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Title: Gas-phase pyrolysis products emitted by prescribed fires in pine forests with a shrub understory in the southeastern United States

Abstract

Here we confirm pyrolysis gases from prescribed burns conducted inpine forests with a shrub understory captured using a manual extraction device. The device selectively sampled emissions ahead of the flame front,minimizing the collection of oxidized gases, with the captured gases analyzed in the laboratory using infrared (IR) absorption spectroscopy. Results show that emission ratios (ERs) relative to CO for ethene and acetylene were significantly greater than in previous fire studies, suggesting that the sample device was able to collect gases predominantly generated prior to ignition. Additional evidence that ignition had not begun was corroborated by novel IR detections of several species, in particular naphthalene. With regards to oxygenated species, several aldehydes (acrolein, furaldehyde, acetaldehyde,formaldehyde) and carboxylic acids (formic, acetic) were all observed;results show that ERs for acetaldehyde were noticeably greater, while ERs for formaldehyde and acetic acid were lower compared to other studies. The acetylene-to-furan ratio also suggests that high-temperature pyrolysis was the dominant process generating the collected gases.

Authors:
 [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1];  [2];  [2];  [3];  [3];  [3];  [4];  [5]; ORCiD logo [3]; ORCiD logo [1]
  1. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  2. USDA Forest Service, Missoula, MT (United States)
  3. USDA Forest Service, Riverside, CA (United States)
  4. USDA Forest Service, Seattle, WA (United States)
  5. Univ. of Washington, Seattle, WA (United States)
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1557233
Report Number(s):
PNNL-SA-141102
Journal ID: ISSN 1680-7324
Grant/Contract Number:  
AC05-76RL01830
Resource Type:
Accepted Manuscript
Journal Name:
Atmospheric Chemistry and Physics (Online)
Additional Journal Information:
Journal Name: Atmospheric Chemistry and Physics (Online); Journal Volume: 19; Journal Issue: 15; Journal ID: ISSN 1680-7324
Publisher:
European Geosciences Union
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES

Citation Formats

Scharko, Nicole K., Oeck, Ashley M., Myers, Tanya L., Tonkyn, Russell G., Banach, Catherine A., Baker, Stephen P., Lincoln, Emily N., Chong, Joey, Corcoran, Bonni M., Burke, Gloria M., Ottmar, Roger D., Restaino, Joseph C., Weise, David R., and Johnson, Timothy J. Gas-phase pyrolysis products emitted by prescribed fires in pine forests with a shrub understory in the southeastern United States. United States: N. p., 2019. Web. doi:10.5194/acp-19-9681-2019.
Scharko, Nicole K., Oeck, Ashley M., Myers, Tanya L., Tonkyn, Russell G., Banach, Catherine A., Baker, Stephen P., Lincoln, Emily N., Chong, Joey, Corcoran, Bonni M., Burke, Gloria M., Ottmar, Roger D., Restaino, Joseph C., Weise, David R., & Johnson, Timothy J. Gas-phase pyrolysis products emitted by prescribed fires in pine forests with a shrub understory in the southeastern United States. United States. doi:10.5194/acp-19-9681-2019.
Scharko, Nicole K., Oeck, Ashley M., Myers, Tanya L., Tonkyn, Russell G., Banach, Catherine A., Baker, Stephen P., Lincoln, Emily N., Chong, Joey, Corcoran, Bonni M., Burke, Gloria M., Ottmar, Roger D., Restaino, Joseph C., Weise, David R., and Johnson, Timothy J. Thu . "Gas-phase pyrolysis products emitted by prescribed fires in pine forests with a shrub understory in the southeastern United States". United States. doi:10.5194/acp-19-9681-2019. https://www.osti.gov/servlets/purl/1557233.
@article{osti_1557233,
title = {Gas-phase pyrolysis products emitted by prescribed fires in pine forests with a shrub understory in the southeastern United States},
author = {Scharko, Nicole K. and Oeck, Ashley M. and Myers, Tanya L. and Tonkyn, Russell G. and Banach, Catherine A. and Baker, Stephen P. and Lincoln, Emily N. and Chong, Joey and Corcoran, Bonni M. and Burke, Gloria M. and Ottmar, Roger D. and Restaino, Joseph C. and Weise, David R. and Johnson, Timothy J.},
abstractNote = {Here we confirm pyrolysis gases from prescribed burns conducted inpine forests with a shrub understory captured using a manual extraction device. The device selectively sampled emissions ahead of the flame front,minimizing the collection of oxidized gases, with the captured gases analyzed in the laboratory using infrared (IR) absorption spectroscopy. Results show that emission ratios (ERs) relative to CO for ethene and acetylene were significantly greater than in previous fire studies, suggesting that the sample device was able to collect gases predominantly generated prior to ignition. Additional evidence that ignition had not begun was corroborated by novel IR detections of several species, in particular naphthalene. With regards to oxygenated species, several aldehydes (acrolein, furaldehyde, acetaldehyde,formaldehyde) and carboxylic acids (formic, acetic) were all observed;results show that ERs for acetaldehyde were noticeably greater, while ERs for formaldehyde and acetic acid were lower compared to other studies. The acetylene-to-furan ratio also suggests that high-temperature pyrolysis was the dominant process generating the collected gases.},
doi = {10.5194/acp-19-9681-2019},
journal = {Atmospheric Chemistry and Physics (Online)},
number = 15,
volume = 19,
place = {United States},
year = {2019},
month = {8}
}

