Photoelectrochemical water splitting using strain-balanced multiple quantum well photovoltaic cells
Abstract
Starting from the classical GaInP/GaAs tandem photoelectrochemical water splitting device, higher solar-to-hydrogen efficiencies can be pursued by extending photon absorption to longer wavelengths. We incorporate strain-balanced GaInAs/GaAsP quantum wells into the bottom GaAs junction, to increase the range of photon absorption. The inclusion of 1.34 eV quantum wells in the depletion region of the bottom cell extends the absorption edge to 930 nm. With a corresponding increase in the thickness of the top cell for current matching, the light-limiting photocurrent increases by >8%. The estimated solar-to-hydrogen efficiency is 13.6 ± 0.5%, and we show a pathway to further improvement. With the semiconductor device remaining on the growth substrate, this quantum well architecture may enable improved stability and durability of the photoelectrochemical electrodes.
- Authors:
-
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Univ. of New South Wales, Sydney, NSW (Australia)
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office
- OSTI Identifier:
- 1559779
- Alternate Identifier(s):
- OSTI ID: 1557905
- Report Number(s):
- NREL/JA-5900-73750
Journal ID: ISSN 2398-4902; SEFUA7
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Sustainable Energy & Fuels
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 10; Journal ID: ISSN 2398-4902
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; photoelectrochemical water splitting; III-V; quantum well; photovoltaic cells
Citation Formats
Steiner, Myles A., Barraugh, Collin, Aldridge, Chase, Barraza, Isabel, Friedman, Daniel J., Ekins-Daukes, Nicholas J., Deutsch, Todd G., and Young, James. Photoelectrochemical water splitting using strain-balanced multiple quantum well photovoltaic cells. United States: N. p., 2019.
Web. doi:10.1039/C9SE00276F.
Steiner, Myles A., Barraugh, Collin, Aldridge, Chase, Barraza, Isabel, Friedman, Daniel J., Ekins-Daukes, Nicholas J., Deutsch, Todd G., & Young, James. Photoelectrochemical water splitting using strain-balanced multiple quantum well photovoltaic cells. United States. https://doi.org/10.1039/C9SE00276F
Steiner, Myles A., Barraugh, Collin, Aldridge, Chase, Barraza, Isabel, Friedman, Daniel J., Ekins-Daukes, Nicholas J., Deutsch, Todd G., and Young, James. Wed .
"Photoelectrochemical water splitting using strain-balanced multiple quantum well photovoltaic cells". United States. https://doi.org/10.1039/C9SE00276F. https://www.osti.gov/servlets/purl/1559779.
@article{osti_1559779,
title = {Photoelectrochemical water splitting using strain-balanced multiple quantum well photovoltaic cells},
author = {Steiner, Myles A. and Barraugh, Collin and Aldridge, Chase and Barraza, Isabel and Friedman, Daniel J. and Ekins-Daukes, Nicholas J. and Deutsch, Todd G. and Young, James},
abstractNote = {Starting from the classical GaInP/GaAs tandem photoelectrochemical water splitting device, higher solar-to-hydrogen efficiencies can be pursued by extending photon absorption to longer wavelengths. We incorporate strain-balanced GaInAs/GaAsP quantum wells into the bottom GaAs junction, to increase the range of photon absorption. The inclusion of 1.34 eV quantum wells in the depletion region of the bottom cell extends the absorption edge to 930 nm. With a corresponding increase in the thickness of the top cell for current matching, the light-limiting photocurrent increases by >8%. The estimated solar-to-hydrogen efficiency is 13.6 ± 0.5%, and we show a pathway to further improvement. With the semiconductor device remaining on the growth substrate, this quantum well architecture may enable improved stability and durability of the photoelectrochemical electrodes.},
doi = {10.1039/C9SE00276F},
journal = {Sustainable Energy & Fuels},
number = 10,
volume = 3,
place = {United States},
year = {Wed Jul 31 00:00:00 EDT 2019},
month = {Wed Jul 31 00:00:00 EDT 2019}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Molybdenum Disulfide as a Protection Layer and Catalyst for Gallium Indium Phosphide Solar Water Splitting Photocathodes
journal, May 2016
- Britto, Reuben J.; Benck, Jesse D.; Young, James L.
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 11
A quantum-well superlattice solar cell for enhanced current output and minimized drop in open-circuit voltage under sunlight concentration
journal, December 2012
- Sugiyama, Masakazu; Wang, Yunpeng; Fujii, Hiromasa
- Journal of Physics D: Applied Physics, Vol. 46, Issue 2
Minority Carrier Transport and Their Lifetime in InGaAs/GaAsP Multiple Quantum Well Structures
journal, August 2013
- Carlin, Conrad Zachary; Bradshaw, Geoffrey Keith; Samberg, Joshua Paul
- IEEE Transactions on Electron Devices, Vol. 60, Issue 8
Strain-balanced GaAsP/InGaAs quantum well solar cells
journal, December 1999
- Ekins-Daukes, N. J.; Barnham, K. W. J.; Connolly, J. P.
