A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand

Mishra, Manish Kumar; Patil, Yogesh; Kelley, Steven P.; Rogers, Robin D.

doi:10.1021/acs.cgd.9b00544

Title: A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand

Abstract

We report a unique uranium-based metal organic framework afforded from the spontaneous reaction of 1,4-(diamidoximyl)benzene (1,4-(DAO)Bz) with uranyl chloride. The structure is the first reported example to show either hydrolysis alongside amidoxime coordination or the presence of multiple amidoxime protonation states in a single complex. The ability of the ligand to adopt three chemically distinct forms affords it enough flexibility to link the typically planar uranyl nodes in three orthogonal directions, giving rise to a cationic framework with large channels and suggesting applications for this system in crystal engineering.

Authors:

^[1]; Patil, Yogesh ^[1];

^[2];

^[3]

Univ. of Alabama, Tuscaloosa, AL (United States)
Univ. of Missouri, Columbia, MO (United States)
Univ. of Alabama, Tuscaloosa, AL (United States); 525 Solutions, Inc., Tuscaloosa, AL (United States)

Publication Date:: 2019-08-21

Research Org.:: Univ. of Alabama, Tuscaloosa, AL (United States)

Sponsoring Org.:: USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5)

OSTI Identifier:: 1558201

Alternate Identifier(s):: OSTI ID: 1592763; OSTI ID: 1592764

Report Number(s):: DOE-UA-08427
Journal ID: ISSN 1528-7483

Grant/Contract Number:: NE0008427

Resource Type:: Accepted Manuscript

Journal Name:: Crystal Growth and Design

Additional Journal Information:: Journal Volume: 19; Journal Issue: 10; Related Information: CCDC No. 1862662 (crystal structure data); Journal ID: ISSN 1528-7483

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; Metal Organic Framework; 1,4-(diamidoximyl)benzene; Metal Organic Framework, 1,4-(diamidoximyl)benzene

Citation Formats


                    Mishra, Manish Kumar, Patil, Yogesh, Kelley, Steven P., and Rogers, Robin D. A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand.  United States: N. p., 2019. 
Web.  doi:10.1021/acs.cgd.9b00544.

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                    Mishra, Manish Kumar, Patil, Yogesh, Kelley, Steven P., & Rogers, Robin D. A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand.  United States.  https://doi.org/10.1021/acs.cgd.9b00544

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                    Mishra, Manish Kumar, Patil, Yogesh, Kelley, Steven P., and Rogers, Robin D. Wed .  
"A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand".  United States.  https://doi.org/10.1021/acs.cgd.9b00544.  https://www.osti.gov/servlets/purl/1558201.

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@article{osti_1558201,

  title        = {A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand},

  author       = {Mishra, Manish Kumar and Patil, Yogesh and Kelley, Steven P. and Rogers, Robin D.},

  abstractNote = {We report a unique uranium-based metal organic framework afforded from the spontaneous reaction of 1,4-(diamidoximyl)benzene (1,4-(DAO)Bz) with uranyl chloride. The structure is the first reported example to show either hydrolysis alongside amidoxime coordination or the presence of multiple amidoxime protonation states in a single complex. The ability of the ligand to adopt three chemically distinct forms affords it enough flexibility to link the typically planar uranyl nodes in three orthogonal directions, giving rise to a cationic framework with large channels and suggesting applications for this system in crystal engineering.},

  doi          = {10.1021/acs.cgd.9b00544},

  journal      = {Crystal Growth and Design},

  number       = 10,

  volume       = 19,

  place        = {United States},

  year         = {2019},

  month        = {8}

}

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Works referenced in this record:

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Title: A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(diamidoximyl)benzene Ligand

Abstract

Citation Formats

Chemical Forms of Uranium in Artificial Seawater journal, February 1982

Development of Sorbers for the Recovery of Uranium from Seawater. 1. Assessment of Key Parameters and Screening Studies of Sorber Materials journal, August 1982

Development of Sorbers for the Recovery of Uranium from Seawater. Part 2. The Accumulation of Uranium from Seawater by Resins Containing Amidoxime and Imidoxime Functional Groups journal, April 1983

Coordination chemistry and metal-involving reactions of amidoximes: Relevance to the chemistry of oximes and oxime ligands journal, April 2016

Materials for the Recovery of Uranium from Seawater journal, June 2017

Cyclic Imide Dioximes: Formation and Hydrolytic Stability journal, May 2012

An overview and recent progress in the chemistry of uranium extraction from seawater journal, January 2018

Uranyl complexes of acetamidoxime and benzamidoxime. Preparation, characterization, and crystal structure journal, June 1984

Highly selective extraction of the uranyl ion with hydrophobic amidoxime-functionalized ionic liquids via η2 coordination journal, January 2012

How Amidoximate Binds the Uranyl Cation journal, February 2012

Sequestering uranium from seawater: binding strength and modes of uranyl complexes with glutarimidedioxime journal, January 2012

Structural clues to UO 2 2+ /VO 2 + competition in seawater extraction using amidoxime-based extractants journal, January 2014

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The Crystal Structure of [(UO2)4Cl2O2(OH)2(H2O)6].4H2O, a Compound Containing a Tetranuclear Aquachlorohydroxooxo Complex of Uranyl(VI). journal, January 1976

An uranyl citrate coordination polymer with a 3D open-framework involving uranyl cation-cation interactions journal, January 2011

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Chemical Forms of Uranium in Artificial Seawater
journal, February 1982

Development of Sorbers for the Recovery of Uranium from Seawater. 1. Assessment of Key Parameters and Screening Studies of Sorber Materials
journal, August 1982

Development of Sorbers for the Recovery of Uranium from Seawater. Part 2. The Accumulation of Uranium from Seawater by Resins Containing Amidoxime and Imidoxime Functional Groups
journal, April 1983

Coordination chemistry and metal-involving reactions of amidoximes: Relevance to the chemistry of oximes and oxime ligands
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Materials for the Recovery of Uranium from Seawater
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Cyclic Imide Dioximes: Formation and Hydrolytic Stability
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An overview and recent progress in the chemistry of uranium extraction from seawater
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Uranyl complexes of acetamidoxime and benzamidoxime. Preparation, characterization, and crystal structure
journal, June 1984

Highly selective extraction of the uranyl ion with hydrophobic amidoxime-functionalized ionic liquids via η2 coordination
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How Amidoximate Binds the Uranyl Cation
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Sequestering uranium from seawater: binding strength and modes of uranyl complexes with glutarimidedioxime
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Structural clues to UO ₂ ²⁺ /VO ₂ ⁺ competition in seawater extraction using amidoxime-based extractants
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Hydrogen bond patterns in aromatic and aliphatic dioximes
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