A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand

doi:10.1021/acs.cgd.9b00544

This content will become publicly available on August 21, 2020

Title: A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand

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Abstract

We report a unique uranium-based metal organic framework afforded from the spontaneous reaction of 1,4-(diamidoximyl)benzene (1,4-(DAO)Bz) with uranyl chloride. The structure is the first reported example to show either hydrolysis alongside amidoxime coordination or the presence of multiple amidoxime protonation states in a single complex. The ability of the ligand to adopt three chemically distinct forms affords it enough flexibility to link the typically planar uranyl nodes in three orthogonal directions, giving rise to a cationic framework with large channels and suggesting applications for this system in crystal engineering.

Authors:

^[1]; Patil, Yogesh ^[1];

^[2];

^[3]

Univ. of Alabama, Tuscaloosa, AL (United States)
Univ. of Missouri, Columbia, MO (United States)
Univ. of Alabama, Tuscaloosa, AL (United States); 525 Solutions, Inc., Tuscaloosa, AL (United States)

Publication Date:: 2019-08-21

Research Org.:: Univ. of Alabama, Tuscaloosa, AL (United States)

Sponsoring Org.:: USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5)

OSTI Identifier:: 1558201

Alternate Identifier(s):: OSTI ID: 1592763; OSTI ID: 1592764

Report Number(s):: DOE-UA-08427
Journal ID: ISSN 1528-7483

Grant/Contract Number:: NE0008427

Resource Type:: Accepted Manuscript

Journal Name:: Crystal Growth and Design

Additional Journal Information:: Journal Volume: 19; Journal Issue: 10; Related Information: CCDC No. 1862662 (crystal structure data); Journal ID: ISSN 1528-7483

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; Metal Organic Framework; 1,4-(diamidoximyl)benzene; Metal Organic Framework, 1,4-(diamidoximyl)benzene

Citation Formats


                    Mishra, Manish Kumar, Patil, Yogesh, Kelley, Steven P., and Rogers, Robin D. A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand.  United States: N. p., 2019. 
        Web.  doi:10.1021/acs.cgd.9b00544.

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                    Mishra, Manish Kumar, Patil, Yogesh, Kelley, Steven P., & Rogers, Robin D. A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand.  United States.  doi:10.1021/acs.cgd.9b00544.

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                    Mishra, Manish Kumar, Patil, Yogesh, Kelley, Steven P., and Rogers, Robin D. Wed .  
        "A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand".  United States.  doi:10.1021/acs.cgd.9b00544.

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@article{osti_1558201,

  title        = {A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand},

  author       = {Mishra, Manish Kumar and Patil, Yogesh and Kelley, Steven P. and Rogers, Robin D.},

  abstractNote = {We report a unique uranium-based metal organic framework afforded from the spontaneous reaction of 1,4-(diamidoximyl)benzene (1,4-(DAO)Bz) with uranyl chloride. The structure is the first reported example to show either hydrolysis alongside amidoxime coordination or the presence of multiple amidoxime protonation states in a single complex. The ability of the ligand to adopt three chemically distinct forms affords it enough flexibility to link the typically planar uranyl nodes in three orthogonal directions, giving rise to a cationic framework with large channels and suggesting applications for this system in crystal engineering.},

  doi          = {10.1021/acs.cgd.9b00544},

  journal      = {Crystal Growth and Design},

  number       = 10,

  volume       = 19,

  place        = {United States},

  year         = {2019},

  month        = {8}

}

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DOI: 10.1021/acs.cgd.9b00544

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A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(Diamidoximyl)benzene Ligand

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We report a unique uranium-based metal organic framework afforded from the spontaneous reaction of 1,4-(diamidoximyl)benzene (1,4-(DAO)Bz) with uranyl chloride. The structure is the first reported example to show either hydrolysis alongside amidoxime coordination or the presence of multiple amidoxime protonation states in a single complex. The ability of the ligand to adopt three chemically distinct forms affords it enough flexibility to link the typically planar uranyl nodes in three orthogonal directions, giving rise to a cationic framework with large channels and suggesting applications for this system in crystal engineering.
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A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(Diamidoximyl)benzene Ligand

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