- Applied Physics Letters, Vol. 75, Issue 26
Design and comparison of GaAs, GaAsP and InGaAlAs quantum-well active regions for 808-nm VCSELs
journal, January 2011
- Zhang, Yan; Ning, Yongqiang; Zhang, Lisen
- Optics Express, Vol. 19, Issue 13
100-period InGaAsP/InGaP superlattice solar cell with sub-bandgap quantum efficiency approaching 80%
journal, August 2017
- Sayed, Islam E. H.; Jain, Nikhil; Steiner, Myles A.
- Applied Physics Letters, Vol. 111, Issue 8
Optimizing "Artificial Leaf" Photoanode-Photocathode-Catalyst Interface Systems for Solar Water Splitting
journal, August 2016
- Porter, S. H.; Hwang, S.; Amarasinghe, V.
- ECS Transactions, Vol. 72, Issue 37
Investigations on Al$_{\bm x}$Ga$_{\bm {1-x}}$As Solar Cells Grown by MOVPE
journal, January 2015
- Heckelmann, Stefan; Lackner, David; Karcher, Christian
- IEEE Journal of Photovoltaics, Vol. 5, Issue 1
A Monolithic Photovoltaic-Photoelectrochemical Device for Hydrogen Production via Water Splitting
journal, April 1998
- Khaselev, O.
- Science, Vol. 280, Issue 5362
Direct solar-to-hydrogen conversion via inverted metamorphic multi-junction semiconductor architectures
journal, March 2017
- Young, James L.; Steiner, Myles A.; Döscher, Henning
- Nature Energy, Vol. 2, Issue 4
Recent results for single-junction and tandem quantum well solar cells
journal, January 2011
- Adams, J. G. J.; Browne, B. C.; Ballard, I. M.
- Progress in Photovoltaics: Research and Applications, Vol. 19, Issue 7
Strain-Balanced Criteria for Multiple Quantum Well Structures and Its Signature in X-ray Rocking Curves †
journal, July 2002
- Ekins-Daukes, N. J.; Kawaguchi, K.; Zhang, J.
- Crystal Growth & Design, Vol. 2, Issue 4
Enhanced Current Collection in 1.7 eV GaInAsP Solar Cells Grown on GaAs by Metalorganic Vapor Phase Epitaxy
journal, May 2017
- Jain, Nikhil; Geisz, John F.; France, Ryan M.
- IEEE Journal of Photovoltaics, Vol. 7, Issue 3
Short-circuit current enhancement in Bragg stack multi-quantum-well solar cells for multi-junction space cell applications
journal, January 2003
- Bushnell, D.; Ekinsdaukes, N.; Barnham, K.
- Solar Energy Materials and Solar Cells, Vol. 75, Issue 1-2
Quantum Well Solar Cells: Principles, Recent Progress, and Potential
journal, March 2019
- Sayed, Islam; Bedair, S. M.
- IEEE Journal of Photovoltaics, Vol. 9, Issue 2
Sunlight absorption in water – efficiency and design implications for photoelectrochemical devices
journal, January 2014
- Döscher, H.; Geisz, J. F.; Deutsch, T. G.
- Energy Environ. Sci., Vol. 7, Issue 9
Investigation of Carrier Recombination Dynamics of InGaP/InGaAsP Multiple Quantum Wells for Solar Cells via Photoluminescence
journal, May 2017
- Lee, Kan-Hua; Barnham, Keith W. J.; Roberts, John S.
- IEEE Journal of Photovoltaics, Vol. 7, Issue 3
High-efficiency inverted metamorphic 1.7/1.1 eV GaInAsP/GaInAs dual-junction solar cells
journal, January 2018
- Jain, Nikhil; Schulte, Kevin L.; Geisz, John F.
- Applied Physics Letters, Vol. 112, Issue 5
Demonstration of Photon Coupling in Dual Multiple-Quantum-Well Solar Cells
journal, January 2012
- Lee, Kan-Hua; Barnham, Keith W. J.; Connolly, James P.
- IEEE Journal of Photovoltaics, Vol. 2, Issue 1
Steady-state carrier escape from single quantum wells
journal, June 1993
- Nelson, J.; Paxman, M.; Barnham, K. W. J.
- IEEE Journal of Quantum Electronics, Vol. 29, Issue 6
GaInP/GaAs Tandem Solar Cells With InGaAs/GaAsP Multiple Quantum Wells
journal, March 2014
- Bradshaw, Geoffrey K.; Samberg, Joshua P.; Carlin, C. Zachary
- IEEE Journal of Photovoltaics, Vol. 4, Issue 2
Efficient direct solar-to-hydrogen conversion by in situ interface transformation of a tandem structure
journal, September 2015
- May, Matthias M.; Lewerenz, Hans-Joachim; Lackner, David
- Nature Communications, Vol. 6, Issue 1
Figures / Tables found in this record: