Self-assembly and metal-directed assembly of organic semiconductor aerogels and conductive carbon nanofiber aerogels with controllable nanoscale morphologies
Abstract
A versatile and highly tunable synthesis for nanofiber aerogels based on the n-type organic semiconductor perylene tetracarboxylic diimide (PTCDI) is presented. PTCDI nanofiber aerogels are demonstrated to incorporate the organic semiconductor into a high surface area and porous morphology, and can also be graphitized to synthesize carbon nanofiber (CNF) aerogels by thermal annealing. Using this approach, CNF aerogels with variable density and crystallinity are synthesized. Furthermore, by incorporating metal salts into the synthesis, metal-directed assembly yields a variety of nanoscale morphologies. The selection of post-synthesis thermal treatment can result in metal-directed assembly of PTCDI aerogels, low crystallinity graphitic aerogels decorated with metal nanoparticles, or highly crystalline graphitic aerogels with controllable nanoscale morphologies. The high surface area and porosity afforded by the aerogel morphology coupled with the intrinsic properties of PTCDI or CNFs is important for improving their performance in a number of applications including energy storage and catalysis.
- Authors:
-
- University of California, Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Kavli Energy NanoScience Institute, Berkeley, CA (United States)
- University of California, Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Molecular Foundry; Kavli Energy NanoScience Institute, Berkeley, CA (United States)
- University of California, Berkeley, CA (United States); Kavli Energy NanoScience Institute, Berkeley, CA (United States)
- University of California, Berkeley, CA (United States)
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Molecular Foundry
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- University of California, Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Materials Science Division; Kavli Energy NanoScience Institute, Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1559260
- Alternate Identifier(s):
- OSTI ID: 1545387; OSTI ID: 2229594
- Report Number(s):
- LLNL-JRNL-843433
Journal ID: ISSN 0008-6223; ark:/13030/qt5655m7tw
- Grant/Contract Number:
- AC02-05CH11231; AC52-07NA27344
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Carbon
- Additional Journal Information:
- Journal Volume: 153; Journal Issue: C; Journal ID: ISSN 0008-6223
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY; Aerogel; Carbon nanofiber; Organic semiconductor; PTCDI; Self-assembly; Metal-directed assembly
Citation Formats
Turner, Sally, Shevitski, Brian, Long, Hu, Lorenzo, Maydelle, Marquez, James, Aloni, Shaul, Altoe, Virginia, Worsley, Marcus A., and Zettl, Alex. Self-assembly and metal-directed assembly of organic semiconductor aerogels and conductive carbon nanofiber aerogels with controllable nanoscale morphologies. United States: N. p., 2019.
Web. doi:10.1016/j.carbon.2019.07.039.
Turner, Sally, Shevitski, Brian, Long, Hu, Lorenzo, Maydelle, Marquez, James, Aloni, Shaul, Altoe, Virginia, Worsley, Marcus A., & Zettl, Alex. Self-assembly and metal-directed assembly of organic semiconductor aerogels and conductive carbon nanofiber aerogels with controllable nanoscale morphologies. United States. https://doi.org/10.1016/j.carbon.2019.07.039
Turner, Sally, Shevitski, Brian, Long, Hu, Lorenzo, Maydelle, Marquez, James, Aloni, Shaul, Altoe, Virginia, Worsley, Marcus A., and Zettl, Alex. Fri .
"Self-assembly and metal-directed assembly of organic semiconductor aerogels and conductive carbon nanofiber aerogels with controllable nanoscale morphologies". United States. https://doi.org/10.1016/j.carbon.2019.07.039. https://www.osti.gov/servlets/purl/1559260.
