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Title: Synthesis, Characterization, and HER Activity of Pendant Diamine Derivatives of NiATSM

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [1];  [2]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry University of Louisville 2320 South Brook Street 40292 Louisville KY USA
  2. Conn Center for Renewable Energy Research University of Louisville 40292 Louisville KY USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1558811
Grant/Contract Number:  
DEFG02‐08CH11538
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
European Journal of Inorganic Chemistry
Additional Journal Information:
Journal Name: European Journal of Inorganic Chemistry Journal Volume: 2019 Journal Issue: 33; Journal ID: ISSN 1434-1948
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Calvary, Caleb A., Hietsoi, Oleksandr, Strain, Jacob M., Mashuta, Mark S., Spurgeon, Joshua M., Buchanan, Robert M., and Grapperhaus, Craig A. Synthesis, Characterization, and HER Activity of Pendant Diamine Derivatives of NiATSM. Germany: N. p., 2019. Web. https://doi.org/10.1002/ejic.201900721.
Calvary, Caleb A., Hietsoi, Oleksandr, Strain, Jacob M., Mashuta, Mark S., Spurgeon, Joshua M., Buchanan, Robert M., & Grapperhaus, Craig A. Synthesis, Characterization, and HER Activity of Pendant Diamine Derivatives of NiATSM. Germany. https://doi.org/10.1002/ejic.201900721
Calvary, Caleb A., Hietsoi, Oleksandr, Strain, Jacob M., Mashuta, Mark S., Spurgeon, Joshua M., Buchanan, Robert M., and Grapperhaus, Craig A. Mon . "Synthesis, Characterization, and HER Activity of Pendant Diamine Derivatives of NiATSM". Germany. https://doi.org/10.1002/ejic.201900721.
@article{osti_1558811,
title = {Synthesis, Characterization, and HER Activity of Pendant Diamine Derivatives of NiATSM},
author = {Calvary, Caleb A. and Hietsoi, Oleksandr and Strain, Jacob M. and Mashuta, Mark S. and Spurgeon, Joshua M. and Buchanan, Robert M. and Grapperhaus, Craig A.},
abstractNote = {},
doi = {10.1002/ejic.201900721},
journal = {European Journal of Inorganic Chemistry},
number = 33,
volume = 2019,
place = {Germany},
year = {2019},
month = {8}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/ejic.201900721

Citation Metrics:
Cited by: 3 works
Citation information provided by
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Works referenced in this record:

The Artificial Leaf
journal, January 2012

  • Nocera, Daniel G.
  • Accounts of Chemical Research, Vol. 45, Issue 5
  • DOI: 10.1021/ar2003013

Metal-Free and Noble Metal-Free Heteroatom-Doped Nanostructured Carbons as Prospective Sustainable Electrocatalysts
journal, September 2016


High-performance Platinum-free oxygen reduction reaction and hydrogen oxidation reaction catalyst in polymer electrolyte membrane fuel cell
journal, February 2018


Light-driven hydrogen evolution with a nickel thiosemicarbazone redox catalyst featuring Ni⋯H interactions under basic conditions
journal, January 2015

  • Jing, Xu; Wu, Pengyan; Liu, Xin
  • New Journal of Chemistry, Vol. 39, Issue 2
  • DOI: 10.1039/C4NJ01540A

[NiFeSe]-Hydrogenase Chemistry
journal, October 2015


Structure validation in chemical crystallography
journal, January 2009

  • Spek, Anthony L.
  • Acta Crystallographica Section D Biological Crystallography, Vol. 65, Issue 2, p. 148-155
  • DOI: 10.1107/S090744490804362X

A family of molecular nickel hydrogen evolution catalysts providing tunable overpotentials using ligand-centered proton-coupled electron transfer paths
journal, January 2018

  • Aimoto, Yutaro; Koshiba, Keita; Yamauchi, Kosei
  • Chemical Communications, Vol. 54, Issue 91
  • DOI: 10.1039/C8CC07467D

Mesoporous Platinum Prepared by Electrodeposition for Ultralow Loading Proton Exchange Membrane Fuel Cells
journal, March 2019


Natural inspirations for metal–ligand cooperative catalysis
journal, December 2017


Reactions of H 2 with the Nickel Site(s) of the [FeNi] and [FeNiSe] Hydrogenases: What Do the Model Complexes Suggest?
journal, December 1995

