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Title: Improved retrievals of carbon dioxide from Orbiting Carbon Observatory-2 with the version 8 ACOS algorithm

Abstract

Since September 2014, NASA's Orbiting Carbon Observatory-2 (OCO-2) satellite has been taking measurements of reflected solar spectra and using them to infer atmospheric carbon dioxide levels. This work provides details of the OCO-2 retrieval algorithm, versions 7 and 8, used to derive the column-averaged dry air mole fraction of atmospheric CO2( X CO 2 ) for the roughly 100000 cloud-free measurements recorded by OCO-2 each day. The algorithm is based on the Atmospheric Carbon Observations from Space (ACOS) algorithm which has been applied to observations from the Greenhouse Gases Observing SATellite (GOSAT) since 2009, with modifications necessary for OCO-2. Because high accuracy,better than 0.25%, is required in order to accurately infer carbon sources and sinks from X CO 2 , significant errors and regional-scale biases in the measurements must be minimized. We discuss efforts to filter out poor-quality measurements, and correct the remaining good-quality measurements to minimize regional-scale biases. Updates to the radiance calibration and retrieval forward model in version 8 have improved many aspects of the retrieved data products. The version 8 data appear to have reduced regional-scale biases overall, and demonstrate a clear improvement over the version 7 data. In particular, error variance with respect to TCCON was reduced by 20% over land and 40% over ocean between versions 7 and 8, and nadir and glint observations over land are now more consistent. While this paper documents the significant improvements in the ACOS algorithm, it will continue to evolve and improve as the CO2 data record continues to expand.

Authors:
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  1. Colorado State Univ., Fort Collins, CO (United States)
  2. California Inst. of Technology (CalTech), Pasadena, CA (United States)
  3. Finnish Meteorological Inst., Helsinki (Finland)
  4. Univ. of Wisconsin, Madison, WI (United States)
  5. Univ. of Toronto, ON (Canada)
  6. NOAA Earth System Research Laboratory, Boulder, CO (United States); Univ. of Colorado, Boulder, CO (United States)
  7. CEA-CNRS-UVSQ, Gif-sur-Yvette (France)
  8. Univ. of Oklahoma, Norman, OK (United States)
  9. Univ. of Edinburgh, Scotland (United Kingdom)
  10. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  11. Meteorological State Agency of Spain (AEMet), Santa Cruz de Tenerife (Spain)
  12. Univ. of Wollongong, NSW (Australia)
  13. Karlsruhe Inst. of Technology (Germany)
  14. NASA Ames Research Center, Moffett Field, CA (United States)
  15. Finnish Meteorological Institute, Sodankylä (Finland)
  16. National Inst. for Environmental Studies (NIES), Tsukuba (Japan)
  17. Univ. of Bremen (Germany)
  18. Royal Belgian Institute for Space Aeronomy, Brussels (Belgium)
  19. Sorbonne Université, Observatoire de Paris, Université PSL, CNRS, Paris (France)
Publication Date:
Research Org.:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Office of Science (SC). Biological and Environmental Research (BER) (SC-23)
OSTI Identifier:
1557767
Report Number(s):
LA-UR-19-22771
Journal ID: ISSN 1867-8548
Grant/Contract Number:  
89233218CNA000001
Resource Type:
Accepted Manuscript
Journal Name:
Atmospheric Measurement Techniques (Online)
Additional Journal Information:
Journal Name: Atmospheric Measurement Techniques (Online); Journal Volume: 11; Journal Issue: 12; Journal ID: ISSN 1867-8548
Publisher:
European Geosciences Union
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; 58 GEOSCIENCES; Earth Sciences; Energy Sciences; Satellite; OCO-2; TCCON; CO2 validation; Carbon Cycle; Climate; Remote Sensing; Amazon