@article{osti_1559260,
title = {Self-assembly and metal-directed assembly of organic semiconductor aerogels and conductive carbon nanofiber aerogels with controllable nanoscale morphologies},
author = {Turner, Sally and Shevitski, Brian and Long, Hu and Lorenzo, Maydelle and Marquez, James and Aloni, Shaul and Altoe, Virginia and Worsley, Marcus A. and Zettl, Alex},
abstractNote = {A versatile and highly tunable synthesis for nanofiber aerogels based on the n-type organic semiconductor perylene tetracarboxylic diimide (PTCDI) is presented. PTCDI nanofiber aerogels are demonstrated to incorporate the organic semiconductor into a high surface area and porous morphology, and can also be graphitized to synthesize carbon nanofiber (CNF) aerogels by thermal annealing. Using this approach, CNF aerogels with variable density and crystallinity are synthesized. Furthermore, by incorporating metal salts into the synthesis, metal-directed assembly yields a variety of nanoscale morphologies. The selection of post-synthesis thermal treatment can result in metal-directed assembly of PTCDI aerogels, low crystallinity graphitic aerogels decorated with metal nanoparticles, or highly crystalline graphitic aerogels with controllable nanoscale morphologies. The high surface area and porosity afforded by the aerogel morphology coupled with the intrinsic properties of PTCDI or CNFs is important for improving their performance in a number of applications including energy storage and catalysis.},
doi = {10.1016/j.carbon.2019.07.039},
journal = {Carbon},
number = C,
volume = 153,
place = {United States},
year = {Fri Nov 01 00:00:00 EDT 2019},
month = {Fri Nov 01 00:00:00 EDT 2019}
}
Web of Science
Works referenced in this record:
Ultrasensitive and Highly Selective Gas Sensors Based on Electrospun SnO2 Nanofibers Modified by Pd Loading
journal, September 2010
- Yang, Dae-Jin; Kamienchick, Itai; Youn, Doo Young
- Advanced Functional Materials, Vol. 20, Issue 24
Self-Assembled Chiral Nanofibers from Ultrathin Low-Dimensional Nanomaterials
journal, January 2015
- Tan, Chaoliang; Qi, Xiaoying; Liu, Zhengdong
- Journal of the American Chemical Society, Vol. 137, Issue 4
Differences between carbon nanofibers produced using Fe and Ni catalysts in a floating catalyst reactor
journal, July 2006
- Martin-Gullon, Ignacio; Vera, José; Conesa, Juan A.
- Carbon, Vol. 44, Issue 8
Self-Assembled Nanowires of Organic n-Type Semiconductor for Nonvolatile Transistor Memory Devices
journal, June 2012
- Chou, Ying-Hsuan; Lee, Wen-Ya; Chen, Wen-Chang
- Advanced Functional Materials, Vol. 22, Issue 20
Optically Active 1D MoS 2 Nanobelts
journal, February 2018
- Murthy, Akshay A.; Li, Yuan; Palacios, Edgar
- ACS Applied Materials & Interfaces, Vol. 10, Issue 8
Ultrafine TiO2 nanofibers for photocatalysis
journal, January 2013
- Chacko, Daya K.; Madhavan, Asha Anish; Arun, T. A.
- RSC Advances, Vol. 3, Issue 47
Direct Growth of MoS2 Nanowalls on Carbon Nanofibers for Use in Supercapacitor
journal, July 2017
- Sari, Fitri Nur Indah; Ting, Jyh-Ming
- Scientific Reports, Vol. 7, Issue 1
Thin-Wall Assembled SnO 2 Fibers Functionalized by Catalytic Pt Nanoparticles and their Superior Exhaled-Breath-Sensing Properties for the Diagnosis of Diabetes
journal, December 2012
- Shin, Jungwoo; Choi, Seon-Jin; Lee, Inkun
- Advanced Functional Materials, Vol. 23, Issue 19
Synthesis and characterisation of nanofibrillar cellulose aerogels
journal, August 2007
- Hoepfner, Sandra; Ratke, Lorenz; Milow, Barbara
- Cellulose, Vol. 15, Issue 1
3D Printing Hierarchical Silver Nanowire Aerogel with Highly Compressive Resilience and Tensile Elongation through Tunable Poisson's Ratio
journal, August 2017
- Yan, Pengli; Brown, Emery; Su, Qing
- Small, Vol. 13, Issue 38
Tuning the Charge-Transport Parameters of Perylene Diimide Single Crystals via End and/or Core Functionalization: A Density Functional Theory Investigation
journal, March 2010
- Delgado, M. Carmen Ruiz; Kim, Eung-Gun; Filho, Demétrio A. da Silva
- Journal of the American Chemical Society, Vol. 132, Issue 10
Nanobelt Self-Assembly from an Organic n-Type Semiconductor: Propoxyethyl-PTCDI
journal, August 2005
- Balakrishnan, Kaushik; Datar, Aniket; Oitker, Randy
- Journal of the American Chemical Society, Vol. 127, Issue 30
Electrical Transport through Single Nanowires of Dialkyl Perylene Diimide
journal, May 2013
- Kim, Beom Joon; Yu, Hojeong; Oh, Joon Hak
- The Journal of Physical Chemistry C, Vol. 117, Issue 20
Interfacial Donor–Acceptor Engineering of Nanofiber Materials To Achieve Photoconductivity and Applications
journal, September 2015
- Zang, Ling
- Accounts of Chemical Research, Vol. 48, Issue 10
Thermoactivated Electrical Conductivity in Perylene Diimide Nanofiber Materials
journal, December 2016
- Wu, Na; Zhang, Yaqiong; Wang, Chen
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 1
Structure control and photocatalytic performance of porous conjugated polymers based on perylene diimide
journal, January 2016
- Li, Lianwei; Cai, Zhengxu
- Polymer Chemistry, Vol. 7, Issue 30
Three-Dimensional Arylene Diimide Frameworks for Highly Stable Lithium Ion Batteries
journal, April 2017
- Schon, Tyler B.; Tilley, Andrew J.; Kynaston, Emily L.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 18
A nanomesh scaffold for supramolecular nanowire optoelectronic devices
journal, July 2016
- Zhang, Lei; Zhong, Xiaolan; Pavlica, Egon
- Nature Nanotechnology, Vol. 11, Issue 10
Nitrogen-enriched electrospun porous carbon nanofiber networks as high-performance free-standing electrode materials
journal, January 2014
- Nan, Ding; Huang, Zheng-Hong; Lv, Ruitao
- J. Mater. Chem. A, Vol. 2, Issue 46
Carbon nanofiber supercapacitors with large areal capacitances
journal, December 2009
- McDonough, James R.; Choi, Jang Wook; Yang, Yuan
- Applied Physics Letters, Vol. 95, Issue 24
Optimizing the synthesis of carbon nanofiber based electrocatalysts for fuel cells
journal, March 2013
- Sebastián, David; Suelves, Isabel; Moliner, Rafael
- Applied Catalysis B: Environmental, Vol. 132-133
Strongly coupled carbon nanofiber–metal oxide coaxial nanocables with enhanced lithium storage properties
journal, January 2014
- Zhang, Genqiang; Wu, Hao Bin; Hoster, Harry E.
