35; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Perras, Frédéric A., Wang, Zichun, Kobayashi, Takeshi, Baiker, Alfons, Huang, Jun, and Pruski, Marek. Shedding light on the atomic-scale structure of amorphous silica–alumina and its Brønsted acid sites. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9CP04099D.
Perras, Frédéric A., Wang, Zichun, Kobayashi, Takeshi, Baiker, Alfons, Huang, Jun, & Pruski, Marek. Shedding light on the atomic-scale structure of amorphous silica–alumina and its Brønsted acid sites. United Kingdom. https://doi.org/10.1039/C9CP04099D
Perras, Frédéric A., Wang, Zichun, Kobayashi, Takeshi, Baiker, Alfons, Huang, Jun, and Pruski, Marek. Wed .
"Shedding light on the atomic-scale structure of amorphous silica–alumina and its Brønsted acid sites". United Kingdom. https://doi.org/10.1039/C9CP04099D.
@article{osti_1559344,
title = {Shedding light on the atomic-scale structure of amorphous silica–alumina and its Brønsted acid sites},
author = {Perras, Frédéric A. and Wang, Zichun and Kobayashi, Takeshi and Baiker, Alfons and Huang, Jun and Pruski, Marek},
abstractNote = {Advanced solid-state NMR methods, using dynamic nuclear polarization (DNP), are applied to probe the atomic-scale bulk structure of amorphous silica–alumina catalysts prepared by flame-spray pyrolysis, and the structure of their Brønsted acid sites.},
doi = {10.1039/C9CP04099D},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 35,
volume = 21,
place = {United Kingdom},
year = {Wed Sep 11 00:00:00 EDT 2019},
month = {Wed Sep 11 00:00:00 EDT 2019}
}
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https://doi.org/10.1039/C9CP04099D
https://doi.org/10.1039/C9CP04099D
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Cited by: 28 works
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Figures / Tables:
Fig. 1: 27Al 1D MAS (a) and 2D DQ/SQ (b) spectra of ASA samples with different concentrations of aluminum, as indicated on the figure.
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