A fundamental understanding of whole biomass dissolution in ionic liquid for regeneration of fiber by solution-spinning

Nguyen, Ngoc A.; Kim, Keonhee; Bowland, Christopher C.; Keum, Jong K.; Kearney, Logan T.; André, Nicolas; Labbé, Nicole; Naskar, Amit K.

doi:10.1039/C9GC00774A

Title: A fundamental understanding of whole biomass dissolution in ionic liquid for regeneration of fiber by solution-spinning

Abstract

Materials made from renewable resources are interesting and attractive substitutes for petroleum-based materials. Recently, regeneration of cellulose fibers using ionic liquids (ILs) as green solvents has been a topic of interest to both industrial and academic sectors. However, extraction of cellulose from lignocellulosic biomass requires numerous energy intensive processing steps. Additionally, the deconstruction and removal of lignin and hemicellulose components from lignocellulosic biomass usually involve corrosive pretreatment and the solvation of specific biomass components. Instead, utilization of the whole biomass—particularly woody residues—to manufacture high-performance materials offers an attractive value-proposition. In this study, we demonstrated fiber regeneration of whole hybrid poplar (HP) biomass by a sustainable method. We developed an environmentally friendly approach by partially auto-hydrolyzing the biomass with water before its dissolution in 1-ethyl-3-methylimidazolium acetate ([C2mim][OAc]) ionic liquid, for large-scale, roll-to-roll production of fibers by solution spinning. We discuss, for the first time, a fundamental understanding of the inter- and intramolecular interactions in HP biomass–IL solutions, as well as their corresponding spinnability, structural reformation, and mechanical performance of the regenerated fibers. Particularly, the molecular alignment, recrystallization, and crystallinity of the spun fibers were correlated to the chain entanglement, molecular relaxation, and rheological properties of the HP biomass–IL solutions. A windowmore »« less

Authors:

^[1]; Kim, Keonhee ^[2];

^[1];

^[1]; Kearney, Logan T. ^[1]; André, Nicolas ^[2];

^[2];

^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Publication Date:: 2019-06-20

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office

OSTI Identifier:: 1557507

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Green Chemistry

Additional Journal Information:: Journal Volume: 21; Journal Issue: 16; Journal ID: ISSN 1463-9262

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Nguyen, Ngoc A., Kim, Keonhee, Bowland, Christopher C., Keum, Jong K., Kearney, Logan T., André, Nicolas, Labbé, Nicole, and Naskar, Amit K.. A fundamental understanding of whole biomass dissolution in ionic liquid for regeneration of fiber by solution-spinning.  United States: N. p., 2019. 
Web.  doi:10.1039/C9GC00774A.

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                    Nguyen, Ngoc A., Kim, Keonhee, Bowland, Christopher C., Keum, Jong K., Kearney, Logan T., André, Nicolas, Labbé, Nicole, & Naskar, Amit K.. A fundamental understanding of whole biomass dissolution in ionic liquid for regeneration of fiber by solution-spinning.  United States.  https://doi.org/10.1039/C9GC00774A

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                    Nguyen, Ngoc A., Kim, Keonhee, Bowland, Christopher C., Keum, Jong K., Kearney, Logan T., André, Nicolas, Labbé, Nicole, and Naskar, Amit K.. Thu .  
"A fundamental understanding of whole biomass dissolution in ionic liquid for regeneration of fiber by solution-spinning".  United States.  https://doi.org/10.1039/C9GC00774A.  https://www.osti.gov/servlets/purl/1557507.

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@article{osti_1557507,

  title        = {A fundamental understanding of whole biomass dissolution in ionic liquid for regeneration of fiber by solution-spinning},

  author       = {Nguyen, Ngoc A. and Kim, Keonhee and Bowland, Christopher C. and Keum, Jong K. and Kearney, Logan T. and André, Nicolas and Labbé, Nicole and Naskar, Amit K.},

