Molecular flexure and atom trapping with sexiphenyl molecules by scanning tunneling microscope manipulation
Abstract
Molecular flexure, and molecule-metal contact of para-sexiphenyl molecules on a Ag(111) surface are investigated by using low temperature scanning tunneling microscopy, and molecular manipulations. Atom trapping with sexiphenyl molecules is realized by laterally manipulating the molecules onto individual silver atoms and up to three silver atoms have been trapped. We also demonstrate breaking of a silver dimer into individual silver atoms by atom trapping. STM manipulation experiments show that the molecule-metal complexes formed by the atom trapping are mechanically stable. Moreover, Lateral manipulation of a single sexiphenyl across a Ag(111) atomic step highlights how the molecule moves across step-edges; the molecule can easily conform across the step and it recovers original configuration after the manipulation.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
- Ohio Univ., Athens, OH (United States). Nanoscale and Quantum Phenomena Inst., and Physics & Astronomy Dept.
- Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials; Ohio Univ., Athens, OH (United States). Nanoscale and Quantum Phenomena Inst., and Physics & Astronomy Dept.
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1558988
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Surface Science
- Additional Journal Information:
- Journal Volume: 678; Journal Issue: C; Journal ID: ISSN 0039-6028
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Ag(111); Para-sexiphenyl; STM; atom trapping; single atom and molecule manipulation
Citation Formats
Zhang, Yuan, Wang, Shaoze, Braun, Kai-Felix, and Hla, Saw-Wai. Molecular flexure and atom trapping with sexiphenyl molecules by scanning tunneling microscope manipulation. United States: N. p., 2018.
Web. doi:10.1016/j.susc.2018.07.004.
Zhang, Yuan, Wang, Shaoze, Braun, Kai-Felix, & Hla, Saw-Wai. Molecular flexure and atom trapping with sexiphenyl molecules by scanning tunneling microscope manipulation. United States. https://doi.org/10.1016/j.susc.2018.07.004
Zhang, Yuan, Wang, Shaoze, Braun, Kai-Felix, and Hla, Saw-Wai. Sat .
"Molecular flexure and atom trapping with sexiphenyl molecules by scanning tunneling microscope manipulation". United States. https://doi.org/10.1016/j.susc.2018.07.004. https://www.osti.gov/servlets/purl/1558988.
@article{osti_1558988,
title = {Molecular flexure and atom trapping with sexiphenyl molecules by scanning tunneling microscope manipulation},
author = {Zhang, Yuan and Wang, Shaoze and Braun, Kai-Felix and Hla, Saw-Wai},
abstractNote = {Molecular flexure, and molecule-metal contact of para-sexiphenyl molecules on a Ag(111) surface are investigated by using low temperature scanning tunneling microscopy, and molecular manipulations. Atom trapping with sexiphenyl molecules is realized by laterally manipulating the molecules onto individual silver atoms and up to three silver atoms have been trapped. We also demonstrate breaking of a silver dimer into individual silver atoms by atom trapping. STM manipulation experiments show that the molecule-metal complexes formed by the atom trapping are mechanically stable. Moreover, Lateral manipulation of a single sexiphenyl across a Ag(111) atomic step highlights how the molecule moves across step-edges; the molecule can easily conform across the step and it recovers original configuration after the manipulation.},
doi = {10.1016/j.susc.2018.07.004},
journal = {Surface Science},
number = C,
volume = 678,
place = {United States},
year = {Sat Dec 01 00:00:00 EST 2018},
month = {Sat Dec 01 00:00:00 EST 2018}
}
Web of Science
Works referenced in this record:
Epitaxy of highly ordered organic semiconductor crystallite networks supported by hexagonal boron nitride
journal, December 2016
- Matković, Aleksandar; Genser, Jakob; Lüftner, Daniel
- Scientific Reports, Vol. 6, Issue 1
Intra- and Intermolecular Band Dispersion in an Organic Crystal
journal, July 2007
- Koller, G.; Berkebile, S.; Oehzelt, M.
- Science, Vol. 317, Issue 5836
Self-Waveguided Gain-Narrowing of Blue Light Emission from Epitaxially Oriented p-Sexiphenyl Crystals
journal, September 2001
- Yanagi, H.; Ohara, T.; Morikawa, T.
- Advanced Materials, Vol. 13, Issue 19
Orientation-controlled organic electroluminescence of p-sexiphenyl films
journal, November 1997
- Yanagi, H.; Okamoto, S.
- Applied Physics Letters, Vol. 71, Issue 18
Random laser action in self-organized para-sexiphenyl nanofibers grown by hot-wall epitaxy
journal, May 2004
- Quochi, F.; Cordella, F.; Orrù, R.
- Applied Physics Letters, Vol. 84, Issue 22
Color Tuning of Nanofibers by Periodic Organic–Organic Hetero-Epitaxy
journal, May 2012
- Simbrunner, Clemens; Hernandez-Sosa, Gerardo; Quochi, Francesco
- ACS Nano, Vol. 6, Issue 6
On the nucleation and initial film growth of rod-like organic molecules
journal, October 2016
- Winkler, Adolf
- Surface Science, Vol. 652
Reconstruction of Molecular Orbital Densities from Photoemission Data
journal, September 2009
- Puschnig, P.; Berkebile, S.; Fleming, A. J.
