skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Preparation of Macroscopic Block‐Copolymer‐Based Gyroidal Mesoscale Single Crystals by Solvent Evaporation

Authors:
ORCiD logo [1]; ORCiD logo [1];  [2]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [1]
  1. Department of Materials Science and Engineering Cornell University Ithaca NY 14853 USA
  2. Department of Materials Science and Engineering Cornell University Ithaca NY 14853 USA, Robert Frederick Smith School of Chemical and Biomolecular Engineering Cornell University Ithaca NY 14853 USA
  3. Department of Physics Cornell University Ithaca NY 14853 USA, Kavli Institute at Cornell for Nanoscale Science Ithaca NY 14853 USA
  4. Department of Materials Science and Engineering Cornell University Ithaca NY 14853 USA, Kavli Institute at Cornell for Nanoscale Science Ithaca NY 14853 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1558671
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials Journal Volume: 31 Journal Issue: 40; Journal ID: ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Susca, Ethan M., Beaucage, Peter A., Thedford, R. Paxton, Singer, Andrej, Gruner, Sol M., Estroff, Lara A., and Wiesner, Ulrich. Preparation of Macroscopic Block‐Copolymer‐Based Gyroidal Mesoscale Single Crystals by Solvent Evaporation. Germany: N. p., 2019. Web. https://doi.org/10.1002/adma.201902565.
Susca, Ethan M., Beaucage, Peter A., Thedford, R. Paxton, Singer, Andrej, Gruner, Sol M., Estroff, Lara A., & Wiesner, Ulrich. Preparation of Macroscopic Block‐Copolymer‐Based Gyroidal Mesoscale Single Crystals by Solvent Evaporation. Germany. https://doi.org/10.1002/adma.201902565
Susca, Ethan M., Beaucage, Peter A., Thedford, R. Paxton, Singer, Andrej, Gruner, Sol M., Estroff, Lara A., and Wiesner, Ulrich. Thu . "Preparation of Macroscopic Block‐Copolymer‐Based Gyroidal Mesoscale Single Crystals by Solvent Evaporation". Germany. https://doi.org/10.1002/adma.201902565.
@article{osti_1558671,
title = {Preparation of Macroscopic Block‐Copolymer‐Based Gyroidal Mesoscale Single Crystals by Solvent Evaporation},
author = {Susca, Ethan M. and Beaucage, Peter A. and Thedford, R. Paxton and Singer, Andrej and Gruner, Sol M. and Estroff, Lara A. and Wiesner, Ulrich},
abstractNote = {},
doi = {10.1002/adma.201902565},
journal = {Advanced Materials},
number = 40,
volume = 31,
place = {Germany},
year = {2019},
month = {8}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/adma.201902565

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Nanostructure engineering by templated self-assembly of block copolymers
journal, October 2004

  • Cheng, Joy Y.; Mayes, Anne M.; Ross, Caroline A.
  • Nature Materials, Vol. 3, Issue 11
  • DOI: 10.1038/nmat1211

Microdomain patterns from directional eutectic solidification and epitaxy
journal, May 2000

  • De Rosa, Claudio; Park, Cheolmin; Thomas, Edwin L.
  • Nature, Vol. 405, Issue 6785, p. 433-437
  • DOI: 10.1038/35013018

A Bicontinuous Double Gyroid Hybrid Solar Cell
journal, August 2009

  • Crossland, Edward J. W.; Kamperman, Marleen; Nedelcu, Mihaela
  • Nano Letters, Vol. 9, Issue 8
  • DOI: 10.1021/nl803174p

A Noncubic Triply Periodic Network Morphology in Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers
journal, August 2002

  • Bailey, Travis S.; Hardy, Cordell M.; Epps, Thomas H.
  • Macromolecules, Vol. 35, Issue 18
  • DOI: 10.1021/ma011716x

X-ray line broadening from filed aluminium and wolfram
journal, January 1953


Exploring Periodic Bicontinuous Cubic Network Structures with Complete Phononic Bandgaps
journal, September 2017

  • Hur, Kahyun; Hennig, Richard G.; Wiesner, Ulrich
  • The Journal of Physical Chemistry C, Vol. 121, Issue 40
  • DOI: 10.1021/acs.jpcc.7b07267

Single-Grain Lamellar Microdomain from a Diblock Copolymer
journal, March 1999

  • Bodycomb, Jeffrey; Funaki, Yoshinori; Kimishima, Kohtaro
  • Macromolecules, Vol. 32, Issue 6
  • DOI: 10.1021/ma981538g