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Works referenced in this record:

Smoke emissions from biomass burning in a Mediterranean shrubland
journal, August 2010


Polycyclic Aromatic Hydrocarbons in Birch Wood Slow Pyrolysis Products
journal, October 2012

  • Fagernäs, Leena; Kuoppala, Eeva; Simell, Pekka
  • Energy & Fuels, Vol. 26, Issue 11
  • DOI: 10.1021/ef3010515

Airborne measurements of western U.S. wildfire emissions: Comparison with prescribed burning and air quality implications: Western U.S. Wildfire Emissions
journal, June 2017

  • Liu, Xiaoxi; Huey, L. Gregory; Yokelson, Robert J.
  • Journal of Geophysical Research: Atmospheres, Vol. 122, Issue 11
  • DOI: 10.1002/2016JD026315

Airborne and ground-based measurements of the trace gases and particles emitted by prescribed fires in the United States
journal, January 2011

  • Burling, I. R.; Yokelson, R. J.; Akagi, S. K.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 23
  • DOI: 10.5194/acp-11-12197-2011

Aerosol optical properties and trace gas emissions by PAX and OP-FTIR for laboratory-simulated western US wildfires during FIREX
journal, January 2018

  • Selimovic, Vanessa; Yokelson, Robert J.; Warneke, Carsten
  • Atmospheric Chemistry and Physics, Vol. 18, Issue 4
  • DOI: 10.5194/acp-18-2929-2018

Boreal forest fire emissions in fresh Canadian smoke plumes: C 1 -C 10 volatile organic compounds (VOCs), CO 2 , CO, NO 2 , NO, HCN and CH 3 CN
journal, January 2011

  • Simpson, I. J.; Akagi, S. K.; Barletta, B.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 13
  • DOI: 10.5194/acp-11-6445-2011

An infrared spectral database for detection of gases emitted by biomass burning
journal, May 2010


Smoke and fire characteristics for cerrado and deforestation burns in Brazil: BASE-B Experiment
journal, January 1992

  • Ward, D. E.; Susott, R. A.; Kauffman, J. B.
  • Journal of Geophysical Research, Vol. 97, Issue D13
  • DOI: 10.1029/92JD01218

Measurements of reactive trace gases and variable O 3 formation rates in some South Carolina biomass burning plumes
journal, January 2013