  • Goldman, Christine Marganian; Mascharak, Pradip K.
  • Comments on Inorganic Chemistry, Vol. 18, Issue 1
  • DOI: 10.1080/02603599508033861

A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

WinGX and ORTEP for Windows : an update
journal, July 2012


Proton-coupled electron transfer kinetics for the hydrogen evolution reaction of hangman porphyrins
journal, January 2012

  • Roubelakis, Manolis M.; Bediako, D. Kwabena; Dogutan, Dilek K.
  • Energy & Environmental Science, Vol. 5, Issue 7
  • DOI: 10.1039/c2ee21123h

Pendant Bases as Proton Relays in Iron Hydride and Dihydrogen Complexes
journal, March 2006

  • Henry, Renee M.; Shoemaker, Richard K.; DuBois, Daniel L.
  • Journal of the American Chemical Society, Vol. 128, Issue 9
  • DOI: 10.1021/ja057242p

Molecular Electrocatalysts for the Oxidation of Hydrogen and the Production of Hydrogen - The Role of Pendant Amines as Proton Relays
journal, January 2011

  • DuBois, Daniel L.; Bullock, R. Morris
  • European Journal of Inorganic Chemistry, Vol. 2011, Issue 7
  • DOI: 10.1002/ejic.201001081

Hydrogen Evolution Reactions Catalyzed by a Bis(thiosemicarbazone) Cobalt Complex: An Experimental and Theoretical Study
journal, June 2018

  • Straistari, Tatiana; Hardré, Renaud; Fize, Jennifer
  • Chemistry - A European Journal, Vol. 24, Issue 35
  • DOI: 10.1002/chem.201801155

Redox Potential and Electronic Structure Effects of Proximal Nonredox Active Cations in Cobalt Schiff Base Complexes
journal, February 2017


A nickel complex of a conjugated bis-dithiocarbazate Schiff base for the photocatalytic production of hydrogen
journal, January 2015

  • Wise, Catherine F.; Liu, Dan; Mayer, Kathryn J.
  • Dalton Transactions, Vol. 44, Issue 32
  • DOI: 10.1039/C5DT02042E

Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins
journal, October 2014

  • Bediako, D. Kwabena; Solis, Brian H.; Dogutan, Dilek K.
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 42
  • DOI: 10.1073/pnas.1414908111

Beyond Metal-Hydrides: Non-Transition-Metal and Metal-Free Ligand-Centered Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation
journal, June 2016

  • Haddad, Andrew Z.; Garabato, Brady D.; Kozlowski, Pawel M.
  • Journal of the American Chemical Society, Vol. 138, Issue 25
  • DOI: 10.1021/jacs.6b04441

Controlled Axial Coordination: Solid-Phase Synthesis and Purification of Metallo-Radiopharmaceuticals
journal, October 2008

  • Betts, Helen M.; Barnard, Peter J.; Bayly, Simon R.
  • Angewandte Chemie, Vol. 120, Issue 44
  • DOI: 10.1002/ange.200801936

High-efficiency hydrogen evolution reaction catalyzed by iron phosphide nanocrystals
journal, January 2016

  • Gao, Zhichao; Gao, Qian; Liu, Zhipeng
  • RSC Advances, Vol. 6, Issue 115
  • DOI: 10.1039/C6RA24186G

Mimicking hydrogenases: From biomimetics to artificial enzymes
journal, July 2014

  • Simmons, Trevor R.; Berggren, Gustav; Bacchi, Marine
  • Coordination Chemistry Reviews, Vol. 270-271
  • DOI: 10.1016/j.ccr.2013.12.018

A Thiosemicarbazone-Nickel(II) Complex as Efficient Electrocatalyst for Hydrogen Evolution
journal, November 2016

  • Straistari, Tatiana; Fize, Jennifer; Shova, Sergiu
  • ChemCatChem, Vol. 9, Issue 12
  • DOI: 10.1002/cctc.201600967

Pathways of H2 toward the Active Site of [NiFe]-Hydrogenase
journal, September 2006

  • Teixeira, Vitor H.; Baptista, António M.; Soares, Cláudio M.
  • Biophysical Journal, Vol. 91, Issue 6
  • DOI: 10.1529/biophysj.106.084376

H 2 Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation
journal, November 2010