  abstractNote = {Materials made from renewable resources are interesting and attractive substitutes for petroleum-based materials. Recently, regeneration of cellulose fibers using ionic liquids (ILs) as green solvents has been a topic of interest to both industrial and academic sectors. However, extraction of cellulose from lignocellulosic biomass requires numerous energy intensive processing steps. Additionally, the deconstruction and removal of lignin and hemicellulose components from lignocellulosic biomass usually involve corrosive pretreatment and the solvation of specific biomass components. Instead, utilization of the whole biomass—particularly woody residues—to manufacture high-performance materials offers an attractive value-proposition. In this study, we demonstrated fiber regeneration of whole hybrid poplar (HP) biomass by a sustainable method. We developed an environmentally friendly approach by partially auto-hydrolyzing the biomass with water before its dissolution in 1-ethyl-3-methylimidazolium acetate ([C2mim][OAc]) ionic liquid, for large-scale, roll-to-roll production of fibers by solution spinning. We discuss, for the first time, a fundamental understanding of the inter- and intramolecular interactions in HP biomass–IL solutions, as well as their corresponding spinnability, structural reformation, and mechanical performance of the regenerated fibers. Particularly, the molecular alignment, recrystallization, and crystallinity of the spun fibers were correlated to the chain entanglement, molecular relaxation, and rheological properties of the HP biomass–IL solutions. A window of entangled concentration (4–6.5 wt%) of biomass in the IL was determined to be favorable for fiber spinning.},

  doi          = {10.1039/C9GC00774A},

  journal      = {Green Chemistry},

  number       = 16,

  volume       = 21,

  place        = {United States},

  year         = {2019},

  month        = {6}

}

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This work aims to characterize microbial tolerance to 1-ethyl-3-methylimidazolium acetate ([C2mim][OAc]), ionic liquid that has emerged as a novel biomass pretreatment for lignocellulosic biomass. Enrichment experiments performed using inocula treated with [C2mim][OAc] under solid and liquid cultivation yielded fungal populationsdominated by Aspergilli. Ionic liquid-tolerant Aspergillus isolates from these enrichments were capable of growing in a radial plate growth assay in the presence of 10% [C2mim][OAc]. When a [C2mim][OAc]-tolerant Aspergillus fumigatus strain was grown in the presence of switchgrass, endoglucanases and xylanases were secreted that retained residual enzymatic activity in the presence of 20% [C2mim][OAc]. The results of the study suggestmore »« less
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Controlled Assembly of Lignocellulosic Biomass Components and Properties of Reformed Materials

Journal Article Wang, Jing ; Boy, Ramiz ; Nguyen, Ngoc A. ; ... - ACS Sustainable Chemistry & Engineering

Reforming whole lignocellulosic biomass into value-added materials has yet to be achieved mainly due to the infusible nature of biomass and its recalcitrance to dissolve in common organic solvents. Recently, the solubility of biomass in ionic liquids (ILs) has been explored to develop all-lignocellulosic materials; however, efficient dissolution and therefore production of value-added materials with desired mechanical properties remain a challenge. This article presents an approach to producing high-performance lignocellulosic films from hybrid poplar wood. An autohydrolysis step that removes ≤50% of the hemicellulose fraction is performed to enhance biomass solvation in 1-ethyl-3-methyl imidazolium acetate ([C2mim][OAc]). The resulting biomass–IL solutionmore »« less
Cited by 18
https://doi.org/10.1021/acssuschemeng.7b01639

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Regenerating cellulose from ionic liquids for an accelerated enzymatic hydrolysis

Journal Article Zhao, Hua ; Jones, Cecil L ; Baker, Gary A ; ... - Journal of Biotechnology

The efficient conversion of lignocellulosic materials into fuel ethanol has become a research priority in producing affordable and renewable energy. The pretreatment of lignocelluloses is known to be key to the fast enzymatic hydrolysis of cellulose. Recently, certain ionic liquids (ILs)were found capable of dissolving more than 10 wt% cellulose. Preliminary investigations [Dadi, A.P., Varanasi, S., Schall, C.A., 2006. Enhancement of cellulose saccharification kinetics using an ionic liquid pretreatment step. Biotechnol. Bioeng. 95, 904 910; Liu, L., Chen, H., 2006. Enzymatic hydrolysis of cellulose materials treated with ionic liquid [BMIM]Cl. Chin. Sci. Bull. 51, 2432 2436; Dadi, A.P., Schall, C.A.,more »« less
https://doi.org/10.1016/j.jbiotec.2008.08.009
Ionic Liquid Platform for Spinning Composite Chitin–Poly(lactic acid) Fibers