- Science, Vol. 326, Issue 5953
Characterization of Step-Edge Barriers in Organic Thin-Film Growth
journal, July 2008
- Hlawacek, G.; Puschnig, P.; Frank, P.
- Science, Vol. 321, Issue 5885
Electrostatic-Field-Driven Alignment of Organic Oligomers on ZnO Surfaces
journal, September 2011
- Della Sala, F.; Blumstengel, S.; Henneberger, F.
- Physical Review Letters, Vol. 107, Issue 14
Device relevant organic films and interfaces: A surface science approach
journal, December 2007
- Koller, G.; Berkebile, S.; Ivanco, J.
- Surface Science, Vol. 601, Issue 24
Highly Anisotropically Self-Assembled Structures ofpara-Sexiphenyl Grown by Hot-Wall Epitaxy
journal, May 2000
- Andreev, A.; Matt, G.; Brabec, C. J.
- Advanced Materials, Vol. 12, Issue 9
Ab initio investigation of the electronic properties of planar and twisted polyparaphenylenes
journal, July 1996
- Champagne, Benoît; Mosley, David H.; Fripiat, Joseph G.
- Physical Review B, Vol. 54, Issue 4
Probing the Conformation of Physisorbed Molecules at the Atomic Scale Using STM Manipulation
journal, January 2005
- Braun, Kai-Felix; Hla, Saw-Wai
- Nano Letters, Vol. 5, Issue 1
Energy levels at interfaces between metals and conjugated organic molecules
journal, April 2008
- Koch, Norbert
- Journal of Physics: Condensed Matter, Vol. 20, Issue 18
Electronic structure and electron dynamics at molecule?metal interfaces: implications for molecule-based electronics
journal, November 2004
- Zhu, X.
- Surface Science Reports, Vol. 56, Issue 1-2
Resolving metal-molecule interfaces at single-molecule junctions
journal, May 2016
- Komoto, Yuki; Fujii, Shintaro; Nakamura, Hisao
- Scientific Reports, Vol. 6, Issue 1
Unimolecular Logic Gate with Classical Input by Single Gold Atoms
journal, January 2018
- Skidin, Dmitry; Faizy, Omid; Krüger, Justus
- ACS Nano, Vol. 12, Issue 2
Supramolecular Rotor and Translator at Work: On-Surface Movement of Single Atoms
journal, July 2015
- Ohmann, Robin; Meyer, Jörg; Nickel, Anja
- ACS Nano, Vol. 9, Issue 8
Manipulating Molecular Quantum States with Classical Metal Atom Inputs: Demonstration of a Single Molecule NOR Logic Gate
journal, January 2011
- Soe, We-Hyo; Manzano, Carlos; Renaud, Nicolas
- ACS Nano, Vol. 5, Issue 2
Manipulation of a single molecule ground state by means of gold atom contacts
journal, November 2013
- Manzano, C.; Soe, W. H.; Hliwa, M.
- Chemical Physics Letters, Vol. 587
Trapping and moving metal atoms with a six-leg molecule
journal, November 2005
- Gross, Leo; Rieder, Karl-Heinz; Moresco, Francesca
- Nature Materials, Vol. 4, Issue 12
Imaging Bond Formation Between a Gold Atom and Pentacene on an Insulating Surface
journal, May 2006
- Repp, J.
- Science, Vol. 312, Issue 5777
Tuning the Electronic and Dynamical Properties of a Molecule by Atom Trapping Chemistry
journal, September 2017
- Pham, Van Dong; Repain, Vincent; Chacon, Cyril
- ACS Nano, Vol. 11, Issue 11
Atom-by-atom assembly
journal, May 2014
- Hla, Saw Wai
- Reports on Progress in Physics, Vol. 77, Issue 5
Atom-By-Atom Extraction Using the Scanning Tunneling Microscope Tip-Cluster Interaction
journal, January 2007
- Deshpande, A.; Yildirim, H.; Kara, A.
- Physical Review Letters, Vol. 98, Issue 2
Magnetization of potassium-doped -terphenyl and -quaterphenyl by high-pressure synthesis
journal, December 2017
- Liu, Wenhao; Lin, Hai; Kang, Ruizhe
- Physical Review B, Vol. 96, Issue 22
Structural and Bonding Characteristics of Potassium-Doped p -Terphenyl Superconductors
journal, February 2018
- Zhong, Guo-Hua; Wang, Xiao-Hui; Wang, Ren-Shu
- The Journal of Physical Chemistry C, Vol. 122, Issue 7
Step Motion on Crystal Surfaces
journal, September 1966
- Schwoebel, Richard L.; Shipsey, Edward J.
- Journal of Applied Physics, Vol. 37, Issue 10
Works referencing / citing this record:
Towards atomic and close-to-atomic scale manufacturing
journal, April 2019
- Fang, Fengzhou; Zhang, Nan; Guo, Dongming
- International Journal of Extreme Manufacturing, Vol. 1, Issue 1