  • Fourmond, Vincent; Jacques, Pierre-André; Fontecave, Marc
  • Inorganic Chemistry, Vol. 49, Issue 22
  • DOI: 10.1021/ic101187v

Mechanism of H 2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides
journal, July 2016

  • Ulloa, Olbelina A.; Huynh, Mioy T.; Richers, Casseday P.
  • Journal of the American Chemical Society, Vol. 138, Issue 29
  • DOI: 10.1021/jacs.6b04579

Ligand-Assisted Metal-Centered Electrocatalytic Hydrogen Evolution upon Reduction of a Bis(thiosemicarbazonato)Ni(II) Complex
journal, October 2018


Cobalt Porphyrin–Polypyridyl Surface Coatings for Photoelectrosynthetic Hydrogen Production
journal, October 2017


Metal-Assisted Ligand-Centered Electrocatalytic Hydrogen Evolution upon Reduction of a Bis(thiosemicarbazonato)Cu(II) Complex
journal, August 2017


Structural trends in copper( ii ) bis(thiosemicarbazone) radiopharmaceuticals
journal, January 2003

  • Blower, Philip J.; Castle, Thomas C.; Cowley, Andrew R.
  • Dalton Trans., Issue 23
  • DOI: 10.1039/B307499D

Exploiting Copper Redox for 19 F Magnetic Resonance-Based Detection of Cellular Hypoxia
journal, February 2016

  • Xie, Da; King, Tyler L.; Banerjee, Arnab
  • Journal of the American Chemical Society, Vol. 138, Issue 9
  • DOI: 10.1021/jacs.5b13215

Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds
journal, November 2010

  • Cook, Timothy R.; Dogutan, Dilek K.; Reece, Steven Y.
  • Chemical Reviews, Vol. 110, Issue 11
  • DOI: 10.1021/cr100246c

Photocatalytic hydrogen production
journal, January 2011

  • Teets, Thomas S.; Nocera, Daniel G.
  • Chemical Communications, Vol. 47, Issue 33
  • DOI: 10.1039/c1cc12390d

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis
journal, June 2012

  • Costentin, Cyrille; Drouet, Samuel; Robert, Marc
  • Journal of the American Chemical Society, Vol. 134, Issue 27, p. 11235-11242
  • DOI: 10.1021/ja303560c

First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
journal, January 2013

  • Kong, Desheng; Cha, Judy J.; Wang, Haotian
  • Energy & Environmental Science, Vol. 6, Issue 12
  • DOI: 10.1039/c3ee42413h

Recent Development in Hydrogen Evolution Reaction Catalysts and Their Practical Implementation
journal, March 2015

  • Vesborg, Peter C. K.; Seger, Brian; Chorkendorff, Ib
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 6
  • DOI: 10.1021/acs.jpclett.5b00306

Mechanism of Proton Transfer in [FeFe]-Hydrogenase from Clostridium pasteurianum
journal, September 2011

  • Cornish, Adam J.; Gärtner, Katrin; Yang, Hui
  • Journal of Biological Chemistry, Vol. 286, Issue 44
  • DOI: 10.1074/jbc.M111.254664

Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts
journal, May 2017

  • Lee, Katherine J.; Elgrishi, Noémie; Kandemir, Banu
  • Nature Reviews Chemistry, Vol. 1, Issue 5
  • DOI: 10.1038/s41570-017-0039

Controlled Axial Coordination: Solid-Phase Synthesis and Purification of Metallo-Radiopharmaceuticals
journal, October 2008

  • Betts, Helen M.; Barnard, Peter J.; Bayly, Simon R.
  • Angewandte Chemie International Edition, Vol. 47, Issue 44
  • DOI: 10.1002/anie.200801936

Acidities of strong neutral Brønsted acids in different media: ACIDITIES OF STRONG NEUTRAL BRØNSTED ACIDS
journal, May 2012

  • Raamat, Elin; Kaupmees, Karl; Ovsjannikov, Gea
  • Journal of Physical Organic Chemistry, Vol. 26, Issue 2
  • DOI: 10.1002/poc.2946

A Functional [NiFe]-Hydrogenase Model Compound That Undergoes Biologically Relevant Reversible Thiolate Protonation
journal, December 2012

  • Weber, Katharina; Krämer, Tobias; Shafaat, Hannah S.
  • Journal of the American Chemical Society, Vol. 134, Issue 51
  • DOI: 10.1021/ja309563p