Journal Article Shamshina, Julia L. ; Zavgorodnya, Oleksandra ; Berton, Paula ; ... - ACS Sustainable Chemistry & Engineering

In the design of stronger chitin fibers reinforced with poly(lactic acid) (PLA), an ionic-liquid-based (IL-based) approach was developed in which both polymers were codissolved in an 1-ethyl-3-methylimidazolium acetate ([C₂mim][OAc]) and wet-jet spun into composite fibers. Chitin, directly extracted from shrimp shell, had a solubility in the IL of 2.75 wt %, while PLA of MW 700 000 g/mol had a solubility of 49 wt %. Keeping the IL saturated in chitin, homogeneous solutions of chitin and PLA could be obtained up to 27 wt % (relative to the IL) PLA. Spinning dopes were prepared by maintaining the chitin concentration relativemore »« less
Cited by 24
https://doi.org/10.1021/acssuschemeng.8b01554

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Title: A fundamental understanding of whole biomass dissolution in ionic liquid for regeneration of fiber by solution-spinning

Abstract

Citation Formats

Valorization of Arundo donax for the production of high performance lignocellulosic films journal, November 2018

Dynamic shear modulus of a semiflexible polymer network journal, August 1998

Filament spinning of unbleached birch kraft pulps: Effect of pulping intensity on the processability and the fiber properties journal, January 2018

Crystalline characteristics of cellulose fiber and film regenerated from ionic liquid solution journal, March 2015

Deformation Mechanism of Poly(3-alkylthiophene) Studied by in Situ X-ray Scattering and Texture Analysis journal, October 2018

Application of mild autohydrolysis to facilitate the dissolution of wood chips in direct-dissolution solvents journal, January 2016

Dissolution of Cellose with Ionic Liquids journal, May 2002

Structure development during polymer processing: Studies of the melt spinning of polyethylene and polypropylene fibers journal, September 1975

Physical and mechanical properties of ultra-oriented high-density polyethylene fibers journal, May 1979

Dissolution of lignocellulosic materials and its constituents using ionic liquids—A review journal, November 2010

Solution rheology of cellulose in 1-butyl-3-methyl imidazolium chloride journal, May 2011

Molecular theory for the viscoelasticity of compatible polymer mixtures. 2. Tube model with reptation and constraint release contributions journal, November 1989

Regenerated-Cellulose/Multiwalled- Carbon-Nanotube Composite Fibers with Enhanced Mechanical Properties Prepared with the Ionic Liquid 1-Allyl-3-methylimidazolium Chloride journal, March 2007

Mechanical behavior of electrospun polyurethane journal, October 2003

Nature or Petrochemistry?—Biologically Degradable Materials journal, February 2004

Are natural fiber composites environmentally superior to glass fiber reinforced composites? journal, March 2004

Kenaf fiber reinforced composites: A review journal, September 2011

Dissolution of Wood in Ionic Liquids journal, October 2007

Analysis of regenerated cellulose fibers with ionic liquids as a solvent as spinning speed is increased journal, May 2012

Shear and Extensional Rheology of Cellulose/Ionic Liquid Solutions journal, April 2012

Polymers from Renewable Resources: A Challenge for the Future of Macromolecular Materials journal, December 2008

Dissolution and forming of cellulose with ionic liquids journal, September 2007

Crystallization of running filament in melt spinning of polypropylene journal, September 1977

Reinforcement of complete denture bases with continuous high performance polyethylene fibers journal, December 1992

Kenaf reinforced biodegradable composite journal, July 2003

Phase Transition and Rheological Behaviors of Concentrated Cellulose/Ionic Liquid Solutions journal, May 2010

Cellulose nanofiber-reinforced polylactic acid journal, July 2008

Rheological Properties of Cellulose/Ionic Liquid Solutions: From Dilute to Concentrated States journal, May 2009

High-strength polyethylene fibres from solution and gel spinning journal, July 1985

Bamboo (Neosinocalamus affinis)-based thin film, a novel biomass material with high performances journal, March 2015

Correlations of Solution Rheology with Electrospun Fiber Formation of Linear and Branched Polyesters journal, March 2004

The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming Liquids journal, July 1955

Controlled Assembly of Lignocellulosic Biomass Components and Properties of Reformed Materials journal, August 2017

