Resolving structures of transition metal complex reaction intermediates with femtosecond EXAFS
Abstract
Femtosecond-resolved Extended X-ray Absorption Fine Structure (EXAFS) measurements of solvated transition metal complexes are successfully implemented at the X-ray Free Electron Laser LCLS. Benchmark experiments on [Fe(terpy)2]2+ in solution show a signal-to-noise ratio on the order of 500, comparable to typical 100 ps-resolution synchrotron measurements. In the few femtoseconds after photoexcitation, we observe the EXAFS fingerprints of a short-lived (B100 fs) intermediate as well as those of a vibrationally hot long-lived (Bns) excited state.
- Authors:
-
- Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, USA, Linac Coherent Light Source
- Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, USA, Stanford Synchrotron Radiation Lightsource
- Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, USA
- Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, USA
- SUNCAT Center for Interface Science and Catalysis, Department of Chemical Engineering, Stanford University, Stanford, USA
- Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, USA
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1558679
- Alternate Identifier(s):
- OSTI ID: 1546779
- Grant/Contract Number:
- AC02-76SF00515; SC0014607
- Resource Type:
- Published Article
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP (Print)
- Additional Journal Information:
- Journal Name: Physical Chemistry Chemical Physics. PCCP (Print) Journal Volume: 22 Journal Issue: 5; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS
Citation Formats
Britz, Alexander, Abraham, Baxter, Biasin, Elisa, van Driel, Tim Brandt, Gallo, Alessandro, Garcia-Esparza, Angel T., Glownia, James, Loukianov, Anton, Nelson, Silke, Reinhard, Marco, Sokaras, Dimosthenis, and Alonso-Mori, Roberto. Resolving structures of transition metal complex reaction intermediates with femtosecond EXAFS. United Kingdom: N. p., 2020.
Web. doi:10.1039/C9CP03483H.
Britz, Alexander, Abraham, Baxter, Biasin, Elisa, van Driel, Tim Brandt, Gallo, Alessandro, Garcia-Esparza, Angel T., Glownia, James, Loukianov, Anton, Nelson, Silke, Reinhard, Marco, Sokaras, Dimosthenis, & Alonso-Mori, Roberto. Resolving structures of transition metal complex reaction intermediates with femtosecond EXAFS. United Kingdom. https://doi.org/10.1039/C9CP03483H
Britz, Alexander, Abraham, Baxter, Biasin, Elisa, van Driel, Tim Brandt, Gallo, Alessandro, Garcia-Esparza, Angel T., Glownia, James, Loukianov, Anton, Nelson, Silke, Reinhard, Marco, Sokaras, Dimosthenis, and Alonso-Mori, Roberto. Wed .
"Resolving structures of transition metal complex reaction intermediates with femtosecond EXAFS". United Kingdom. https://doi.org/10.1039/C9CP03483H.
@article{osti_1558679,
title = {Resolving structures of transition metal complex reaction intermediates with femtosecond EXAFS},
author = {Britz, Alexander and Abraham, Baxter and Biasin, Elisa and van Driel, Tim Brandt and Gallo, Alessandro and Garcia-Esparza, Angel T. and Glownia, James and Loukianov, Anton and Nelson, Silke and Reinhard, Marco and Sokaras, Dimosthenis and Alonso-Mori, Roberto},
abstractNote = {Femtosecond-resolved Extended X-ray Absorption Fine Structure (EXAFS) measurements of solvated transition metal complexes are successfully implemented at the X-ray Free Electron Laser LCLS. Benchmark experiments on [Fe(terpy)2]2+ in solution show a signal-to-noise ratio on the order of 500, comparable to typical 100 ps-resolution synchrotron measurements. In the few femtoseconds after photoexcitation, we observe the EXAFS fingerprints of a short-lived (B100 fs) intermediate as well as those of a vibrationally hot long-lived (Bns) excited state.},
doi = {10.1039/C9CP03483H},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 5,
volume = 22,
place = {United Kingdom},
year = {2020},
month = {2}
}
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https://doi.org/10.1039/C9CP03483H
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