Bioinspired nacre-like alumina with a bulk-metallic glass-forming alloy as a compliant phase

Wat, Amy; Lee, Je In; Ryu, Chae Woo; Gludovatz, Bernd; Kim, Jinyeon; Tomsia, Antoni P.; Ishikawa, Takehiko; Schmitz, Julianna; Meyer, Andreas; Alfreider, Markus; Kiener, Daniel; Park, Eun Soo; Ritchie, Robert O.

doi:10.1038/s41467-019-08753-6

Title: Bioinspired nacre-like alumina with a bulk-metallic glass-forming alloy as a compliant phase

Journal Article · 27 February 2019 · Nature Communications

DOI: https://doi.org/10.1038/s41467-019-08753-6 · OSTI ID:1559188

Wat, Amy ^[1]; Lee, Je In ^[2]; Ryu, Chae Woo ^[3]; Gludovatz, Bernd ^[4]; Kim, Jinyeon ^[5]; Tomsia, Antoni P. ^[6]; Ishikawa, Takehiko ^[7]; Schmitz, Julianna ^[8]; Meyer, Andreas ^[8]; Alfreider, Markus ^[9];

^[9];

^[3];

^[10]

Univ. of California, Berkeley, CA (United States)
Seoul National Univ. (Korea, Republic of); National Institute for Materials Science, Tsukuba, Ibaraki (Japan)
Seoul National Univ. (Korea, Republic of)
UNSW Sydney, NSW (Australia)
Seoul National Univ. (Korea, Republic of); Korea Inst. of Science and Technology, Seoul (Korea, Republic of)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Japan Aerospace Explanation Agency, Tsukuba, Ibaraki (Japan)
Institut für Materialphysik im Weltraum, DLR, Köln (Germany)
Montanuniversität Leoben (Austria)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Bioinspired ceramics with micron-scale ceramic "bricks" bonded by a metallic "mortar" are projected to result in higher strength and toughness ceramics, but their processing is challenging as metals do not typically wet ceramics. To resolve this issue, we made alumina structures using rapid pressureless infiltration of a zirconium-based bulk-metallic glass mortar that reactively wets the surface of freeze-cast alumina preforms. The mechanical properties of the resulting Al₂O₃ with a glass-forming compliant-phase change with infiltration temperature and ceramic content, leading to a trade-off between flexural strength (varying from 89 to 800 MPa) and fracture toughness (varying from 4 to more than 9 MPa·m^½). The high toughness levels are attributed to brick pull-out and crack deflection along the ceramic/metal interfaces. Since these mechanisms are enabled by interfacial failure rather than failure within the metallic mortar, the potential for optimizing these bioinspired materials for damage tolerance has still not been fully realized.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1559188

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 10; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Hierarchical nanostructured aluminum alloy with ultrahigh strength and large plasticity Wu, Ge; Liu, Chang; Sun, Ligang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13087-4	journal	November 2019
Fabrication and Mechanics of Bioinspired Materials with Dense Architectures: Current Status and Future Perspectives Mirkhalaf, Mohammad; Zreiqat, Hala Unpublished https://doi.org/10.13140/rg.2.2.24854.09284	text	January 2019
Bioinspired Materials: From Living Systems to New Concepts in Materials Chemistry Böhm, Corinna F.; Harris, Joe; Schodder, Philipp I. Materials, Vol. 12, Issue 13 https://doi.org/10.3390/ma12132117	journal	July 2019

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