Magnetite-embedded cellulose fibers prepared from ionic liquid journal, January 2008

Celluloses in an Ionic Liquid: the Rheological Properties of the Solutions Spanning the Dilute and Semidilute Regimes journal, August 2008

Dry jet-wet spinning of strong cellulose filaments from ionic liquid solution journal, September 2014

Ionic liquids as a tool for lignocellulosic biomass fractionation journal, January 2013

Rheology of 1-butyl-3-methylimidazolium chloride cellulose solutions. I. Shear rheology journal, October 2008

Lignin Valorization: Improving Lignin Processing in the Biorefinery journal, May 2014

Structure and linear viscoelasticity of flexible polymer solutions: comparison of polyelectrolyte and neutral polymer solutions journal, December 2009

Research progress on dissolution and functional modification of cellulose in ionic liquids journal, August 2008

Characterization of cellulose fibers electrospun using ionic liquid journal, December 2009

Deconstruction of lignocellulosic biomass with ionic liquids journal, January 2013

A path for lignin valorization via additive manufacturing of high-performance sustainable composites with enhanced 3D printability journal, December 2018

High-Frequency Stress Relaxation in Semiflexible Polymer Solutions and Networks journal, April 2006

Carbon fiber reinforced plastics in aircraft construction journal, December 2005

Studies on lignocellulosic fibers of Brazil. Part I: Source, production, morphology, properties and applications journal, July 2007

Increasing the revenue from lignocellulosic biomass: Maximizing feedstock utilization journal, May 2017

Transparent Woody Film Made by Dissolution of Finely Divided Japanese Beech in Formic Acid at Room Temperature journal, November 2017

On the use of time-temperature superposition in multicomponent/multiphase polymer systems journal, January 1993

Effect of water and methanol on the dissolution and gelatinization of corn starch in [MMIM][(MeO)HPO 2 ] journal, January 2015

Transforming Sugarcane Bagasse into Bioplastics via Homogeneous Modification with Phthalic Anhydride in Ionic Liquid journal, August 2015

Composite fibers spun directly from solutions of raw lignocellulosic biomass dissolved in ionic liquids journal, January 2011

Cellulose-Lignin Interactions (A Computational Study) journal, March 1995

Where are ionic liquid strategies most suited in the pursuit of chemicals and energy from lignocellulosic biomass? journal, January 2011

Rapid dissolution of lignocellulosic biomass in ionic liquids using temperatures above the glass transition of lignin journal, January 2011

Structure and properties of cellulose fibers from ionic liquids journal, January 2010

Rheological characterization of concentrated cellulose solutions in 1-allyl-3-methylimidazolium chloride journal, November 2011

Ionic Liquids and Their Interaction with Cellulose journal, December 2009

A general method to improve 3D-printability and inter-layer adhesion in lignin-based composites journal, September 2018

Fabrication of aligned and molecularly oriented electrospun polyacrylonitrile nanofibers and the mechanical behavior of their twisted yarns journal, May 2004

Banana fibers and microfibrils as lignocellulosic reinforcements in polymer composites journal, July 2010

Thermogravimetric analysis and kinetic study of poplar wood pyrolysis journal, September 2012

Liquid Crystalline Phase and Gel−Sol Transitions for Concentrated Microcrystalline Cellulose (MCC)/1-Ethyl-3-methylimidazolium Acetate (EMIMAc) Solutions journal, April 2011

Viscoelasticity of tightly entangled solutions of semiflexible polymers journal, August 1998

High-performance aromatic polyimide fibres: 2. Thermal mechanical and dynamic properties journal, January 1993

Approach to Renewable Lignocellulosic Biomass Film Directly from Bagasse journal, March 2014

Effect of alkaline pretreatment on the preparation of regenerated lignocellulose fibers from bamboo stem journal, June 2016

Ultrahigh-strength polyethylene filaments by solution spinning and hot drawing journal, October 1979

Viscosity of Cellulose−Imidazolium-Based Ionic Liquid Solutions journal, June 2010

Biodegradable composites based on lignocellulosic fibers—An overview journal, September 2009

Enhancement of ionic liquid-aided fractionation of birchwood. Part 1: autohydrolysis pretreatment journal, January 2013

Possibilities for the Physical Modification of Cellulose Shapes Using Ionic Liquids journal, June 2009