Citation Formats

O'Dell, Christopher W., Eldering, Annmarie, Wennberg, Paul O., Crisp, David, Gunson, Michael R., Fisher, Brendan, Frankenberg, Christian, Kiel, Matthäus, Lindqvist, Hannakaisa, Mandrake, Lukas, Merrelli, Aronne, Natraj, Vijay, Nelson, Robert R., Osterman, Gregory B., Payne, Vivienne H., Taylor, Thomas E., Wunch, Debra, Drouin, Brian J., Oyafuso, Fabiano, Chang, Albert, McDuffie, James, Smyth, Michael, Baker, David F., Basu, Sourish, Chevallier, Frédéric, Crowell, Sean M. R., Feng, Liang, Palmer, Paul I., Dubey, Mavendra Krishna, García, Omaira E., Griffith, David W. T., Hase, Frank, Iraci, Laura T., Kivi, Rigel, Morino, Isamu, Notholt, Justus, Ohyama, Hirofumi, Petri, Christof, Roehl, Coleen M., Sha, Mahesh K., Strong, Kimberly, Sussmann, Ralf, Te, Yao, Uchino, Osamu, and Velazco, Voltaire A. Improved retrievals of carbon dioxide from Orbiting Carbon Observatory-2 with the version 8 ACOS algorithm. United States: N. p., 2018. Web. doi:10.5194/amt-11-6539-2018.
O'Dell, Christopher W., Eldering, Annmarie, Wennberg, Paul O., Crisp, David, Gunson, Michael R., Fisher, Brendan, Frankenberg, Christian, Kiel, Matthäus, Lindqvist, Hannakaisa, Mandrake, Lukas, Merrelli, Aronne, Natraj, Vijay, Nelson, Robert R., Osterman, Gregory B., Payne, Vivienne H., Taylor, Thomas E., Wunch, Debra, Drouin, Brian J., Oyafuso, Fabiano, Chang, Albert, McDuffie, James, Smyth, Michael, Baker, David F., Basu, Sourish, Chevallier, Frédéric, Crowell, Sean M. R., Feng, Liang, Palmer, Paul I., Dubey, Mavendra Krishna, García, Omaira E., Griffith, David W. T., Hase, Frank, Iraci, Laura T., Kivi, Rigel, Morino, Isamu, Notholt, Justus, Ohyama, Hirofumi, Petri, Christof, Roehl, Coleen M., Sha, Mahesh K., Strong, Kimberly, Sussmann, Ralf, Te, Yao, Uchino, Osamu, & Velazco, Voltaire A. Improved retrievals of carbon dioxide from Orbiting Carbon Observatory-2 with the version 8 ACOS algorithm. United States. https://doi.org/10.5194/amt-11-6539-2018
O'Dell, Christopher W., Eldering, Annmarie, Wennberg, Paul O., Crisp, David, Gunson, Michael R., Fisher, Brendan, Frankenberg, Christian, Kiel, Matthäus, Lindqvist, Hannakaisa, Mandrake, Lukas, Merrelli, Aronne, Natraj, Vijay, Nelson, Robert R., Osterman, Gregory B., Payne, Vivienne H., Taylor, Thomas E., Wunch, Debra, Drouin, Brian J., Oyafuso, Fabiano, Chang, Albert, McDuffie, James, Smyth, Michael, Baker, David F., Basu, Sourish, Chevallier, Frédéric, Crowell, Sean M. R., Feng, Liang, Palmer, Paul I., Dubey, Mavendra Krishna, García, Omaira E., Griffith, David W. T., Hase, Frank, Iraci, Laura T., Kivi, Rigel, Morino, Isamu, Notholt, Justus, Ohyama, Hirofumi, Petri, Christof, Roehl, Coleen M., Sha, Mahesh K., Strong, Kimberly, Sussmann, Ralf, Te, Yao, Uchino, Osamu, and Velazco, Voltaire A. Tue . "Improved retrievals of carbon dioxide from Orbiting Carbon Observatory-2 with the version 8 ACOS algorithm". United States. https://doi.org/10.5194/amt-11-6539-2018. https://www.osti.gov/servlets/purl/1557767.
@article{osti_1557767,
title = {Improved retrievals of carbon dioxide from Orbiting Carbon Observatory-2 with the version 8 ACOS algorithm},
author = {O'Dell, Christopher W. and Eldering, Annmarie and Wennberg, Paul O. and Crisp, David and Gunson, Michael R. and Fisher, Brendan and Frankenberg, Christian and Kiel, Matthäus and Lindqvist, Hannakaisa and Mandrake, Lukas and Merrelli, Aronne and Natraj, Vijay and Nelson, Robert R. and Osterman, Gregory B. and Payne, Vivienne H. and Taylor, Thomas E. and Wunch, Debra and Drouin, Brian J. and Oyafuso, Fabiano and Chang, Albert and McDuffie, James and Smyth, Michael and Baker, David F. and Basu, Sourish and Chevallier, Frédéric and Crowell, Sean M. R. and Feng, Liang and Palmer, Paul I. and Dubey, Mavendra Krishna and García, Omaira E. and Griffith, David W. T. and Hase, Frank and Iraci, Laura T. and Kivi, Rigel and Morino, Isamu and Notholt, Justus and Ohyama, Hirofumi and Petri, Christof and Roehl, Coleen M. and Sha, Mahesh K. and Strong, Kimberly and Sussmann, Ralf and Te, Yao and Uchino, Osamu and Velazco, Voltaire A.},
abstractNote = {Since September 2014, NASA's Orbiting Carbon Observatory-2 (OCO-2) satellite has been taking measurements of reflected solar spectra and using them to infer atmospheric carbon dioxide levels. This work provides details of the OCO-2 retrieval algorithm, versions 7 and 8, used to derive the column-averaged dry air mole fraction of atmospheric CO2(XCO2) for the roughly 100000 cloud-free measurements recorded by OCO-2 each day. The algorithm is based on the Atmospheric Carbon Observations from Space (ACOS) algorithm which has been applied to observations from the Greenhouse Gases Observing SATellite (GOSAT) since 2009, with modifications necessary for OCO-2. Because high accuracy,better than 0.25%, is required in order to accurately infer carbon sources and sinks from XCO2, significant errors and regional-scale biases in the measurements must be minimized. We discuss efforts to filter out poor-quality measurements, and correct the remaining good-quality measurements to minimize regional-scale biases. Updates to the radiance calibration and retrieval forward model in version 8 have improved many aspects of the retrieved data products. The version 8 data appear to have reduced regional-scale biases overall, and demonstrate a clear improvement over the version 7 data. In particular, error variance with respect to TCCON was reduced by 20% over land and 40% over ocean between versions 7 and 8, and nadir and glint observations over land are now more consistent. While this paper documents the significant improvements in the ACOS algorithm, it will continue to evolve and improve as the CO2 data record continues to expand.},
doi = {10.5194/amt-11-6539-2018},
journal = {Atmospheric Measurement Techniques (Online)},
number = 12,
volume = 11,
place = {United States},
year = {Tue Dec 11 00:00:00 EST 2018},
month = {Tue Dec 11 00:00:00 EST 2018}
}