Spatial and Orientation Control of Cylindrical Nanostructures in ABA Triblock Copolymer Thin Films by Raster Solvent Vapor Annealing
journal, October 2012

  • Seppala, Jonathan E.; Lewis, Ronald L.; Epps, Thomas H.
  • ACS Nano, Vol. 6, Issue 11
  • DOI: 10.1021/nn303416p

Multiblock Polymers: Panacea or Pandora's Box?
journal, April 2012


Self-Assembled Gyroidal Mesoporous Polymer-Derived High Temperature Ceramic Monoliths
journal, March 2016


Synthesis and Characterization of Gyroidal Mesoporous Carbons and Carbon Monoliths with Tunable Ultralarge Pore Size
journal, December 2013

  • Werner, Jörg G.; Hoheisel, Tobias N.; Wiesner, Ulrich
  • ACS Nano, Vol. 8, Issue 1
  • DOI: 10.1021/nn405392t

Pathways to Macroscale Order in Nanostructured Block Copolymers
journal, August 1997


Lamellar diblock copolymers under large amplitude oscillatory shear flow: Order and dynamics
journal, November 1997


A Re-Evaluation of the Morphology of a Bicontinuous Block Copolymer−Ceramic Material
journal, December 2007

  • Toombes, Gilman E. S.; Finnefrock, Adam C.; Tate, Mark W.
  • Macromolecules, Vol. 40, Issue 25
  • DOI: 10.1021/ma0715369

Soft self-assembly of Weyl materials for light and sound
journal, April 2018

  • Fruchart, Michel; Jeon, Seung-Yeol; Hur, Kahyun
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 16
  • DOI: 10.1073/pnas.1720828115

Three-Dimensionally Isotropic Negative Refractive Index Materials from Block Copolymer Self-Assembled Chiral Gyroid Networks
journal, October 2011

  • Hur, Kahyun; Francescato, Yan; Giannini, Vincenzo
  • Angewandte Chemie International Edition, Vol. 50, Issue 50
  • DOI: 10.1002/anie.201104888

Block copolymer self-assembly–directed synthesis of mesoporous gyroidal superconductors
journal, January 2016

  • Robbins, Spencer W.; Beaucage, Peter A.; Sai, Hiroaki
  • Science Advances, Vol. 2, Issue 1
  • DOI: 10.1126/sciadv.1501119

Giant Gyroid and Templates from High-Molecular-Weight Block Copolymer Self-assembly
journal, November 2016

  • Park, Sungmin; Kim, Yeongsik; Ahn, Hyungju
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep36326

Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates
journal, December 2000


Enhanced Order of Block Copolymer Cylinders in Single-Layer Films Using a Sweeping Solidification Front
journal, September 2007

  • Angelescu, D. E.; Waller, J. H.; Adamson, D. H.
  • Advanced Materials, Vol. 19, Issue 18, p. 2687-2690
  • DOI: 10.1002/adma.200602904

Experimental observation of Weyl points
journal, July 2015


Highly oriented and ordered microstructures in block copolymer films: Highly Oriented and Ordered Microstructures in Block Copolymer Films
journal, September 2018

  • Zhao, Wei; Zhang, Yi; Wang, Xiao
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 56, Issue 20
  • DOI: 10.1002/polb.24720

Epitaxial self-assembly of block copolymers on lithographically defined nanopatterned substrates
journal, July 2003

  • Ouk Kim, Sang; Solak, Harun H.; Stoykovich, Mark P.
  • Nature, Vol. 424, Issue 6947, p. 411-414
  • DOI: 10.1038/nature01775

Polarity-Switching Top Coats Enable Orientation of Sub-10-nm Block Copolymer Domains
journal, November 2012


Identification of the “Voided Double-Gyroid-Channel”:  A New Morphology in Block Copolymers
journal, February 2007

  • Hashimoto, Takeji; Nishikawa, Yukihiro; Tsutsumi, Kiyoharu
  • Macromolecules, Vol. 40, Issue 4
  • DOI: 10.1021/ma061739h

Highly ordered microstructures of poly(styrene-b-isoprene) block copolymers induced by solution meniscus
journal, October 2005


Macro-lattice from Segregated Amorphous Phases of a Three Block Copolymer
journal, February 1970

  • Keller, A.; Pedemonte, E.; Willmouth, F. M.
  • Nature, Vol. 225, Issue 5232
  • DOI: 10.1038/225538a0