Production of nanocrystalline cellulose from lignocellulosic biomass: Technology and applications journal, April 2013

Natural fiber polymer composites: A review journal, January 1999

Ionic liquid processing of cellulose journal, January 2012

Rheology of End-Tethered Polymer Layered Silicate Nanocomposites journal, July 1997

Valorization of Arundo donax for the production of high performance lignocellulosic films
journal, November 2018

Dynamic shear modulus of a semiflexible polymer network
journal, August 1998

Filament spinning of unbleached birch kraft pulps: Effect of pulping intensity on the processability and the fiber properties
journal, January 2018

Crystalline characteristics of cellulose fiber and film regenerated from ionic liquid solution
journal, March 2015

Deformation Mechanism of Poly(3-alkylthiophene) Studied by in Situ X-ray Scattering and Texture Analysis
journal, October 2018

Application of mild autohydrolysis to facilitate the dissolution of wood chips in direct-dissolution solvents
journal, January 2016

Dissolution of Cellose with Ionic Liquids
journal, May 2002

Structure development during polymer processing: Studies of the melt spinning of polyethylene and polypropylene fibers
journal, September 1975

Physical and mechanical properties of ultra-oriented high-density polyethylene fibers
journal, May 1979

Dissolution of lignocellulosic materials and its constituents using ionic liquids—A review
journal, November 2010

Solution rheology of cellulose in 1-butyl-3-methyl imidazolium chloride
journal, May 2011

Molecular theory for the viscoelasticity of compatible polymer mixtures. 2. Tube model with reptation and constraint release contributions
journal, November 1989

Regenerated-Cellulose/Multiwalled- Carbon-Nanotube Composite Fibers with Enhanced Mechanical Properties Prepared with the Ionic Liquid 1-Allyl-3-methylimidazolium Chloride
journal, March 2007

Mechanical behavior of electrospun polyurethane
journal, October 2003

Nature or Petrochemistry?—Biologically Degradable Materials
journal, February 2004

Are natural fiber composites environmentally superior to glass fiber reinforced composites?
journal, March 2004

Kenaf fiber reinforced composites: A review
journal, September 2011

Dissolution of Wood in Ionic Liquids
journal, October 2007

Analysis of regenerated cellulose fibers with ionic liquids as a solvent as spinning speed is increased
journal, May 2012

Shear and Extensional Rheology of Cellulose/Ionic Liquid Solutions
journal, April 2012

Polymers from Renewable Resources: A Challenge for the Future of Macromolecular Materials
journal, December 2008

Dissolution and forming of cellulose with ionic liquids
journal, September 2007

Crystallization of running filament in melt spinning of polypropylene
journal, September 1977

Reinforcement of complete denture bases with continuous high performance polyethylene fibers
journal, December 1992

Kenaf reinforced biodegradable composite
journal, July 2003

Phase Transition and Rheological Behaviors of Concentrated Cellulose/Ionic Liquid Solutions
journal, May 2010

Cellulose nanofiber-reinforced polylactic acid
journal, July 2008

Rheological Properties of Cellulose/Ionic Liquid Solutions: From Dilute to Concentrated States
journal, May 2009

High-strength polyethylene fibres from solution and gel spinning
journal, July 1985

Bamboo (Neosinocalamus affinis)-based thin film, a novel biomass material with high performances
journal, March 2015

Correlations of Solution Rheology with Electrospun Fiber Formation of Linear and Branched Polyesters
journal, March 2004

The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming Liquids
journal, July 1955

Controlled Assembly of Lignocellulosic Biomass Components and Properties of Reformed Materials
journal, August 2017

Magnetite-embedded cellulose fibers prepared from ionic liquid
journal, January 2008

Celluloses in an Ionic Liquid: the Rheological Properties of the Solutions Spanning the Dilute and Semidilute Regimes
journal, August 2008

Dry jet-wet spinning of strong cellulose filaments from ionic liquid solution
journal, September 2014

Ionic liquids as a tool for lignocellulosic biomass fractionation
journal, January 2013

Rheology of 1-butyl-3-methylimidazolium chloride cellulose solutions. I. Shear rheology
journal, October 2008

Lignin Valorization: Improving Lignin Processing in the Biorefinery
journal, May 2014