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  • Kulawik, Susan; Wunch, Debra; O'Dell, Christopher
  • Atmospheric Measurement Techniques, Vol. 9, Issue 2
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Influence of El Niño on atmospheric CO 2 over the tropical Pacific Ocean: Findings from NASA’s OCO-2 mission
journal, October 2017


Precision requirements for space-based data: REQUIREMENTS FOR SPACE-BASED
journal, May 2007

  • Miller, C. E.; Crisp, D.; DeCola, P. L.
  • Journal of Geophysical Research: Atmospheres, Vol. 112, Issue D10
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TCCON data from Lamont (US), Release GGG2014.R1
dataset, January 2016


Observational evidence of 3-D cloud effects in OCO-2 CO 2 retrievals: Evidence of 3-D Cloud Effects
journal, July 2017

  • Massie, Steven T.; Sebastian Schmidt, K.; Eldering, Annmarie
  • Journal of Geophysical Research: Atmospheres, Vol. 122, Issue 13
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Tropospheric Aerosol Optical Thickness from the GOCART Model and Comparisons with Satellite and Sun Photometer Measurements
journal, February 2002


Impact of aerosol and thin cirrus on retrieving and validating XCO 2 from GOSAT shortwave infrared measurements : CIRRUS AND AEROSOL ERRORS IN GOSAT XCO
journal, May 2013