- Energy Environ. Sci., Vol. 7, Issue 1
Ultracompressible, High-Rate Supercapacitors from Graphene-Coated Carbon Nanotube Aerogels
journal, February 2015
- Wilson, Evan; Islam, Mohammad F.
- ACS Applied Materials & Interfaces, Vol. 7, Issue 9
Boron- and Nitrogen-Substituted Graphene Nanoribbons as Efficient Catalysts for Oxygen Reduction Reaction
journal, February 2015
- Gong, Yongji; Fei, Huilong; Zou, Xiaolong
- Chemistry of Materials, Vol. 27, Issue 4
Co–N Decorated Hierarchically Porous Graphene Aerogel for Efficient Oxygen Reduction Reaction in Acid
journal, March 2016
- Fu, Xiaogang; Choi, Ja-Yeon; Zamani, Pouyan
- ACS Applied Materials & Interfaces, Vol. 8, Issue 10
Green synthesis of carbon nanotube–graphene hybrid aerogels and their use as versatile agents for water purification
journal, January 2012
- Sui, Zhuyin; Meng, Qinghan; Zhang, Xuetong
- Journal of Materials Chemistry, Vol. 22, Issue 18
Thermal and electrical conductivity of monolithic carbon aerogels
journal, January 1993
- Lu, Xianping; Nilsson, Ove; Fricke, Jochen
- Journal of Applied Physics, Vol. 73, Issue 2, p. 581-584
Organic aerogels from the polycondensation of resorcinol with formaldehyde
journal, September 1989
- Pekala, R. W.
- Journal of Materials Science, Vol. 24, Issue 9
Advances in Tailoring Resorcinol-Formaldehyde Organic and Carbon Gels
journal, May 2011
- ElKhatat, Ahmed M.; Al-Muhtaseb, Shaheen A.
- Advanced Materials, Vol. 23, Issue 26
Synthesis of Graphene Aerogel with High Electrical Conductivity
journal, October 2010
- Worsley, Marcus A.; Pauzauskie, Peter J.; Olson, Tammy Y.
- Journal of the American Chemical Society, Vol. 132, Issue 40, p. 14067-14069
Superelastic Hard Carbon Nanofiber Aerogels
journal, March 2019
- Yu, Zhi‐Long; Qin, Bing; Ma, Zhi‐Yuan
- Advanced Materials, Vol. 31, Issue 23
Wood-Derived Ultrathin Carbon Nanofiber Aerogels
journal, May 2018
- Li, Si-Cheng; Hu, Bi-Cheng; Ding, Yan-Wei
- Angewandte Chemie International Edition, Vol. 57, Issue 24
Bacterial cellulose derived nitrogen-doped carbon nanofiber aerogel: An efficient metal-free oxygen reduction electrocatalyst for zinc-air battery
journal, January 2015
- Liang, Hai-Wei; Wu, Zhen-Yu; Chen, Li-Feng
- Nano Energy, Vol. 11
Bacterial-Cellulose-Derived Carbon Nanofiber@MnO 2 and Nitrogen-Doped Carbon Nanofiber Electrode Materials: An Asymmetric Supercapacitor with High Energy and Power Density
journal, May 2013
- Chen, Li-Feng; Huang, Zhi-Hong; Liang, Hai-Wei
- Advanced Materials, Vol. 25, Issue 34
Carbon aerogels from bacterial nanocellulose as anodes for lithium ion batteries
journal, January 2014
- Wang, Liping; Schütz, Christina; Salazar-Alvarez, German
- RSC Advances, Vol. 4, Issue 34
Synthesis of Uniform Te@Carbon-Rich Composite Nanocables with Photoluminescence Properties and Carbonaceous Nanofibers by the Hydrothermal Carbonization of Glucose
journal, April 2006
- Qian, Hai-Sheng; Yu, Shu-Hong; Luo, Lin-Bao
- Chemistry of Materials, Vol. 18, Issue 8
Porous carbon nanofiber webs derived from bacterial cellulose as an anode for high performance lithium ion batteries
journal, September 2015
- Wang, Wei; Sun, Ying; Liu, Bing
- Carbon, Vol. 91
Carbon nanofibers by pyrolysis of self-assembled perylene diimide derivative gels as supercapacitor electrode materials
journal, January 2015
- Liu, Xia; Roberts, Aled; Ahmed, Adham
- Journal of Materials Chemistry A, Vol. 3, Issue 30
A Perylene Diimide Crystal with High Capacity and Stable Cyclability for Na-Ion Batteries
journal, September 2015
- Deng, Wenwen; Shen, Yifei; Qian, Jiangfeng
- ACS Applied Materials & Interfaces, Vol. 7, Issue 38
Porous Semiconductor Chalcogenide Aerogels
journal, January 2005
- Mohanan, Jaya L.; Arachchige, Indika U.; Brock, Stephanie L.
