Crystal structure and magnetic properties of the layered van der Waals compound
Abstract
Single crystals of the layered, van der Waals compound VBr3 were synthesized by a vapor transport technique, and characterized by single-crystal x-ray diffraction, temperature- and field-dependent magnetization, and temperature-dependent specific-heat measurements. VBr3 has a honeycomb-based BiI3-type structure with space group $$R$$-3 (no. 148) at 100 K, analogous to the structure of other honeycomb trihalides. Structural stacking faults were observed as evidenced by the streaking of reflections along $c*$ in the diffraction data. VBr3 goes through a structural phase transition at 90.4 K and a subsequent antiferromagnetic phase transition at 26.5 K, below which the magnetic moments are primarily aligned along the $$c$$-axis.
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Institute for Quantum Matter (IQM); Princeton Univ., NJ (United States). Dept. of Chemistry
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1559287
- Alternate Identifier(s):
- OSTI ID: 1559387
- Grant/Contract Number:
- SC0019331
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Materials
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 8; Journal ID: ISSN 2475-9953
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Kong, Tai, Guo, Shu, Ni, Danrui, and Cava, Robert J. Crystal structure and magnetic properties of the layered van der Waals compound VBr3. United States: N. p., 2019.
Web. doi:10.1103/PhysRevMaterials.3.084419.
Kong, Tai, Guo, Shu, Ni, Danrui, & Cava, Robert J. Crystal structure and magnetic properties of the layered van der Waals compound VBr3. United States. https://doi.org/10.1103/PhysRevMaterials.3.084419
Kong, Tai, Guo, Shu, Ni, Danrui, and Cava, Robert J. Thu .
"Crystal structure and magnetic properties of the layered van der Waals compound VBr3". United States. https://doi.org/10.1103/PhysRevMaterials.3.084419. https://www.osti.gov/servlets/purl/1559287.
@article{osti_1559287,
title = {Crystal structure and magnetic properties of the layered van der Waals compound VBr3},
author = {Kong, Tai and Guo, Shu and Ni, Danrui and Cava, Robert J.},
abstractNote = {Single crystals of the layered, van der Waals compound VBr3 were synthesized by a vapor transport technique, and characterized by single-crystal x-ray diffraction, temperature- and field-dependent magnetization, and temperature-dependent specific-heat measurements. VBr3 has a honeycomb-based BiI3-type structure with space group $R$-3 (no. 148) at 100 K, analogous to the structure of other honeycomb trihalides. Structural stacking faults were observed as evidenced by the streaking of reflections along $c*$ in the diffraction data. VBr3 goes through a structural phase transition at 90.4 K and a subsequent antiferromagnetic phase transition at 26.5 K, below which the magnetic moments are primarily aligned along the $c$-axis.},
doi = {10.1103/PhysRevMaterials.3.084419},
journal = {Physical Review Materials},
number = 8,
volume = 3,
place = {United States},
year = {Thu Aug 29 00:00:00 EDT 2019},
month = {Thu Aug 29 00:00:00 EDT 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 18 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
VI 3 —a New Layered Ferromagnetic Semiconductor
journal, March 2019
- Kong, Tai; Stolze, Karoline; Timmons, Erik I.
- Advanced Materials, Vol. 31, Issue 17
Magnetochemische Untersuchungen. XX. Über das magnetische Verhalten einiger einfacher Vanadinverbindungen
journal, March 1936
- Klemm, Wilhelm; Hoschek, Ernst
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 226, Issue 4
Monoclinic crystal structure of and the zigzag antiferromagnetic ground state
journal, December 2015
- Johnson, R. D.; Williams, S. C.; Haghighirad, A. A.
- Physical Review B, Vol. 92, Issue 23
Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals
journal, April 2017
- Gong, Cheng; Li, Lin; Li, Zhenglu
- Nature, Vol. 546, Issue 7657
Magnetic order in : A honeycomb-lattice quantum magnet with strong spin-orbit coupling
journal, April 2015
- Sears, J. A.; Songvilay, M.; Plumb, K. W.
- Physical Review B, Vol. 91, Issue 14
Coupling of Crystal Structure and Magnetism in the Layered, Ferromagnetic Insulator CrI 3
journal, January 2015
- McGuire, Michael A.; Dixit, Hemant; Cooper, Valentino R.
- Chemistry of Materials, Vol. 27, Issue 2
Crystal structure refinement with SHELXL
journal, January 2015
- Sheldrick, George M.
- Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
Bulk properties of the van der Waals hard ferromagnet
journal, January 2019
- Son, Suhan; Coak, Matthew J.; Lee, Nahyun
- Physical Review B, Vol. 99, Issue 4
Ferromagnetic van der Waals Crystal VI 3
journal, March 2019
- Tian, Shangjie; Zhang, Jian-Feng; Li, Chenghe
- Journal of the American Chemical Society, Vol. 141, Issue 13
Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides
journal, April 2017
- McGuire, Michael
- Crystals, Vol. 7, Issue 5
Anomalous behaviour in the layer halides and oxyhalides of titanium and vanadium: a study of materials close to delocalisation
journal, September 1987
- Wilson, J. A.; Maule, C.; Strange, P.
- Journal of Physics C: Solid State Physics, Vol. 20, Issue 26
Study of Frustration Effects in Two-Dimensional Triangular Lattice Antiferromagnets–Neutron Powder Diffraction Study of VX 2 , X≡Cl, Br and I
journal, May 1983
- Hirakawa, Kinshiro; Kadowaki, Hiroaki; Ubukoshi, Koji
- Journal of the Physical Society of Japan, Vol. 52, Issue 5
Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit
journal, June 2017
- Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efrén
- Nature, Vol. 546, Issue 7657
Single-crystal structure validation with the program PLATON
journal, January 2003
- Spek, A. L.
- Journal of Applied Crystallography, Vol. 36, Issue 1, p. 7-13
An optical investigation into the 3d 1 and 3d 2 transition-metal halides and oxyhalides, compounds near to delocalisation
journal, April 1988
- Maule, C. H.; Tothill, J. N.; Strange, P.
- Journal of Physics C: Solid State Physics, Vol. 21, Issue 11
OLEX2 : a complete structure solution, refinement and analysis program
journal, January 2009
- Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J.
- Journal of Applied Crystallography, Vol. 42, Issue 2
Transport Reactions of Some Vanadium(III) Halides. Mixed Halide Formation
journal, January 1964
- McCarley, Robert E.; Roddy, James W.; Berry, Keith O.
- Inorganic Chemistry, Vol. 3, Issue 1
Low-temperature crystal and magnetic structure of
journal, April 2016
- Cao, H. B.; Banerjee, A.; Yan, J. -Q.
- Physical Review B, Vol. 93, Issue 13
Discovery of Intrinsic Ferromagnetism in Two-Dimensional van der Waals Crystals
conference, January 2017
- Gong, Cheng; Li, Lin; Li, Zhenglu
- CLEO: Applications and Technology, Conference on Lasers and Electro-Optics
Crystallography and crystal chemistry of materials with layered structures
journal, January 1980
- Russell, G. J.
- Progress in Crystal Growth and Characterization, Vol. 3, Issue 2-3
Layer-dependent Ferromagnetism in a van der Waals Crystal down to the Monolayer Limit
text, January 2017
- Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efren
- arXiv
Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides
text, January 2017
- McGuire, Michael A.
- arXiv