  • Akagi, S. K.; Yokelson, R. J.; Burling, I. R.
  • Atmospheric Chemistry and Physics, Vol. 13, Issue 3
  • DOI: 10.5194/acp-13-1141-2013

NO x and N 2 O Precursors from Biomass Pyrolysis: Role of Cellulose, Hemicellulose and Lignin
journal, July 2013

  • Ren, Qiangqiang; Zhao, Changsui
  • Environmental Science & Technology
  • DOI: 10.1021/es4017574

Multi-instrument comparison and compilation of non-methane organic gas emissions from biomass burning and implications for smoke-derived secondary organic aerosol precursors
journal, January 2017

  • Hatch, Lindsay E.; Yokelson, Robert J.; Stockwell, Chelsea E.
  • Atmospheric Chemistry and Physics, Vol. 17, Issue 2
  • DOI: 10.5194/acp-17-1471-2017

Assignment of the Fundamental Modes of Hydroxyacetone Using Gas-Phase Infrared, Far-Infrared, Raman, and ab Initio Methods: Band Strengths for Atmospheric Measurements
journal, July 2016

  • Lindenmaier, Rodica; Tipton, Nicole; Sams, Robert L.
  • The Journal of Physical Chemistry A, Vol. 120, Issue 30
  • DOI: 10.1021/acs.jpca.6b05045

Temperature dependence of fast pyrolysis volatile products from European and African biomasses
journal, March 2011

  • Azeez, Akeem M.; Meier, Dietrich; Odermatt, Jürgen
  • Journal of Analytical and Applied Pyrolysis, Vol. 90, Issue 2
  • DOI: 10.1016/j.jaap.2010.11.005

Emissions of trace gases from Australian temperate forest fires: emission factors and dependence on modified combustion efficiency
journal, January 2018

  • Guérette, Elise-Andrée; Paton-Walsh, Clare; Desservettaz, Maximilien
  • Atmospheric Chemistry and Physics, Vol. 18, Issue 5
  • DOI: 10.5194/acp-18-3717-2018

Biomass burning as a source of atmospheric gases CO, H2, N2O, NO, CH3Cl and COS
journal, November 1979

  • Crutzen, Paul J.; Heidt, Leroy E.; Krasnec, Joseph P.
  • Nature, Vol. 282, Issue 5736
  • DOI: 10.1038/282253a0

Numerical simulation and experiments of burning douglas fir trees
journal, October 2009


Field measurements of trace gases emitted by prescribed fires in southeastern US pine forests using an open-path FTIR system
journal, January 2014

  • Akagi, S. K.; Burling, I. R.; Mendoza, A.
  • Atmospheric Chemistry and Physics, Vol. 14, Issue 1
  • DOI: 10.5194/acp-14-199-2014

Study on the pyrolytic behaviour of xylan-based hemicellulose using TG–FTIR and Py–GC–FTIR
journal, March 2010

  • Shen, D. K.; Gu, S.; Bridgwater, A. V.
  • Journal of Analytical and Applied Pyrolysis, Vol. 87, Issue 2
  • DOI: 10.1016/j.jaap.2009.12.001

The mechanism for thermal decomposition of cellulose and its main products
journal, December 2009


Absolute integrated intensities of vapor-phase hydrogen peroxide (H2O2) in the mid-infrared at atmospheric pressure
journal, May 2009

  • Johnson, Timothy J.; Sams, Robert L.; Burton, Sarah D.
  • Analytical and Bioanalytical Chemistry, Vol. 395, Issue 2
  • DOI: 10.1007/s00216-009-2805-x

A sub-grid, mixture - fraction-based thermodynamic equilibrium model for gas phase combustion in FIRETEC: development and results
journal, January 2010

  • Clark, Michael M.; Fletcher, Thomas H.; Linn, Rodman R.
  • International Journal of Wildland Fire, Vol. 19, Issue 2
  • DOI: 10.1071/WF07116