Ordered Mesoporous Ceramics Stable up to 1500 °C from Diblock Copolymer Mesophases
journal, November 2004

  • Kamperman, Marleen; Garcia, Carlos B. W.; Du, Phong
  • Journal of the American Chemical Society, Vol. 126, Issue 45
  • DOI: 10.1021/ja046795h

Shear Orientation and Rheology of a Lamellar Polystyrene-Polyisoprene Block Copolymer
journal, June 1995

  • Patel, S. S.; Larson, R. G.; Winey, K. I.
  • Macromolecules, Vol. 28, Issue 12
  • DOI: 10.1021/ma00116a038

The Gyroid: A New Equilibrium Morphology in Weakly Segregated Diblock Copolymers
journal, July 1994

  • Hajduk, Damian A.; Harper, Paul E.; Gruner, Sol M.
  • Macromolecules, Vol. 27, Issue 15
  • DOI: 10.1021/ma00093a006

Local Control of Microdomain Orientation in Diblock Copolymer Thin Films with Electric Fields
journal, August 1996


Structural Evolution of Colloidal Crystal Films in the Process of Melting Revealed by Bragg Peak Analysis
journal, January 2015

  • Sulyanova, Elena A.; Shabalin, Anatoly; Zozulya, Alexey V.
  • Langmuir, Vol. 31, Issue 19
  • DOI: 10.1021/la504652z

Gyroid Structures in Solvent Annealed PS- b -PMMA Films: Controlled Orientation by Substrate Interactions
journal, June 2017


Alignment of Self-Assembled Structures in Block Copolymer Films by Solvent Vapor Permeation
journal, April 2010


Nanostructured Calcite Single Crystals with Gyroid Morphologies
journal, October 2009

  • Finnemore, Alexander S.; Scherer, Maik R. J.; Langford, Richard
  • Advanced Materials, Vol. 21, Issue 38–39
  • DOI: 10.1002/adma.200900615

Ordered Network Mesostructures in Block Polymer Materials
journal, October 2009

  • Meuler, Adam J.; Hillmyer, Marc A.; Bates, Frank S.
  • Macromolecules, Vol. 42, Issue 19
  • DOI: 10.1021/ma9009593

Long-Range Ordered Thin Films of Block Copolymers Prepared by Zone-Casting and Their Thermal Conversion into Ordered Nanostructured Carbon
journal, May 2005

  • Tang, Chuanbing; Tracz, Adam; Kruk, Michal
  • Journal of the American Chemical Society, Vol. 127, Issue 19, p. 6918-6919
  • DOI: 10.1021/ja0508929

Long-Range Ordering of Diblock Copolymers Induced by Droplet Pinning
journal, November 2003

  • Kimura, Masahiro; Misner, Matthew J.; Xu, Ting
  • Langmuir, Vol. 19, Issue 23, p. 9910-9913
  • DOI: 10.1021/la0351360

Oriented double gyroid films via roll casting
journal, July 2000


Labyrinth-Induced Faceted Electrochemical Growth
journal, February 2014

  • Scherer, Maik R. J.; Cunha, Pedro M. S.; Steiner, Ullrich
  • Advanced Materials, Vol. 26, Issue 15
  • DOI: 10.1002/adma.201305074

Controlled Ordering of Block Copolymer Gyroid Thin Films by Solvent Annealing
journal, December 2013

  • She, Ming-Shiuan; Lo, Ting-Ya; Ho, Rong-Ming
  • Macromolecules, Vol. 47, Issue 1
  • DOI: 10.1021/ma402187j

Optical Imaging of Large Gyroid Grains in Block Copolymer Templates by Confined Crystallization
journal, August 2017


Block Copolymers—Designer Soft Materials
journal, February 1999

  • Bates, Frank S.; Fredrickson, Glenn H.
  • Physics Today, Vol. 52, Issue 2
  • DOI: 10.1063/1.882522

Ordered Network Phases in Linear Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers
journal, November 2004

  • Epps, Thomas H.; Cochran, Eric W.; Bailey, Travis S.
  • Macromolecules, Vol. 37, Issue 22
  • DOI: 10.1021/ma048762s

The Plumber's Nightmare: 1 A New Morphology in Block Copolymer−Ceramic Nanocomposites and Mesoporous Aluminosilicates
journal, October 2003

  • Finnefrock, Adam C.; Ulrich, Ralph; Toombes, Gilman E. S.
  • Journal of the American Chemical Society, Vol. 125, Issue 43
  • DOI: 10.1021/ja0355170