- Science, Vol. 307, Issue 5708
Density Tunable Graphene Aerogels Using a Sacrificial Polycyclic Aromatic Hydrocarbon
journal, August 2017
- Turner, Sally; Long, Hu; Shevitski, Brian
- physica status solidi (b), Vol. 254, Issue 11
KOH activation of carbon nanofibers
journal, January 2004
- Yoon, Seong-Ho; Lim, Seongyop; Song, Yan
- Carbon, Vol. 42, Issue 8-9
Carbon dioxide activated carbon nanofibers with hierarchical micro-/mesoporosity towards electrocatalytic oxygen reduction
journal, January 2016
- Chen, Yongfang; Liu, Qian; Wang, Jiacheng
- J. Mater. Chem. A, Vol. 4, Issue 15
Raman Spectrum of Graphene and Graphene Layers
journal, October 2006
- Ferrari, A. C.; Meyer, J. C.; Scardaci, V.
- Physical Review Letters, Vol. 97, Issue 18, Article No. 187401
The Scherrer equation versus the 'Debye-Scherrer equation'
journal, August 2011
- Holzwarth, Uwe; Gibson, Neil
- Nature Nanotechnology, Vol. 6, Issue 9
Electrical and spectroscopic investigations on the reduction mechanism of graphene oxide
journal, April 2013
- Obata, Seiji; Tanaka, Hiroshige; Saiki, Koichiro
- Carbon, Vol. 55
Carbon nano-rod as a structural unit of carbon nanofibers
journal, January 2004
- Yoon, Seong-Ho; Lim, Seongyop; Hong, Seong-hwa
- Carbon, Vol. 42, Issue 15
Making graphene on a large scale
journal, April 2009
- Obraztsov, Alexander N.
- Nature Nanotechnology, Vol. 4, Issue 4
Defect Engineering and Surface Functionalization of Nanocarbons for Metal‐Free Catalysis
journal, January 2019
- Ortiz‐Medina, Josue; Wang, Zhipeng; Cruz‐Silva, Rodolfo
- Advanced Materials, Vol. 31, Issue 13
Significant Contribution of Intrinsic Carbon Defects to Oxygen Reduction Activity
journal, October 2015
- Jiang, Yufei; Yang, Lijun; Sun, Tao
- ACS Catalysis, Vol. 5, Issue 11
Plasmon-Enhanced Photocatalytic Activity of Iron Oxide on Gold Nanopillars
journal, December 2011
- Gao, Hanwei; Liu, Chong; Jeong, Hoon Eui
- ACS Nano, Vol. 6, Issue 1
Plasmonic Enhancement of Dye-Sensitized Solar Cells Using Core–Shell–Shell Nanostructures
journal, January 2013
- Sheehan, Stafford W.; Noh, Heeso; Brudvig, Gary W.
- The Journal of Physical Chemistry C, Vol. 117, Issue 2
Electrospun Palladium Nanoparticle-Loaded Carbon Nanofibers and Their Electrocatalytic Activities towards Hydrogen Peroxide and NADH
journal, February 2008
- Huang, Jianshe; Wang, Dawei; Hou, Haoqing
- Advanced Functional Materials, Vol. 18, Issue 3
Efficient Synthesis of Pt Nanoparticles Supported on Hydrophobic Graphitized Carbon Nanofibers for Electrocatalysts Using Noncovalent Functionalization
journal, August 2011
- Oh, Hyung-Suk; Kim, Hansung
- Advanced Functional Materials, Vol. 21, Issue 20