Ultrapyrolysis of n-hexadecane in a novel micro-reactor
journal, December 1990


Modelling of tar formation and evolution for biomass gasification: A review
journal, November 2013


Modeling and simulation of combustion processes of charring and non-charring solid fuels
journal, January 1993


An investigation of pyrolysis and ignition of moist leaf-like fuel subject to convective heating
journal, April 2018


The Chemistry of Nitrate Esters
journal, June 1955

  • Boschan, Robert; Merrow, Raymond T.; van Dolah, Robert W.
  • Chemical Reviews, Vol. 55, Issue 3
  • DOI: 10.1021/cr50003a001

Laboratory measurements of trace gas emissions from biomass burning of fuel types from the southeastern and southwestern United States
journal, January 2010

  • Burling, I. R.; Yokelson, R. J.; Griffith, D. W. T.
  • Atmospheric Chemistry and Physics, Vol. 10, Issue 22
  • DOI: 10.5194/acp-10-11115-2010

New Approaches to Measuring Sticky Molecules: Improvement of Instrumental Response Times Using Active Passivation
journal, July 2015

  • Roscioli, J. R.; Zahniser, M. S.; Nelson, D. D.
  • The Journal of Physical Chemistry A, Vol. 120, Issue 9
  • DOI: 10.1021/acs.jpca.5b04395

Characterization of pyrolysis products from fast pyrolysis of live and dead vegetation native to the Southern United States
journal, October 2018


Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experiment
journal, January 2018

  • Koss, Abigail R.; Sekimoto, Kanako; Gilman, Jessica B.
  • Atmospheric Chemistry and Physics, Vol. 18, Issue 5
  • DOI: 10.5194/acp-18-3299-2018

Field measurements of trace gases and aerosols emitted by peat fires in Central Kalimantan, Indonesia, during the 2015 El Niño
journal, January 2016

  • Stockwell, Chelsea E.; Jayarathne, Thilina; Cochrane, Mark A.
  • Atmospheric Chemistry and Physics, Vol. 16, Issue 18
  • DOI: 10.5194/acp-16-11711-2016

The quantitative infrared and NIR spectrum of CH<sub>2</sub>I<sub>2</sub> vapor: vibrational assignments and potential for atmospheric monitoring
journal, January 2006

  • Johnson, T. J.; Masiello, T.; Sharpe, S. W.
  • Atmospheric Chemistry and Physics, Vol. 6, Issue 9
  • DOI: 10.5194/acp-6-2581-2006

Smoke emissions from wildland fires
journal, January 1991


Coupling field and laboratory measurements to estimate the emission factors of identified and unidentified trace gases for prescribed fires
journal, January 2013

  • Yokelson, R. J.; Burling, I. R.; Gilman, J. B.
  • Atmospheric Chemistry and Physics, Vol. 13, Issue 1
  • DOI: 10.5194/acp-13-89-2013

Recent acceleration of biomass burning and carbon losses in Alaskan forests and peatlands
journal, December 2010

  • Turetsky, Merritt R.; Kane, Evan S.; Harden, Jennifer W.
  • Nature Geoscience, Vol. 4, Issue 1
  • DOI: 10.1038/ngeo1027

Emissions of formaldehyde, acetic acid, methanol, and other trace gases from biomass fires in North Carolina measured by airborne Fourier transform infrared spectroscopy
journal, December 1999

  • Yokelson, R. J.; Goode, J. G.; Ward, D. E.
  • Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D23
  • DOI: 10.1029/1999JD900817

Pyrolysis kinetics of live and dead wildland vegetation from the Southern United States
journal, September 2019

  • Amini, Elham; Safdari, Mohammad-Saeed; Weise, David R.
  • Journal of Analytical and Applied Pyrolysis, Vol. 142
  • DOI: 10.1016/j.jaap.2019.05.002

A numerical investigation of the influence of radiation and moisture content on pyrolysis and ignition of a leaf-like fuel element
journal, January 2016