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Line mixing and speed dependence in CO2 at 6348cm−1: Positions, intensities, and air- and self-broadening derived with constrained multispectrum analysis
journal, April 2007

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A method for evaluating bias in global measurements of CO 2 total columns from space
journal, January 2011

  • Wunch, D.; Wennberg, P. O.; Toon, G. C.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 23
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Sensitivity of multiangle imaging to natural mixtures of aerosols over ocean
journal, August 2001

  • Kahn, Ralph; Banerjee, Pranab; McDonald, Duncan
  • Journal of Geophysical Research: Atmospheres, Vol. 106, Issue D16
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TCCON data from Park Falls (US), Release GGG2014.R0
dataset, January 2017


TCCON data from Darwin (AU), Release GGG2014.R0
dataset, September 2017


Spaceborne detection of localized carbon dioxide sources
journal, October 2017

  • Schwandner, Florian M.; Gunson, Michael R.; Miller, Charles E.
  • Science, Vol. 358, Issue 6360
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Multispectrum Analysis of the Oxygen A-Band
conference, June 2016

  • Drouin, Brian; Wishnow, Edward; Robichaud, David
  • Proceedings of the 71st International Symposium on Molecular Spectroscopy
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Toward robust and consistent regional CO 2 flux estimates from in situ and spaceborne measurements of atmospheric CO 2 : Chavallier et al.: CO2 flux estimates from GOSAT
journal, February 2014

  • Chevallier, Frédéric; Palmer, Paul I.; Feng, Liang
  • Geophysical Research Letters, Vol. 41, Issue 3
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TCCON data from Izana (ES), Release GGG2014.R0
dataset, September 2017


Online simulations of global aerosol distributions in the NASA GEOS-4 model and comparisons to satellite and ground-based aerosol optical depth
journal, January 2010

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An atmospheric perspective on North American carbon dioxide exchange: CarbonTracker
journal, November 2007

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TCCON data from Edwards (US), Release GGG2014.R1
dataset, January 2016


TCCON data from Tsukuba (JP), 125HR, Release GGG2014.R1
dataset, January 2016


Estimating surface CO 2 fluxes from space-borne CO 2 dry air mole fraction observations using an ensemble Kalman Filter
journal, January 2009

  • Feng, L.; Palmer, P. I.; Bösch, H.
  • Atmospheric Chemistry and Physics, Vol. 9, Issue 8
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The Potential of the Geostationary Carbon Cycle Observatory (GeoCarb) to Provide Multi-scale Constraints on the Carbon Cycle in the Americas
journal, October 2018

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TCCON data from Garmisch (DE), Release GGG2014.R0
dataset, September 2017


Long-range transport of stratospheric aerosols in the Southern Hemisphere following the 2015 Calbuco eruption
journal, January 2017

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  • Atmospheric Chemistry and Physics, Vol. 17, Issue 24
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TCCON data from Bremen (DE), Release GGG2014.R0
dataset, September 2017


A Fast Atmospheric Trace Gas Retrieval for Hyperspectral Instruments Approximating Multiple Scattering—Part 2: Application to XCO2 Retrievals from OCO-2
journal, October 2017

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Calibration of the total carbon column observing network using aircraft profile data
journal, January 2010

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TCCON data from Ascension Island (SH), Release GGG2014.R0
dataset, February 2017


Unified equations for the slope, intercept, and standard errors of the best straight line
journal, March 2004

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The water vapour self-continuum by CRDS at room temperature in the 1.6µm transparency window
journal, November 2013

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The utility of remotely sensed CO 2 concentration data in surface source inversions
journal, January 2001

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On the Ability of Space-Based Passive and Active Remote Sensing Observations of CO 2 to Detect Flux Perturbations to the Carbon Cycle
journal, January 2018

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  • Journal of Geophysical Research: Atmospheres, Vol. 123, Issue 2
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The HITRAN2012 molecular spectroscopic database
journal, November 2013

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The ACOS CO 2 retrieval algorithm – Part 1: Description and validation against synthetic observations
journal, January 2012