Structure and linear viscoelasticity of flexible polymer solutions: comparison of polyelectrolyte and neutral polymer solutions
journal, December 2009

Research progress on dissolution and functional modification of cellulose in ionic liquids
journal, August 2008

Characterization of cellulose fibers electrospun using ionic liquid
journal, December 2009

Deconstruction of lignocellulosic biomass with ionic liquids
journal, January 2013

A path for lignin valorization via additive manufacturing of high-performance sustainable composites with enhanced 3D printability
journal, December 2018

High-Frequency Stress Relaxation in Semiflexible Polymer Solutions and Networks
journal, April 2006

Carbon fiber reinforced plastics in aircraft construction
journal, December 2005

Studies on lignocellulosic fibers of Brazil. Part I: Source, production, morphology, properties and applications
journal, July 2007

Increasing the revenue from lignocellulosic biomass: Maximizing feedstock utilization
journal, May 2017

Transparent Woody Film Made by Dissolution of Finely Divided Japanese Beech in Formic Acid at Room Temperature
journal, November 2017

On the use of time-temperature superposition in multicomponent/multiphase polymer systems
journal, January 1993

Effect of water and methanol on the dissolution and gelatinization of corn starch in [MMIM][(MeO)HPO ₂ ]
journal, January 2015

Transforming Sugarcane Bagasse into Bioplastics via Homogeneous Modification with Phthalic Anhydride in Ionic Liquid
journal, August 2015

Composite fibers spun directly from solutions of raw lignocellulosic biomass dissolved in ionic liquids
journal, January 2011

Cellulose-Lignin Interactions (A Computational Study)
journal, March 1995

Where are ionic liquid strategies most suited in the pursuit of chemicals and energy from lignocellulosic biomass?
journal, January 2011

Rapid dissolution of lignocellulosic biomass in ionic liquids using temperatures above the glass transition of lignin
journal, January 2011

Structure and properties of cellulose fibers from ionic liquids
journal, January 2010

Rheological characterization of concentrated cellulose solutions in 1-allyl-3-methylimidazolium chloride
journal, November 2011

Ionic Liquids and Their Interaction with Cellulose
journal, December 2009

A general method to improve 3D-printability and inter-layer adhesion in lignin-based composites
journal, September 2018

Fabrication of aligned and molecularly oriented electrospun polyacrylonitrile nanofibers and the mechanical behavior of their twisted yarns
journal, May 2004

Banana fibers and microfibrils as lignocellulosic reinforcements in polymer composites
journal, July 2010

Thermogravimetric analysis and kinetic study of poplar wood pyrolysis
journal, September 2012

Liquid Crystalline Phase and Gel−Sol Transitions for Concentrated Microcrystalline Cellulose (MCC)/1-Ethyl-3-methylimidazolium Acetate (EMIMAc) Solutions
journal, April 2011

Viscoelasticity of tightly entangled solutions of semiflexible polymers
journal, August 1998

High-performance aromatic polyimide fibres: 2. Thermal mechanical and dynamic properties
journal, January 1993

Approach to Renewable Lignocellulosic Biomass Film Directly from Bagasse
journal, March 2014

Effect of alkaline pretreatment on the preparation of regenerated lignocellulose fibers from bamboo stem
journal, June 2016

Ultrahigh-strength polyethylene filaments by solution spinning and hot drawing
journal, October 1979

Viscosity of Cellulose−Imidazolium-Based Ionic Liquid Solutions
journal, June 2010

Biodegradable composites based on lignocellulosic fibers—An overview
journal, September 2009

Enhancement of ionic liquid-aided fractionation of birchwood. Part 1: autohydrolysis pretreatment
journal, January 2013

Possibilities for the Physical Modification of Cellulose Shapes Using Ionic Liquids
journal, June 2009

Production of nanocrystalline cellulose from lignocellulosic biomass: Technology and applications
journal, April 2013

Natural fiber polymer composites: A review
journal, January 1999

Ionic liquid processing of cellulose
journal, January 2012

Rheology of End-Tethered Polymer Layered Silicate Nanocomposites
journal, July 1997

New Developments in Dissolving and Processing of Cellulose in Ionic Liquids
journal, February 2008

Nature or Petrochemistry? — Biologically Degradable Materials
journal, May 2004