Detailed chemical kinetic models for the combustion of hydrocarbon fuels
journal, January 2003


Influence of plumes from biomass burning on atmospheric chemistry over the equatorial and tropical South Atlantic during CITE 3
journal, January 1994

  • Andreae, M. O.; Anderson, B. E.; Blake, D. R.
  • Journal of Geophysical Research, Vol. 99, Issue D6
  • DOI: 10.1029/94JD00263

Characterization of pyrolysis products from slow pyrolysis of live and dead vegetation native to the southern United States
journal, January 2019


Biomass burning emissions and potential air quality impacts of volatile organic compounds and other trace gases from fuels common in the US
journal, January 2015

  • Gilman, J. B.; Lerner, B. M.; Kuster, W. C.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 24
  • DOI: 10.5194/acp-15-13915-2015

International geosphere-biosphere programme/international global atmospheric chemistry SAFARI-92 field experiment: Background and overview
journal, October 1996

  • Lindesay, J. A.; Andreae, M. O.; Goldammer, J. G.
  • Journal of Geophysical Research: Atmospheres, Vol. 101, Issue D19
  • DOI: 10.1029/96JD01512

Seasonal trends and local influences on nonmethane hydrocarbon concentrations in the Canadian boreal forest
journal, March 1997

  • Young, V. L.; Kieser, B. N.; Chen, S. P.
  • Journal of Geophysical Research: Atmospheres, Vol. 102, Issue D5
  • DOI: 10.1029/96JD03375

Role of levoglucosan physiochemistry in cellulose pyrolysis
journal, January 2013

  • Bai, Xianglan; Johnston, Patrick; Sadula, Sunitha
  • Journal of Analytical and Applied Pyrolysis, Vol. 99
  • DOI: 10.1016/j.jaap.2012.10.028

Trace gas emissions from savanna fires in northern Australia
journal, January 2010

  • Paton-Walsh, C.; Deutscher, N. M.; Griffith, D. W. T.
  • Journal of Geophysical Research, Vol. 115, Issue D16
  • DOI: 10.1029/2009JD013309

Trace gas emissions from laboratory biomass fires measured by open-path Fourier transform infrared spectroscopy: Fires in grass and surface fuels
journal, September 1999

  • Goode, Jon G.; Yokelson, Robert J.; Susott, Ronald A.
  • Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D17
  • DOI: 10.1029/1999JD900360

Emission of trace gases and aerosols from biomass burning
journal, December 2001

  • Andreae, M. O.; Merlet, P.
  • Global Biogeochemical Cycles, Vol. 15, Issue 4
  • DOI: 10.1029/2000GB001382

Formation of HNCO, HCN, and NH3 from the pyrolysis of bark and nitrogen-containing model compounds
journal, May 2004


Measurement of methanol emissions from Australian wildfires by ground-based solar Fourier transform spectroscopy
journal, January 2008

  • Paton-Walsh, Clare; Wilson, Stephen R.; Jones, Nicholas B.
  • Geophysical Research Letters, Vol. 35, Issue 8
  • DOI: 10.1029/2007GL032951

Molecular Products and Radicals from Pyrolysis of Lignin
journal, November 2012

  • Kibet, J.; Khachatryan, L.; Dellinger, B.
  • Environmental Science & Technology, Vol. 46, Issue 23
  • DOI: 10.1021/es302942c

Emissions from biomass burning in the Yucatan
journal, January 2009

  • Yokelson, R. J.; Crounse, J. D.; DeCarlo, P. F.
  • Atmospheric Chemistry and Physics, Vol. 9, Issue 15
  • DOI: 10.5194/acp-9-5785-2009

Effects of structure on pyrolysis gases from amino acids
journal, January 1981

  • Haidar, Nabeel F.; Patterson, John M.; Moors, Michael
  • Journal of Agricultural and Food Chemistry, Vol. 29, Issue 1
  • DOI: 10.1021/jf00103a040