  • O'Dell, C. W.; Connor, B.; Bösch, H.
  • Atmospheric Measurement Techniques, Vol. 5, Issue 1
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First Global Carbon Dioxide Maps Produced from TanSat Measurements
journal, April 2018


Global Concentrations of CO2 and CH4 Retrieved from GOSAT: First Preliminary Results
journal, January 2009


Evaluation and attribution of OCO-2 XCO 2 uncertainties
journal, January 2017

  • Worden, John R.; Doran, Gary; Kulawik, Susan
  • Atmospheric Measurement Techniques, Vol. 10, Issue 7
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Measuring atmospheric carbon dioxide from space with the Orbiting Carbon Observatory-2 (OCO-2)
conference, September 2015

  • Crisp, D.
  • SPIE Optical Engineering + Applications, SPIE Proceedings
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TCCON data from Ny Ålesund, Spitsbergen (NO), Release GGG2014.R0
dataset, October 2017


Solar Line List for the TCCON 2014 Data Release
dataset, January 2015


TCCON data from Réunion Island (RE), Release GGG2020.R0
dataset, January 2022


OCO-2 Level 2 bias-corrected XCO2 and other select fields from the full-physics retrieval aggregated as daily files, Retrospective processing V10r
dataset, January 2020

  • Science Data Operations System, Jet Propulsion Laboratory
  • NASA Goddard Earth Sciences Data and Information Services Center
  • DOI: 10.5067/e4e140xdmpo2

Probabilistic global maps of the CO 2 column at daily and monthly scales from sparse satellite measurements
journal, July 2017

  • Chevallier, Frédéric; Broquet, Grégoire; Pierangelo, Clémence
  • Journal of Geophysical Research: Atmospheres, Vol. 122, Issue 14
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Water vapor self-continuum absorption in near-infrared windows derived from laboratory measurements
journal, January 2011

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Retrievals of atmospheric CO_2 from simulated space-borne measurements of backscattered near-infrared sunlight: accounting for aerosol effects
journal, January 2009

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  • Applied Optics, Vol. 48, Issue 18
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Does GOSAT capture the true seasonal cycle of carbon dioxide?
journal, January 2015

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  • Atmospheric Chemistry and Physics, Vol. 15, Issue 22
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Carbon dioxide retrieval from OCO-2 satellite observations using the RemoTeC algorithm and validation with TCCON measurements
journal, January 2018

  • Wu, Lianghai; Hasekamp, Otto; Hu, Haili
  • Atmospheric Measurement Techniques, Vol. 11, Issue 5
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Estimating bias in the OCO-2 retrieval algorithm caused by 3-D radiation scattering from unresolved boundary layer clouds
journal, January 2015

  • Merrelli, A.; Bennartz, R.; O'Dell, C. W.
  • Atmospheric Measurement Techniques, Vol. 8, Issue 4
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Consistent evaluation of ACOS-GOSAT, BESD-SCIAMACHY, CarbonTracker, and MACC through comparisons to TCCON
journal, January 2016

  • Kulawik, Susan; Wunch, Debra; O'Dell, Christopher
  • Atmospheric Measurement Techniques, Vol. 9, Issue 2
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OCO-2 Level 2 bias-corrected XCO2 and other select fields from the full-physics retrieval aggregated as daily files, Retrospective processing V10r
dataset, January 2017

  • Science Computing Facility, Jet Propulsion Laboratory
  • NASA Goddard Earth Sciences Data and Information Services Center
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Works referencing / citing this record:

Accelerated MCMC for Satellite-Based Measurements of Atmospheric CO2
journal, September 2019

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Towards monitoring localized CO 2 emissions from space: co-located regional CO 2 and NO 2 enhancements observed by the OCO-2 and S5P satellites
journal, January 2019

  • Reuter, Maximilian; Buchwitz, Michael; Schneising, Oliver
  • Atmospheric Chemistry and Physics, Vol. 19, Issue 14
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Evaluation of MOPITT Version 7 joint TIR-NIR XCO retrievals with TCCON
text, January 2019