Heating rate and temperature effects on pyrolysis products from live wildland fuels
journal, April 2019


Quantitative IR Spectrum and Vibrational Assignments for Glycolaldehyde Vapor: Glycolaldehyde Measurements in Biomass Burning Plumes
journal, May 2013

  • Johnson, Timothy J.; Sams, Robert L.; Profeta, Luisa T. M.
  • The Journal of Physical Chemistry A, Vol. 117, Issue 20
  • DOI: 10.1021/jp311945p

Biomass-burning emissions and associated haze layers over Amazonia
journal, January 1988

  • Andreae, M. O.; Browell, E. V.; Garstang, M.
  • Journal of Geophysical Research, Vol. 93, Issue D2
  • DOI: 10.1029/JD093iD02p01509

Identification of gas-phase pyrolysis products in a prescribed fire: first detections using infrared spectroscopy for naphthalene, methyl nitrite, allene, acrolein and acetaldehyde
journal, January 2019

  • Scharko, Nicole K.; Oeck, Ashley M.; Tonkyn, Russell G.
  • Atmospheric Measurement Techniques, Vol. 12, Issue 1
  • DOI: 10.5194/amt-12-763-2019

The Tropical Forest and Fire Emissions Experiment: method evaluation of volatile organic compound emissions measured by PTR-MS, FTIR, and GC from tropical biomass burning
journal, January 2007

  • Karl, T. G.; Christian, T. J.; Yokelson, R. J.
  • Atmospheric Chemistry and Physics, Vol. 7, Issue 22
  • DOI: 10.5194/acp-7-5883-2007

Study of Inlet Materials for Sampling Atmospheric Nitric Acid
journal, April 1999

  • Neuman, J. A.; Huey, L. G.; Ryerson, T. B.
  • Environmental Science & Technology, Vol. 33, Issue 7
  • DOI: 10.1021/es980767f

The HITRAN2016 molecular spectroscopic database
journal, December 2017

  • Gordon, I. E.; Rothman, L. S.; Hill, C.
  • Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 203
  • DOI: 10.1016/j.jqsrt.2017.06.038

Gas-Phase Databases for Quantitative Infrared Spectroscopy
journal, December 2004

  • Sharpe, Steven W.; Johnson, Timothy J.; Sams, Robert L.
  • Applied Spectroscopy, Vol. 58, Issue 12
  • DOI: 10.1366/0003702042641281

Emission factors for open and domestic biomass burning for use in atmospheric models
journal, January 2011

  • Akagi, S. K.; Yokelson, R. J.; Wiedinmyer, C.
  • Atmospheric Chemistry and Physics, Vol. 11, Issue 9
  • DOI: 10.5194/acp-11-4039-2011

Trace gas emissions from biomass burning in tropical Australian savannas
journal, January 1994

  • Hurst, Dale F.; Griffith, David W. T.; Cook, Garry D.
  • Journal of Geophysical Research, Vol. 99, Issue D8
  • DOI: 10.1029/94JD00670

Formation of polycyclic aromatic hydrocarbons and their growth to soot—a review of chemical reaction pathways
journal, August 2000


Mechanisms of hydrogen cyanide formation from the pyrolysis of amino acids and related compounds
journal, January 1971

  • Johnson, William Randolph; Kan, John C.
  • The Journal of Organic Chemistry, Vol. 36, Issue 1
  • DOI: 10.1021/jo00800a038

Emissions from smoldering combustion of biomass measured by open-path Fourier transform infrared spectroscopy
journal, August 1997

  • Yokelson, Robert J.; Susott, Ronald; Ward, Darold E.
  • Journal of Geophysical Research: Atmospheres, Vol. 102, Issue D15
  • DOI: 10.1029/97JD00852

Effect of fuel composition on combustion efficiency and emission factors for African savanna ecosystems
journal, October 1996

  • Ward, D. E.; Hao, W. M.; Susott, R. A.
  • Journal of Geophysical Research: Atmospheres, Vol. 101, Issue D19
  • DOI: 10.1029/95JD02595

Influence of pyrolysis temperature and time on the cellulose fast pyrolysis products: Analytical Py-GC/MS study
journal, November 2011

  • Lu, Qiang; Yang, Xiao-chu; Dong, Chang-qing
  • Journal of Analytical and Applied Pyrolysis, Vol. 92, Issue 2, p. 430-438
  • DOI: 10.1016/j.jaap.2011.08.006

Evaluation of adsorption effects on measurements of ammonia, acetic acid, and methanol
journal, January 2003


Pyrolysis of isopropyl nitrate. I. Decomposition at low temperatures and pressures
journal, February 1975


A review of prescribed burning effectiveness in fire hazard reduction
journal, January 2003

  • Fernandes, Paulo M.; Botelho, Hermínio S.
  • International Journal of Wildland Fire, Vol. 12, Issue 2
  • DOI: 10.1071/WF02042

Open-path Fourier transform infrared studies of large-scale laboratory biomass fires
journal, September 1996

  • Yokelson, Robert J.; Griffith, David W. T.; Ward, Darold E.
  • Journal of Geophysical Research: Atmospheres, Vol. 101, Issue D15
  • DOI: 10.1029/96JD01800

Biomass Burning in the Tropics: Impact on Atmospheric Chemistry and Biogeochemical Cycles
journal, December 1990


NO x and N 2 O Precursors from Biomass Pyrolysis: Nitrogen Transformation from Amino Acid
journal, March 2012

  • Ren, Qiangqiang; Zhao, Changsui
  • Environmental Science & Technology, Vol. 46, Issue 7
  • DOI: 10.1021/es204142e

High- and low-temperature pyrolysis profiles describe volatile organic compound emissions from western US wildfire fuels
journal, January 2018

  • Sekimoto, Kanako; Koss, Abigail R.; Gilman, Jessica B.
  • Atmospheric Chemistry and Physics, Vol. 18, Issue 13
  • DOI: 10.5194/acp-18-9263-2018

Thermal degradation of xylan and related model compounds
journal, November 1972


Comprehensive laboratory measurements of biomass-burning emissions: 1. Emissions from Indonesian, African, and other fuels
journal, January 2003


The Role of Moisture on Combustion of Pyrolysis Gases in Wildland Fires
journal, February 2013

  • Ferguson, Selina C.; Dahale, Ambarish; Shotorban, Babak
  • Combustion Science and Technology, Vol. 185, Issue 3
  • DOI: 10.1080/00102202.2012.726666

Modeling chemical and physical processes of wood and biomass pyrolysis
journal, February 2008


Atmospheric geochemistry of formic and acetic acids at a mid-latitude temperate site
journal, January 1988

  • Talbot, R. W.; Beecher, K. M.; Harriss, R. C.
  • Journal of Geophysical Research, Vol. 93, Issue D2
  • DOI: 10.1029/JD093iD02p01638

First chemical events in pyrolysis of wood
journal, April 1988

  • Degroot, William F.; Pan, Wei-Ping; Rahman, M. Dalilur
  • Journal of Analytical and Applied Pyrolysis, Vol. 13, Issue 3
  • DOI: 10.1016/0165-2370(88)80024-X

Measurements of trace gases emitted by Australian savanna fires during the 1990 dry season
journal, January 1994

  • Hurst, Dale F.; Griffith, David W. T.; Carras, John N.
  • Journal of Atmospheric Chemistry, Vol. 18, Issue 1
  • DOI: 10.1007/BF00694373

A study of the gas-phase pyrolysis of glycerol
journal, March 1983

  • Stein, Yolanda S.; Antal, Michael Jerry; Jones, Maitland
  • Journal of Analytical and Applied Pyrolysis, Vol. 4, Issue 4
  • DOI: 10.1016/0165-2370(83)80003-5