A Geostatistical Framework for Quantifying the Imprint of Mesoscale Atmospheric Transport on Satellite Trace Gas Retrievals
journal, September 2019

  • Torres, Anthony D.; Keppel‐Aleks, Gretchen; Doney, Scott C.
  • Journal of Geophysical Research: Atmospheres, Vol. 124, Issue 17-18
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Objective evaluation of surface- and satellite-driven carbon dioxide atmospheric inversions
journal, January 2019

  • Chevallier, Frédéric; Remaud, Marine; O'Dell, Christopher W.
  • Atmospheric Chemistry and Physics, Vol. 19, Issue 22
  • DOI: 10.5194/acp-19-14233-2019

Full-physics carbon dioxide retrievals from the Orbiting Carbon Observatory-2 (OCO-2) satellite by only using the 2.06 µm band
journal, January 2019

  • Wu, Lianghai; Hasekamp, Otto; Hu, Haili
  • Atmospheric Measurement Techniques, Vol. 12, Issue 11
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How bias correction goes wrong: measurement of X CO 2 affected by erroneous surface pressure estimates
journal, January 2019

  • Kiel, Matthäus; O'Dell, Christopher W.; Fisher, Brendan
  • Atmospheric Measurement Techniques, Vol. 12, Issue 4
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Estimating power plant CO 2 emission using OCO-2 XCO 2 and high resolution WRF-Chem simulations
journal, July 2019

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The 2015–2016 carbon cycle as seen from OCO-2 and the global in situ network
journal, January 2019

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  • Atmospheric Chemistry and Physics, Vol. 19, Issue 15
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Net carbon emissions from African biosphere dominate pan-tropical atmospheric CO2 signal
journal, August 2019


Evaluation of MOPITT Version 7 joint TIR–NIR XCO retrievals with TCCON
journal, January 2019

  • Hedelius, Jacob K.; He, Tai-Long; Jones, Dylan B. A.
  • Atmospheric Measurement Techniques, Vol. 12, Issue 10
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The impact of improved aerosol priors on near-infrared measurements of carbon dioxide
journal, January 2019

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Validation of OCO-2 error analysis using simulated retrievals
journal, January 2019

  • Kulawik, Susan S.; O'Dell, Chris; Nelson, Robert R.
  • Atmospheric Measurement Techniques, Vol. 12, Issue 10
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Classification of Anomalous Pixels in the Focal Plane Arrays of Orbiting Carbon Observatory-2 and -3 via Machine Learning
journal, December 2019

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  • Remote Sensing, Vol. 11, Issue 24
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Southern California megacity CO 2 , CH 4 , and CO flux estimates using ground- and space-based remote sensing and a Lagrangian model
journal, January 2018

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  • Atmospheric Chemistry and Physics, Vol. 18, Issue 22
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Analysis of Four Years of Global XCO2 Anomalies as Seen by Orbiting Carbon Observatory-2
journal, April 2019

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Quantifying the impact of aerosol scattering on the retrieval of methane from airborne remote sensing measurements
text, January 2020

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Regional Impacts of COVID-19 on Carbon Dioxide Detected Worldwide from Space
preprint, January 2020


WOMBAT: A fully Bayesian global flux-inversion framework
preprint, January 2021


Objective evaluation of surface- and satellite-driven carbon dioxide atmospheric inversions
journal, January 2019

  • Chevallier, Frédéric; Remaud, Marine; O'Dell, Christopher W.
  • Atmospheric Chemistry and Physics, Vol. 19, Issue 22
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The 2015–2016 carbon cycle as seen from OCO-2 and the global in situ network
journal, January 2019

  • Crowell, Sean; Baker, David; Schuh, Andrew
  • Atmospheric Chemistry and Physics, Vol. 19, Issue 15
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Methane retrieved from TROPOMI: improvement of the data product and validation of the first 2 years of measurements
journal, January 2021

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Evaluation of MOPITT Version 7 joint TIR-NIR XCO retrievals with TCCON
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Overview: Estimating and reporting uncertainties in remotely sensed atmospheric composition and temperature
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